scholarly journals Mound Facility activities in chemical and physical research: January-June 1980. [OLECULES; VIRIAL EQUATION; CHEMICAL REACTIONS; DEUTERIUM; TRITIUM; CALCIUM NITRATES; HEAVY WATER; THERMAL DIFFUSION; WATER; CROSS SECTIONS; MOLECULAR BEAMS; TEMPERATURE DEPENDENCE; CHELATING AGENTS; CHLOROFORM]

1980 ◽  
Author(s):  
Not Given Author
Keyword(s):  
Temperature Dependence ◽  
Thermal Diffusion ◽  
Chemical Reactions ◽  
Heavy Water ◽  
Cross Sections ◽  
Chelating Agents ◽  
Molecular Beams ◽  
Virial Equation ◽  
Physical Research

scholarly journals The Reaction of Spin–Orbit State-Selected Ca(PJ03) With CH3I, CH2I2, and SF6

1986 ◽  
Vol 6 (6) ◽  
pp. 391-402 ◽  
Author(s):  
Mark L. Campbell ◽  
Nick Furio ◽  
Paul J. Dagdigian
Keyword(s):  
Chemical Reactions ◽  
Cross Sections ◽  
Optical Pumping ◽  
Spin Orbit ◽  
Alkyl Bromide ◽  
The Individual ◽  
State Selection

Chemiluminescence cross sections for reaction of the individual spin–orbit states of metastable Ca(PJ03) with CH3I, CH2I2, and SF6 have been determined by the use of optical pumping state selection. This technique was also used to separate the chemiluminescence arising from the two excited metastable Ca 3P0 and 1D states. The spin–orbit dependence of the chemiluminescence pathway was found to be substantial for the CH3I and CH2I2 reactions and similar to that previously observed for halogen diatom and alkyl bromide reagents. By contrast, no spin–orbit effect was observed for Ca(3P0)+SF6. These results are discussed in terms of our previously presented model for the origin of spin–orbit effects in chemical reactions.

Heat capacity of activation for the hydrolysis of methanesulfonyl chloride and benzenesulfonyl chloride in light and heavy water

1969 ◽  
Vol 47 (22) ◽  
pp. 4199-4206 ◽  
Author(s):  
R. E. Robertson ◽  
B. Rossall ◽  
S. E. Sugamori ◽  
L. Treindl
Keyword(s):  
Heat Capacity ◽  
Free Energy ◽  
Temperature Dependence ◽  
Heavy Water ◽  
Bond Formation ◽  
Sulfonyl Chlorides ◽  
Benzenesulfonyl Chloride ◽  
Methanesulfonyl Chloride ◽  
Hydrolysis Of ◽  
Parameter Temperature Dependence

Rates of solvolysis of methanesulfonyl chloride and benzenesulfonyl chloride have been determined in H2O and D2O. The free energy, enthalpy, entropy, and heat capacity of activation were calculated. The exceptional accuracy of the data permitted an estimation of dΔCp≠/dT from a four parameter temperature dependence of the kinetic rates.From these data we conclude that both sulfonyl chlorides hydrolyse by the same mechanism (Sn2) The change in R from CH3 to C6H5 in RSO2Cl did not alter ΔCp≠ but ΔS≠ (20°) was changed from −8.32 to −13.25 cal deg−1 mole−1, respectively. The significance of this difference is attributed to the probability of bond formation rather than to differences in solvent reorganization.

Temperature dependence of thermal diffusion for aqueous solutions of monosaccharides, oligosaccharides, and polysaccharides

2012 ◽  
Vol 14 (29) ◽  
pp. 10147 ◽  
Author(s):  
Yuki Kishikawa ◽  
Haruka Shinohara ◽  
Kousaku Maeda ◽  
Yoshiyuki Nakamura ◽  
Simone Wiegand ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Temperature Dependence ◽  
Thermal Diffusion

Experimental and theoretical CO2–Ar pressure-broadening cross sections and their temperature dependence

2001 ◽  
Vol 3 (18) ◽  
pp. 3924-3933 ◽  
Author(s):  
F. Thibault ◽  
B. Calil ◽  
J. Buldyreva ◽  
M. Chrysos ◽  
J.-M. Hartmann ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Cross Sections ◽  
Pressure Broadening

Helium Atom Scattering from Cyclopentane, Pyrrolidine and Tetrahydrofurane in Crossed Molecular Beams

1997 ◽  
Vol 52 (5) ◽  
pp. 425-431
Author(s):  
Christian Gebauer ◽  
Olaf Klein ◽  
Ralf Schmidt ◽  
Wolfhart Seidel
Keyword(s):  
High Resolution ◽  
Helium Atom ◽  
Cross Sections ◽  
Differential Cross ◽  
Molecular Beam ◽  
Molecular Beams ◽  
Geometric Transformation ◽  
Helium Atom Scattering ◽  
Helium Atoms ◽  
Atom Scattering

Abstract Scattering of helium atoms by cyclopentane, pyrrolidine and tetrahydrofurane molecules was ob-served in crossed molecular beam experiments. The intensity of scattered helium atoms, depending on the scattering angle, was measured with high resolution, and the damping of the diffraction oscillations of the differential cross sections was used to extract elastic anisotropic interaction potentials for these molecules. The evaluation included a geometric transformation concerning the puckered states of the envelope and the twisted conformation of the molecules. The potentials were found to be rather similar.

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