scholarly journals ON THE KINETICS OF OXIDATION BY NITRIC ACID

1958 ◽  
Author(s):  
J.E. Savolainen
Keyword(s):  
Nitric Acid ◽  
Kinetics Of Oxidation ◽  
Kinetics Of

Kinetics of oxidation of 30% TBP solutions in С13 diluent with nitric acid: Effect of temperature and γ-irradiation

2016 ◽  
Vol 58 (4) ◽  
pp. 426-430 ◽  
Author(s):  
E. V. Belova ◽  
Z. V. Dzhivanova ◽  
G. P. Tkhorzhnitskii ◽  
S. V. Stefanovsky ◽  
B. F. Myasoedov
Keyword(s):  
Nitric Acid ◽  
Effect Of Temperature ◽  
Γ Irradiation ◽  
Kinetics Of Oxidation ◽  
Acid Effect ◽  
Kinetics Of

Kinetics of Oxidation of Benzyl Alcohol with Dilute Nitric Acid

2005 ◽  
Vol 44 (2) ◽  
pp. 325-333 ◽  
Author(s):  
Sudhir R. Joshi ◽  
Kamal L. Kataria ◽  
Sudhirprakash B. Sawant ◽  
Jyeshtharaj B. Joshi
Keyword(s):  
Nitric Acid ◽  
Benzyl Alcohol ◽  
Kinetics Of Oxidation ◽  
Oxidation Of Benzyl Alcohol ◽  
Kinetics Of ◽  
Dilute Nitric Acid

Kinetics of Oxidation of Cyclohexanol by Ceric Ammonium Nitrate in Aq. HNO3

1972 ◽  
Vol 27 (1) ◽  
pp. 46-49 ◽  
Author(s):  
D. L. Mathur ◽  
G. V. Bakore
Keyword(s):  
Hydrogen Bond ◽  
Nitric Acid ◽  
Hydrogen Ion ◽  
Ceric Ammonium Nitrate ◽  
Nitric Acid Medium ◽  
Kinetics Of Oxidation ◽  
Ion Concentrations ◽  
Rate Determining Step ◽  
Ceric Ion ◽  
Kinetics Of

The oxidation of cyclohexanol by ceric ion has been studied in the presence of nitric acid (~1-2.5 M). The rate dependence on alcohol suggests intermediate complex formation. The increase in hydrogen ion and nitrate ion concentrations retards the rate of oxidation. The results have been explained on the basis of Ce (OH)3⊕, as the reactive species. The value of Kh for the equilibrium Ce4⊕ +H2O ⇄ Ce (OH)3⊕+H⊕ has been evaluated as 4.8 at 25°C in nitric acid medium. A mechanism based on decomposition of Ce (IV) -alcohol complex and rupture of α-carbon hydrogen bond in the rate determining step has been put forward.

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