As part of the joint GE/DoE Water-Cooled Components Test Program,1 a series of tests were performed involving the combustion of a minimally cleaned low-Btu coal gas in a pressurized gas turbine simulator. The fuel gas was produced in a 1-ton/hr advanced fixed-bed gasifier using Illinois #6 coal, and filtered of particulate in a full-pressure, full-temperature cyclone separator. The resulting product had a gross heating value of approximately 5000 kJ/kg at a temperature of 540 °C and a pressure of 22 bar. Numerous contaminants also remained in the fuel gas, including approximately 100 ppmw particulate matter (coal dust of 3 μm average size), 2000–4000 ppmv ammonia, 2000–2500 ppmv H2S, and 0.5–1.0% vaporized tars, oils, phenols, and other condensible hydrocarbons.
The fuel gas was burned with air at 6–7 bar pressure and 400 °C temperature in a gas turbine combustion system at overall fuel-air ratios up to 0.25 (overall equivalence ratio 0.36). Gaseous emissions were sampled in the exhaust stream and measurements made for O2, CO2, CO, unburned hydrocarbons, NOx, and SOx. The CO and unburned hydrocarbon emissions were both below 20 ppmv at full firing conditions, indicating acceptable combustion efficiency. The NOx levels measured were up to 500 ppmv, and were due to the of conversion of fuel-bound nitrogen (ammonia principally). The SOx emissions directly followed the oxidation of fuel-bound sulfur (H2S principally). At part-load conditions, emissions of CO and unburned hydrocarbons were observed to increase, as expected. Stable operation was maintained down to a combustion system temperature rise of approximately 350 °C.