scholarly journals Photofragmentation of ketene to CH sub 2 ( tilde X sup 3 B sub 1 ) + CO: Dissociation rate, energy release and exit barrier height

1989 ◽  
Author(s):  
I-Chia. Chen
Keyword(s):  
Energy Release ◽  
Barrier Height ◽  
Dissociation Rate ◽  
Co Dissociation ◽  
Exit Barrier

Electronic effects on carbon monoxide dissociation from iron(II) tetraphenylporhyrins

2005 ◽  
Vol 09 (12) ◽  
pp. 821-829
Author(s):  
Marco A. Lopez ◽  
Martha A. De La Rosa
Keyword(s):  
Carbon Monoxide ◽  
Rate Constant ◽  
Field Effect ◽  
Dissociation Rate ◽  
Electronic Effects ◽  
Co Dissociation ◽  
Phenyl Rings ◽  
Porphyrin Core ◽  
Electron Donation ◽  
Kinetics Of

We report the kinetics of CO binding to a series of substituted ferrous tetra(4-X-phenyl)porphyrins ( X = CF 3, Cl , H , CH 3, OCH 3) in DMSO solvent using a mixture of 1,2-DMI/1-MeIm as proximal base. The CO dissociation rate constant increases with electron donation of the substituent X; the aggregate Hammett ρ value is -0.38. Using a Swain-Lupton analysis we determine the electronic effects to be transmitted 67% by through-bond or field effect and 33% by resonance. These results indicate that there is significant conjugation between the phenyl rings and the porphyrin core of iron tetraphenylporphyrin systems.

Kinetic-energy release in CO dissociation caused by fastF4+impact

1995 ◽  
Vol 51 (1) ◽  
pp. 391-399 ◽  
Author(s):  
I. Ben-Itzhak ◽  
S. G. Ginther ◽  
Vidhya Krishnamurthi ◽  
K. D. Carnes
Keyword(s):  
Kinetic Energy ◽  
Energy Release ◽  
Kinetic Energy Release ◽  
Co Dissociation

Hypersensitivity to Thromboxane A2 in Cholesterol-Rich Human Platelets

1990 ◽  
Vol 64 (04) ◽  
pp. 594-599 ◽  
Author(s):  
Takuya Tomizuka ◽  
Kyohei Yamamoto ◽  
Aizan Hirai ◽  
Yasushi Tamura ◽  
Sho Yoshida
Keyword(s):  
Calcium Concentration ◽  
Binding Capacity ◽  
Thromboxane A2 ◽  
Cytosolic Calcium ◽  
Cholesterol Content ◽  
Human Platelets ◽  
Dissociation Rate ◽  
Platelet Membrane ◽  
Maximal Concentration ◽  
Equilibrium Dissociation

SummaryThe effect of changes in platelet membrane cholesterol content on thromboxane A2 (TXA2)-induced platelet activation was studied. Concentrations of 9,ll-epithio-ll,12-methano-TXA2 (STA2), a stable analogue of TXA2 which can cause half-maximal aggregation and release of [14C]serotonin in cholesterol-rich platelets were significantly lower than those in cholesterol-normal platelets. STA2-induced increase in cytosolic calcium concentration and [32P]phosphatidic acid formation in cholesterol-rich platelets were significantly greater than those in cholesterol-normal platelets. The maximal concentration of binding site (Bmax) for SQ29548 was significantly increased in cholesterol-rich platelets compared with cholesterol-normal platelets, while the equilibrium dissociation rate constant (Kd) for SQ29548 did not differ between cholesterol-rich and cholesterol-normal platelets. The present study suggested that sensitivity to TXA2 was increased by the incorporation of cholesterol into platelet membrane and that the cause of hypersensitivity to TXA2 in cholesterol-rich platelets may be partly explained by an increase in binding capacity for TXA2.

High Quality HfO2 Film and Its Applications in Novel Poly-Si Devices

2002 ◽  
Vol 716 ◽  
Author(s):  
K.L. Ng ◽  
N. Zhan ◽  
M.C. Poon ◽  
C.W. Kok ◽  
M. Chan ◽  
...  
Keyword(s):  
Barrier Height ◽  
Nonvolatile Memory ◽  
Dielectric Material ◽  
Tunneling Current ◽  
Interface Layer ◽  
Si Substrate ◽  
Hfo2 Film ◽  
Effective Barrier Height ◽  
Effective Barrier ◽  
Nonvolatile Memory Devices

AbstractHfO2 as a dielectric material in MOS capacitor by direct sputtering of Hf in an O2 ambient onto a Si substrate was studied. The results showed that the interface layer formed between HfO2 and the Si substrate was affected by the RTA time in the 500°C annealing temperature. Since the interface layer is mainly composed of hafnium silicate, and has high interface trap density, the effective barrier height is therefore lowered with increased RTA time. The change in the effective barrier height will affect the FN tunneling current and the operation of the MOS devices when it is applied for nonvolatile memory devices.

Calculating Energy Release Rate as a Function of Crack Length Using a Multiple-Step Crack Closure Technique in Tire Finite Element Models

2018 ◽  
Vol 46 (3) ◽  
pp. 130-152
Author(s):  
Dennis S. Kelliher
Keyword(s):  
Finite Element ◽  
Energy Release Rate ◽  
Crack Length ◽  
Energy Release ◽  
Crack Closure ◽  
Release Rate ◽  
Fatigue Behavior ◽  
Three Dimensions ◽  
Quantitative Prediction ◽  
Closure Technique

ABSTRACT When performing predictive durability analyses on tires using finite element methods, it is generally recognized that energy release rate (ERR) is the best measure by which to characterize the fatigue behavior of rubber. By addressing actual cracks in a simulation geometry, ERR provides a more appropriate durability criterion than the strain energy density (SED) of geometries without cracks. If determined as a function of crack length and loading history, and augmented with material crack growth properties, ERR allows for a quantitative prediction of fatigue life. Complications arise, however, from extra steps required to implement the calculation of ERR within the analysis process. This article presents an overview and some details of a method to perform such analyses. The method involves a preprocessing step that automates the creation of a ribbon crack within an axisymmetric-geometry finite element model at a predetermined location. After inflating and expanding to three dimensions to fully load the tire against a surface, full ribbon sections of the crack are then incrementally closed through multiple solution steps, finally achieving complete closure. A postprocessing step is developed to determine ERR as a function of crack length from this enforced crack closure technique. This includes an innovative approach to calculating ERR as the crack length approaches zero.

Effects of energy release on high-speed flows in an axisymmetric combustor

1989 ◽  
Author(s):  
K. KAILASANATH ◽  
J. GARDNER ◽  
E. ORAN ◽  
J. BORIS
Keyword(s):  
Energy Release ◽  
High Speed ◽  
High Speed Flows
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