scholarly journals Electrocatalytic study of ammonia synthesis and methane dimerization in high temperature solid electrolyte cells

1990 ◽  
Author(s):  
M Stoukides
2004 ◽  
Vol 59 (2) ◽  
pp. 163-167 ◽  
Author(s):  
B. K. Zuev ◽  
A. A. Korotkov ◽  
V. G. Filonenko ◽  
A. N. Mashkovtsev ◽  
V. P. Zvolinskii

1993 ◽  
Vol 38 (17) ◽  
pp. 2533-2539 ◽  
Author(s):  
Jiang Yi ◽  
Anthony Kaloyannis ◽  
Constaintinos G. Vayenas

2019 ◽  
Vol 18 (10) ◽  
pp. 1105-1111 ◽  
Author(s):  
Jitti Kasemchainan ◽  
Stefanie Zekoll ◽  
Dominic Spencer Jolly ◽  
Ziyang Ning ◽  
Gareth O. Hartley ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.


1994 ◽  
Vol 349 (8-9) ◽  
pp. 679-683 ◽  
Author(s):  
U. Lawrenz ◽  
S. Jakobs ◽  
H. -H. M�bius ◽  
U. Sch�nauer

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