scholarly journals Melting in phase-change thermal storage media. Final report. [Mixture of sodium nitrate and sodium hydroxide]

1978 ◽  
Author(s):  
E. Sparrow ◽  
J. Ramsey
Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 121
Author(s):  
Liu Liu ◽  
Jianlei Niu ◽  
Jian-Yong Wu

Thermal energy storage (TES) is an important means for the conservation and efficient utilization of excessive and renewable energy. With a much higher thermal storage capacity, latent heat storage (LHS) may be more efficient than sensible heat storage. Phase change materials (PCMs) are the essential storage media for LHS. PCM emulsions have been developed for LHS in flow systems, which act as both heat transfer and thermal storage media with enhanced heat transfer, low pumping power, and high thermal storage capacity. However, two major barriers to the application of PCM emulsions are their instability and high degree of supercooling. To overcome these, various strategies have been attempted, such as the reduction of emulsion droplet size, addition of nucleating agents, and optimization of the formulation. To the best of our knowledge, however, there is still a lack of review articles on fabrication methods for PCM emulsions or their latest applications. This review was to provide an up-to-date and comprehensive summary on the effective strategies and the underlying mechanisms for the preparation of stable PCM emulsions and reduction of supercooling, especially with the organic PCMs of paraffin. It was also to share our insightful perspectives on further development and potential applications of PCM emulsions for efficient energy storage.


2021 ◽  
Vol 11 (13) ◽  
pp. 6234
Author(s):  
Ciprian Neagoe ◽  
Ioan Albert Tudor ◽  
Cristina Florentina Ciobota ◽  
Cristian Bogdanescu ◽  
Paul Stanciu ◽  
...  

Microencapsulation of sodium nitrate (NaNO3) as phase change material for high temperature thermal energy storage aims to reduce costs related to metal corrosion in storage tanks. The goal of this work was to test in a prototype thermal energy storage tank (16.7 L internal volume) the thermal properties of NaNO3 microencapsulated in zinc oxide shells, and estimate the potential of NaNO3–ZnO microcapsules for thermal storage applications. A fast and scalable microencapsulation procedure was developed, a flow calorimetry method was adapted, and a template document created to perform tank thermal transfer simulation by the finite element method (FEM) was set in Microsoft Excel. Differential scanning calorimetry (DSC) and transient plane source (TPS) methods were used to measure, in small samples, the temperature dependency of melting/solidification heat, specific heat, and thermal conductivity of the NaNO3–ZnO microcapsules. Scanning electron microscopy (SEM) and chemical analysis demonstrated the stability of microcapsules over multiple tank charge–discharge cycles. The energy stored as latent heat is available for a temperature interval from 303 to 285 °C, corresponding to onset–offset for NaNO3 solidification. Charge–self-discharge experiments on the pilot tank showed that the amount of thermal energy stored in this interval largely corresponds to the NaNO3 content of the microcapsules; the high temperature energy density of microcapsules is estimated in the range from 145 to 179 MJ/m3. Comparison between real tank experiments and FEM simulations demonstrated that DSC and TPS laboratory measurements on microcapsule thermal properties may reliably be used to design applications for thermal energy storage.


2021 ◽  
Vol 11 (4) ◽  
pp. 1390
Author(s):  
Rocío Bayón

Thermal energy storage using phase change materials (PCMs) is a research topic that has attracted much attention in recent decades [...]


2020 ◽  
Vol 148 ◽  
pp. 987-1001 ◽  
Author(s):  
Pouyan Talebizadeh Sardari ◽  
Donald Giddings ◽  
David Grant ◽  
Mark Gillott ◽  
Gavin S. Walker

2011 ◽  
Vol 31 (17-18) ◽  
pp. 3871-3884 ◽  
Author(s):  
Wei-Biao Ye ◽  
Dong-Sheng Zhu ◽  
Nan Wang

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