scholarly journals Crystal structures of diketone complexes of alkaline earth metals and other compounds

1972 ◽  
Author(s):  
Frederick John Hollander
Keyword(s):  
Crystal Structures ◽  
Alkaline Earth ◽  
Alkaline Earth Metals

scholarly journals Die Kristallstrukturen von Strontium- und Bariumhexacyanoferrat(III)-Hexamethylentetramin-Hydraten. Strukturmodell für Additionsverbindungen der Alkali- und Erdalkalimetallhexacyanoferrate mit Hexamethylentetramin / The Crystal Structures of Hydrates of Strontium and Barium Hexacyanoferrate(III) with Hexamethylenetetramine. Structural Model for Adducts of the Hexacyanoferrates of Alkaline and Alkaline Earth Metals with Hexamethylenetetramine

1989 ◽  
Vol 44 (5) ◽  
pp. 519-525 ◽  
Author(s):  
Hans-Jürgen Meyer ◽  
Joachim Pickardt
Keyword(s):  
Aqueous Solutions ◽  
Crystal Structures ◽  
General Formula ◽  
Alkaline Earth ◽  
Structural Model ◽  
Earth Metal ◽  
Alkaline Earth Metals ◽  
Alkaline Earth Metal ◽  
Monoclinic Space Group ◽  
Space Group

By reaction of methanolic solutions of hexamethylenetetramine with aqueous solutions of hexacyanoferrates(III) of strontium and barium resp., crystals of the compounds were obtained. Sr3[Fe(CN)6]2 · 3 C6H12N4 · 18 H2O, tetragonal, space group P42/nmc, Z = 4, a = 1931.8(4), c = 1579.9(4) pm, 1358 reflections. R = 0.066. Ba3[Fe(CN)6]2 · 2 C6H12N4 · 11 Η2Ο. monoclinic. space group P21/n, Ζ = 2, a = 1148.0(4), b = 1369.7(4), c = 1584.5(4) pm, γ = 95.79(3)°, 2583 reflections, R = 0.057. The crystal structures of these adducts are compared with those of other hexamethylenetetramine adducts of alkaline and alkaline earth metal hexacyanoferrates of the general formula M,[Fe(CN)6]y · zC6H12N4 · vH2O recently investigated by us. A structural model for the adducts is presented.

scholarly journals The Crystal Structures of the Alkaline Earth Metals

1928 ◽  
Vol 14 (8) ◽  
pp. 617-618 ◽  
Author(s):  
G. L. Clark ◽  
A. J. King ◽  
J. F. Hyde
Keyword(s):  
Crystal Structures ◽  
Alkaline Earth ◽  
Alkaline Earth Metals

Synthese und Kristallstrukturen von Diazadien-Komplexen der Erdalkalimetalle / Syntheses and Crystal Structures of Diazadiene Complexes of the Alkaline Earth Metals

1995 ◽  
Vol 50 (1) ◽  
pp. 71-75 ◽  
Author(s):  
Volker Lorenz ◽  
Bernhard Neumüller ◽  
Karl-Heinz Thiele
Keyword(s):  
Crystal Lattice ◽  
Crystal Structures ◽  
Structure Determination ◽  
Alkaline Earth ◽  
Alkaline Earth Metals ◽  
The Other ◽  
Calcium Atom ◽  
Space Group ◽  
X Ray ◽  
Moisture Sensitive

(DME)2] 1 (R = C6H4-4-CH3; DME = dimethoxyethane) was prepared by reaction of calcium with NR=CPh-CPh=NR in DME solution. The compound forms orange, moisture sensitive crystals, which were characterized by an X-ray structure determination [space group orthorhombic, P212121, Z = 4, 4634 observed unique reflections, R = 0.046; lattice dimensions at –70 °C: a = 1340.2(3), b = 1528.1(3), c = 1609.1(3) pm]. The calcium atom is coordinated by the four oxygen atoms of two chelating DME molecules and two nitrogen atoms of the diazadiene ligand, bonded in its enediamide form.[Ba2(DME)3(NPh–CPh=CPh–NPh)2 · DME] 3 was obtained from barium metal and NPh=CPh-CPh=NPh in DME solution as red crystals [space group monoclinic, P2l/c, Z = 4, 4000 observed unique reflections, R = 0.166; lattice dimensions at -70 °C: a = 1704.5(3), b = 1786.1(4), c = 2177.4(4) pm, β = 105.98(3)°]. The two barium atoms are bridged by two differently bonded diazadiene ligands (μ2-Ν,Ν′;μ-Ν, σ-Ν′). Additionally, one of the barium atoms is coordinated to two DME molecules and the other one to only one of the ether molecules. A further DME molecule is a constituent of the crystal lattice.

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