scholarly journals HAZARDS AND EXPERIMENTAL PROCEDURE EVALUATION FOR STUDIES ON THE POLYMERIZATION AND HYDROLYSIS OF PLUTONIUM IN URANYL NITRATE AND NITRIC ACID SOLUTION AT ELEVATED TEMPERATURES

1960 ◽  
Author(s):  
R E Biggers ◽  
D A Costanzo
Keyword(s):  
Nitric Acid ◽  
Acid Solution ◽  
Nitric Acid Solution ◽  
Uranyl Nitrate ◽  
Elevated Temperatures ◽  
Experimental Procedure ◽  
Hydrolysis Of

scholarly journals BEHAVIOR OF RARE-EARTH METALS IN HYDROMETALLURGICAL PROCESSING OF PYROCHLOR-MONAZITE-GOETHITE ORES

2018 ◽  
Vol 13 (3) ◽  
pp. 64-71
Author(s):  
N. A. Permyakova ◽  
E. I. Lysakova ◽  
S. I. Anufrieva ◽  
E. G. Likhnikevich
Keyword(s):  
Rare Earth ◽  
Nitric Acid ◽  
Acid Solution ◽  
Nitric Acid Solution ◽  
Elevated Temperatures ◽  
Rare Earth Metals ◽  
Acid Leaching ◽  
Earth Metal ◽  
Hydrometallurgical Processing ◽  
Nitric Acid Leaching

The article is dedicated to finding out the specific features of the behavior of rare-earth metals in hydrometallurgical processing of pyrochlore-monazite-goetite ores of the Chuktukonsky ore field is shown in the work. Chuktukonsky ore field is a potential source of rare earth metals. The mentioned ores are practically unenforceable. Hydrometallurgical methods for their complex processing were suggested. Agitational and autoclave nitric acid leaching depending on such technological parameters as temperature, HNO3 concentration, process duration, S:L ratio and the use of H2O2 were studied. The possibility of transferring manganese (that is present in a significant amount in the ore) into a nitric acid solution by hydrogen peroxide was considered. Based on the results of the conducted studies, the distribution of REM in the products of the hydrometallurgical conversion of pyrochlore-monazitegoetite ore was estimated. It was found out that incomplete opening of the ore material was observed during agitational leaching: average REM recovery into the solution is 60%. The study made it possible to solve the problem of purifying nitric acid solutions from phosphorus that hinders the subsequent extraction and separation of rare earth metal ions forming strong complexes with rare earths. Removal of phosphorus from the solution was achieved by conducting the process under pressure at elevated temperatures (200-230 0C). It was found that the optimal decomposition conditions ensuring the transfer of almost 99% of the REM into the nitric acid solution are: 25% solution of HNO3, ore size - 0.071 mm; 5% by volume H2O2; t(160 0С) = 1 h; t(230 0С) = 1 h, gradual temperature increase from 160 to 230 0С; S:L = 1:8. Autoclave nitric-acid leaching allows selecting rare earth metals from the main part of iron, phosphorus and niobium.

scholarly journals Novel pyrimidine-bichalcophene derivatives as corrosion inhibitors for copper in 1 M nitric acid solution

RSC Advances ◽  
2021 ◽  
Vol 11 (41) ◽  
pp. 25314-25333
Author(s):  
Mai A. Khaled ◽  
Mohamed A. Ismail ◽  
Ahmed. A. El-Hossiany ◽  
Abd El-Aziz S. Fouda
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Nitric Acid ◽  
Impedance Spectroscopy ◽  
Acid Solution ◽  
Nitric Acid Solution ◽  
Potentiodynamic Polarization ◽  
Corrosion Inhibitors ◽  
Electrochemical Impedance ◽  
Pyrimidine Derivatives

This study targets the investigation of three pyrimidine derivatives (MA-1230, MA-1231, MA-1232) for the prevention of corrosion on copper in 1 M HNO3via weight loss (WL), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) techniques.

scholarly journals The effect of crystal textures on the anodic oxidization of zirconium in a boiling nitric acid solution

2015 ◽  
Vol 53 (9) ◽  
pp. 1371-1379 ◽  
Author(s):  
Chiaki Kato ◽  
Yasuhiro Ishijima ◽  
Fumiyoshi Ueno ◽  
Masahiro Yamamoto
Keyword(s):  
Nitric Acid ◽  
Acid Solution ◽  
Nitric Acid Solution

Influence of Corona Discharge on CaSO4 Solubility of Silicone Rubber Insulator Surface

2021 ◽  
Vol 69 (1) ◽  
pp. 74-79
Author(s):  
Sihua Wang ◽  
Junjun Wang ◽  
Chen Long ◽  
Zhao Lei
Keyword(s):  
Nitric Acid ◽  
Acid Solution ◽  
Corona Discharge ◽  
Nitric Acid Solution ◽  
Silicone Rubber ◽  
Calcium Sulfate ◽  
Salt Composition ◽  
Surface Product ◽  
Two Temperatures ◽  
Discharge Test

Some studies have shown that the operating state of silicone rubber insulators is not only affected by surface corona discharge, but also different due to the surface covered with different pollutants, but few studies have linked the two. In this paper, by designing the corona discharge test of silicone rubber insulator, the output of nitric acid from its surface product was calculated, and the concentration of nitric acid under different air humidity was obtained. The solubility test of slightly dissolved salt calcium sulfate in nitric acid solution at 293.15K and 333.15K was designed to obtain the solubility of calcium sulfate at different concentrations of nitric acid at two temperatures. Finally, a quantitative analysis of the solubility of calcium sulfate on the surface of insulator FXBW-10/70 in nitric acid solution shows that the surface contamination of insulator with good hydrophobicity may be completely dissolved by nitric acid solution, but the surface of insulator with loss of hydrophobicity cannot be completely dissolved by nitric acid. This study provides a theoretical basis for the dissolution characteristics of silicon rubber insulator corona discharge on its surface soluble salt composition and provides a new idea for the influence of insulator corona discharge on its electrical properties.

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