scholarly journals Free energy of formation of U/sub 3/O/sub 7/ in the temperature range 25 to 400/degree/C

1988 ◽  
Author(s):  
C. Pescatore
1976 ◽  
Vol 54 (24) ◽  
pp. 3872-3875
Author(s):  
Harry Horlings ◽  
Donald S. Scott ◽  
John R. Wynnyckyj

Heat of reaction and free energy of formation at 25 °C were determined from experimental equilibrium yields for the reaction[Formula: see text]in an aqueous solution.The values are 5045 and 1927 cal/mol respectively. Equilibrium constants for the reaction were determined over a temperature range from 20 to 193 °C.


1990 ◽  
Vol 163 (1) ◽  
pp. 109-113 ◽  
Author(s):  
Zhi-Tong Sui ◽  
Xing-Yi Xiao ◽  
Ke-Qin Huang ◽  
Chang-Zhen Wang

2021 ◽  
pp. 2150469
Author(s):  
T. G. Naghiyev ◽  
R. M. Rzayev

The solid solutions of [Formula: see text] were synthesized by solid-phase reactions from powder components of CaS, BaS, and Ga2S3. The temperature-concentration dependences of the Gibbs free energy of formation of [Formula: see text] solid solutions from ternary compounds and phase diagrams of the CaGa2S4–BaGa2S4 were determined by a calculation method. It was revealed that continuous solid solutions are formed in these systems. The spinodal decomposition of [Formula: see text] solid solutions into two phases is predicted at ordinary temperatures.


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