scholarly journals Influence of surface defects and local structure on acid/base properties and oxidation pathways over metal oxide surfaces. Final report, June 1990--January 1997

1997 ◽  
Author(s):  
D.F. Cox
Keyword(s):  
Metal Oxide ◽  
Local Structure ◽  
Surface Defects ◽  
Oxide Surfaces ◽  
Final Report ◽  
Acid Base ◽  
Metal Oxide Surfaces ◽  
Base Properties

Measurement of acid–base properties on metal oxide surfaces in aqueous solution

1981 ◽  
Vol 77 (10) ◽  
pp. 2451 ◽  
Author(s):  
Hideaki Kita ◽  
Noriaki Henmi ◽  
Katsuaki Shimazu ◽  
Hideshi Hattori ◽  
Kozo Tanabe
Keyword(s):  
Aqueous Solution ◽  
Metal Oxide ◽  
Oxide Surfaces ◽  
Acid Base ◽  
Metal Oxide Surfaces ◽  
Base Properties

Atomic Bonding at Oxide Surfaces

1994 ◽  
Vol 357 ◽  
Author(s):  
Victor E. Henrich
Keyword(s):  
Point Defects ◽  
Surface Defects ◽  
Oxide Surfaces ◽  
Surface Point ◽  
Acid Base ◽  
Metal Oxide Surfaces ◽  
Oxidation Reduction ◽  
Defect Sites ◽  
Metal Ceramic ◽  
Ceramic Interfaces

AbstractThe fundamental interactions involved in the bonding of atoms and molecules to metal oxides are discussed. Surface defects play a major role in many of those interactions. Both acid/base and oxidation/reduction reactions occur at metal-oxide surfaces, with the latter dominating at point defect sites. The reaction of metals with oxide surfaces is governed largely by the relative heats of formation of the respective oxides, although surface point defects also play an important role. Preliminary studies of ceramic/ceramic interfaces indicate that interfacial interactions are much weaker than for metal/ceramic interfaces.

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