scholarly journals Shape memory effect in uranium-niobium alloys below room temperature. Final report. [6. 2 to 7. 0 wt % Nb]

1985 ◽  
Author(s):  
R.A. Vandermeer
Keyword(s):  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Room Temperature ◽  
Final Report ◽  
Niobium Alloys

High performance shape memory effect in nitinol wire for actuators with increased operating temperature range

2014 ◽  
Vol 07 (05) ◽  
pp. 1450063 ◽  
Author(s):  
Riccardo Casati ◽  
Carlo Alberto Biffi ◽  
Maurizio Vedani ◽  
Ausonio Tuissi
Keyword(s):  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
High Performance ◽  
Room Temperature ◽  
Operating Temperature ◽  
Niti Wire ◽  
Shape Memory Actuators ◽  
Nitinol Wire ◽  
Operating Temperature Range

In this research, the high performance shape memory effect (HP-SME) is experimented on a shape memory NiTi wire, with austenite finish temperature higher than room temperature. The HP-SME consists in the thermal cycling of stress induced martensite and it allows achieving mechanical work higher than that produced by conventional shape memory actuators based on the heating/cooling of detwinned martensite. The Nitinol wire was able to recover about 5.5% of deformation under a stress of 600 MPa and to withstand about 5000 cycles before failure. HP-SME path increased the operating temperature of the shape memory actuator wire. Functioning temperatures higher than 100°C was reached.

Cold Bending a Ni-Ti Shape Memory Alloy Wire

2015 ◽  
Vol 661 ◽  
pp. 98-104 ◽  
Author(s):  
Kuang-Jau Fann ◽  
Pao Min Huang
Keyword(s):  
Shape Memory Alloy ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Room Temperature ◽  
Aging Treatment ◽  
Treatment Temperature ◽  
Bending Test ◽  
Solution Treatment Temperature

Because of being in possession of shape memory effect and superelasticity, Ni-Ti shape memory alloys have earned more intense gaze on the next generation applications. Conventionally, Ni-Ti shape memory alloys are manufactured by hot forming and constraint aging, which need a capital-intensive investment. To have a cost benefit getting rid of plenty of die sets, this study is aimed to form Ni-Ti shape memory alloys at room temperature and to age them at elevated temperature without any die sets. In this study, starting with solution treatments at various temperatures, which served as annealing process, Ni-rich Ni-Ti shape memory alloy wires were bent by V-shaped punches in different curvatures at room temperature. Subsequently, the wires were aged at different temperatures to have shape memory effect. As a result, springback was found after withdrawing the bending punch and further after the aging treatment as well. A higher solution treatment temperature or a smaller bending radius leads to a smaller springback, while a higher aging treatment temperature made a larger springback. This springback may be compensated by bending the wires in further larger curvatures to keep the shape accuracy as designed. To explore the shape memory effect, a reverse bending test was performed. It shows that all bent wires after aging had a shape recovery rate above 96.3% on average.

The Shape Memory Effect in Melt Spun Fe-15Mn-5Si-9Cr-5Ni Alloys

2013 ◽  
Vol 738-739 ◽  
pp. 247-251 ◽  
Author(s):  
Ana Druker ◽  
Paulo La Roca ◽  
Philippe Vermaut ◽  
Patrick Ochim ◽  
Jorge Malarría
Keyword(s):  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Melt Spinning ◽  
Room Temperature ◽  
Tensile Tests ◽  
Argon Atmosphere ◽  
Austenitic Phase ◽  
Melt Spun ◽  
Shape Memory Behaviour

At room temperature, Fe-15Mn-5Si-9Cr-5Ni alloys are usually austenitic and the application of a stress induces a reversible martensitic transformation leading to a shape memory effect (SME). However, when a ribbon of this material is obtained by melt-spinning, the rapid solidification stabilizes a high-temperature ferritic phase. The goals of this work were to find the appropriate heat treatment in order to recover the equilibrium austenitic phase, characterize the ribbon form of this material and evaluate its shape memory behaviour. We found that annealing at 1050°C for 60 min, under a protective argon atmosphere, followed by a water quenching stabilizes the austenite to room temperature. The yield stress, measured by tensile tests, is 250 MPa. Shape-memory tests show that a strain recovery of 55% can be obtained, which is enough for certain applications.

Shape Memory Effect Improvement and Study of the Corrosion Resistance of the Fe-8Mn-6Si-13Cr-6Ni-12Co Alloy

2012 ◽  
Vol 476-478 ◽  
pp. 2162-2170 ◽  
Author(s):  
Amine Charfi ◽  
Fehmi Gamaoun ◽  
Tarak Bouraoui ◽  
Chedly Bradai ◽  
Bernard Normand
Keyword(s):  
Corrosion Resistance ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Room Temperature ◽  
316L Stainless Steel ◽  
Experimental Tests ◽  
Good Corrosion Resistance ◽  
Resistance Tests ◽  
Better Than

Fe-8Mn-6Si-13Cr-6Ni-12Co shape memory alloys are characterized by a good corrosion resistance and a modest shape memory effect. Experimental tests of the corrosion resistance of Fe-8Mn-6Si-13Cr-6Ni-12Co have been studied and compared with the Fe-32Mn-6Si alloy using weight loss, free corrosion and polarization resistance tests. The shape memory effect measurement of the Fe-8Mn-6Si-13Cr-6Ni-12Co and Fe-32Mn-6Si alloys has been also tested after 5% of deformation. The results of corrosion experimental tests show that the Fe-8Mn-6Si-13Cr-6Ni-12Co SMA is not very active in the Na2SO4 solution at pH4 at room temperature. In addition, its corrosion resistance is better than the Fe-32Mn-6Si and almost similar to the 316L stainless steel. To improve the shape memory effect of the Fe-8Mn-6Si-13Cr-6Ni-12Co, a thermomechanical treatment has been applied by 8% prestrain in tensile and followed by heat treatment at 1320K for 1 hour. The results show an improvement in the shape memory effect after 5% of deformation in tensile test.

Towards Novel Light-Activated Shape Memory Polymer: Thermomechanical Properties of Photo-responsive Polymers

2005 ◽  
Vol 872 ◽  
Author(s):  
Emily A. Snyder ◽  
Tat H. Tong
Keyword(s):  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Room Temperature ◽  
Shape Memory Polymer ◽  
Crosslinking Density ◽  
Material System ◽  
Effect Change ◽  
Responsive Polymers ◽  
Original Shape

AbstractThe basic principle for the operation of a thermally stimulated shape memory polymer (SMP) is a drastic change in elastic modulus above the glass transition temperature (Tg). This change from glassy modulus to rubbery modulus allows the material to be deformed above the Tg and retain the deformed shape when cooled below the Tg. The material will recover its original shape when heated above the Tg again. However, thermal activation is not the only possibility for a polymer to exhibit this shape memory effect or change of modulus. This paper discusses results of an alternative approach to SMP activation.It is well known that the Tg of a thermosetting polymer is proportional to its crosslinking density. It is possible for the crosslinking density of a room temperature elastomer to be modified through photo-crosslinking special photo-reactive monomer groups incorporated into the material system in order to increase its Tg. Correspondingly, the modulus will be increased from the rubbery state to the glassy state. As a result, the material is transformed from an elastomer to a rigid glassy photoset, depending on the crosslinking density achieved during exposure to the proper wavelength of light. This crosslinking process is reversible by irradiation with a different wavelength, thus making it possible to produce light-activated SMP materials that could be deformed at room temperature, held in deformed shape by photo-irradiation using one wavelength, and recovered to the original shape by irradiation with a different wavelength.In this work, monomers which contain photo-crosslinkable groups in addition to the primary polymerizable groups were synthesized. These monomers were formulated and cured with other monomers to form photo-responsive polymers. The mechanical properties of these materials, the kinetics, and the reversibility of the photo-activated shape memory effect were studied to demonstrate the effectiveness of using photo-irradiation to effect change in modulus (and thus shape memory effect).

Hot Forming a V-Shaped Ni-Ti Shape Memory Alloy Wire

2014 ◽  
Vol 626 ◽  
pp. 377-382
Author(s):  
Kuang-Jau Fann ◽  
Hau Chi Hsu
Keyword(s):  
Shape Memory Alloy ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Room Temperature ◽  
Phase State ◽  
Process Temperature ◽  
Shape Memory Alloy Wire ◽  
Austenitic Phase ◽  
Alloy Wire

Ni-Ti shape memory alloys have shape memory effect, that if they are deformed from martensitic phase state at a lower temperature, they will recover their original shape by heating them to austenitic phase state. To have them for an application using this shape memory effect, usually they undergo a constraint aging after plastic deformation. That is, they are fixed with tool set and together heat treated in a furnace after they are formed at room temperature. However a large load is needed to form them at room temperature. Thus, this study is aimed to lower the forming load by combining the forming and aging process together in a furnace at high temperature. In this study, a Ni-Ti shape memory alloy wire having a diameter of 0.63 mm is bent in a heated chamber at 450°C, 500°C, 550°C, and 600°C, respectively, by a V-shaped punch of 2 mm in radius to an angle of 60°, then held along with the die set at its dead center in the chamber for maximum one hour long, and then quenched in the water. All of the bent wires have the shape memory effect. That is, the wires recover their bent geometry once they are unbent at about 4°C and heated again at about 100°C. The experiment results showed that the bent wires can have the geometry accuracy as desired because of stress relaxation found in the process, which depends on the process temperature and duration. As a result, the higher the process temperature is and the longer the duration is, the better the accuracy of the formed wires is.

scholarly journals Magnetic Properties and Microstructures of Rapidly Solidified FePd Alloy Ribbons

2008 ◽  
Vol 59 ◽  
pp. 24-29 ◽  
Author(s):  
Yoichi Kishi ◽  
Zenjiro Yajima ◽  
Teiko Okazaki ◽  
Yasubumi Furuya ◽  
Manfred Wuttig
Keyword(s):  
Magnetic Field ◽  
Magnetic Properties ◽  
Coercive Force ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Room Temperature ◽  
Parent Phase ◽  
Diffraction Profile ◽  
Rapidly Solidified

It is well known that FePd alloys are effective as a magneto-thermoelastic actuator material, because they have large magnetostriction and shape memory effect. In order to use the alloys for a micro-actuator, magnetic properties and microstructures have been examined as for rapidly solidified Fe-29.6 at% Pd alloy ribbons. The ribbons exhibit a large magnetostriction at room temperature and good shape memory effect. Magnetostriction and coercive force of the ribbons markedly depend on the direction of the applied magnetic field. Maximum values of magnetostriction and coercive force are obtained at θ = 85 degree (θ is the angle between the magnetic field and the ribbon plane). Relief effects corresponding to the formation of FCT martensite variants are observed on the grains. X-ray diffraction profile at room temperature shows that FCT martensitic phase and FCC parent phase coexist in the ribbon. Dense striations are observed in the TEM bright field images of FCT martensite plates. Selected area electron diffraction patterns revealed the striations to be thin twins.

Study of Micro-Abrasive Wear Resistance of Heat Treated NiTi Alloys

2015 ◽  
Vol 1120-1121 ◽  
pp. 1069-1077
Author(s):  
Palloma Vieira Muterlle ◽  
Ítalo de Barros Casto ◽  
Paulo Herrera
Keyword(s):  
Abrasive Wear ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Room Temperature ◽  
Wear Behavior ◽  
Niti Alloy ◽  
Wear Testing ◽  
Wear Coefficient ◽  
Niti Alloys

The Nickel Titanium (NiTi) alloy is a shape memory alloy. It presents two distinct properties: shape memory effect (martensite phase at room temperature) and the pseudoelasticity (austenite phase at room temperature). These materials are frequently used in industries like engineering, dentistry, medicine and aeronautics, and for certain applications it is important to know the wear behavior of these alloys.Thus, this study aims to evaluate the micro-abrasive wear behavior of pseudoelastic NiTi alloys at the as received and aged conditions, and compare with results obtained for NiTi alloy with shape memory effect. The aging heat treatment was performed at temperatures of 350, 450, 500 and 600 °C with an isotherm of 30 minutes and subsequent quenching in water. The wear tests were carried out in a free ball machine. After wear testing was observed that the wear coefficient obtained were lower for all treatment temperatures when compared to pseudoelastic NiTi alloy as received, reducing wear by 30 % in case of treatment at 350 °C. The alloy with shape memory effect showed good wear behavior, with a wear coefficient about 14 % less than the untreated pseudoelastic NiTi alloy.

Fe-Mn-Si Based Shape Memory Alloys

1991 ◽  
Vol 246 ◽  
Author(s):  
H. Otsuka
Keyword(s):  
Shape Memory Alloys ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Thermomechanical Treatment ◽  
Memory Effect ◽  
Room Temperature ◽  
Steel Pipe ◽  
Original Shape ◽  
Ε Martensite ◽  
Pipe Joints

AbstractFe-Mn-Si based alloys are non-thermoelastic shape memory alloys which utilize the stress-induced transformation from γ austenite to ε martensite. After these shape memory alloys are deformed at room temperature, they recover their original shape when heated to 473K or higher. Fe-Mn-Si based alloys contain 15% to 33% Mn, 5% to 6% Si, 0% to 13% Cr, and 0% to 10% Ni in weight. Mn and Si are indispensable for the development of shape memory effect (SME). The amounts of these elements require to be adjusted so that the Neel temperature (TN) lies lower than Ms temperature and the Ms lies just below room temperature. Though the volume of stress-induced martensite is only 20 to 30%, a thermomechanical treatment called “training” has made it possible for the alloy to recover from a tensi le deformation exceeding 3%. Today, the use of the shape memory al loys for steel pipe joints is being studied. They have already been put into practical use for an auxiliary bicycle part to clamp the frame.

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