scholarly journals A STUDY OF COMPLEX IONS IN FUSED SALT SYSTEMS. Final Report

1959 ◽  
Author(s):  
R.A. Osteryoung ◽  
J.D. VanNorman ◽  
J.H. Christie
Keyword(s):  
Final Report ◽  
Complex Ions ◽  
Salt Systems ◽  
Fused Salt

Vapour pressures and activities in the reciprocal fused salt systems ZnCl2 + Na2SO4 and ZnSO4 + NaCl

1975 ◽  
Vol 28 (12) ◽  
pp. 2587 ◽  
Author(s):  
RG Anthony ◽  
H Bloom
Keyword(s):  
Zinc Chloride ◽  
Vapour Pressure ◽  
Reciprocal System ◽  
Covalent Bonding ◽  
Salt System ◽  
Log P ◽  
Complex Ions ◽  
Partial Molar Enthalpies ◽  
Salt Systems ◽  
Fused Salt

Zinc chloride vapour pressures, activities and partial molar energies have been determined in the reciprocal fused salt system: Zn,Na/Cl,SO4 over the range 770-900 K. The transpiration vapour pressure of pure ZnCl2 was first redetermined for the range 720-900 K and found to follow the equation (in which P� is in mmHg): �������������� Log P�ZnCl2 = (-8247�17)/T-5.033 log T + 26.213 � 0.006 Activities of ZnC1, in the reciprocal system differed greatly from ideality, the degree of departure varying with both composition and temperature. In general, at relatively high ZnCl, concentrations, observed activities were greater than ideal and ZnCl2 partial molar enthalpies were positive; this behaviour is believed to be largely caused by the effect of partial covalent bonding in pure ZnCl2. At low ZnCl2 concentrations, activities were much less than ideal and ZnCl2 partial molar enthalpies were negative; this other effect is believed to be caused by the formation of complex ions within this system.

X-Ray Studies of Fused Salt Systems.1II. Indium(III) Iodide

1952 ◽  
Vol 74 (7) ◽  
pp. 1760-1762 ◽  
Author(s):  
R. E. Wood ◽  
H. L. Ritter
Keyword(s):  
X Ray ◽  
Salt Systems ◽  
Fused Salt

Thermodynamic properties of the binary molten salt systems, PbBr2-KBr, PbBr2-RbBr and PbBr2-CsBr, by measurement of the electromotive forces of galvanic cells

1981 ◽  
Vol 34 (3) ◽  
pp. 479 ◽  
Author(s):  
H Bloom ◽  
MS White
Keyword(s):  
Thermodynamic Properties ◽  
Molten Salt ◽  
Activity Coefficients ◽  
Molten Salts ◽  
Free Energies ◽  
Complex Ions ◽  
Galvanic Cells ◽  
Salt Systems

The electromotive forces of galvanic cells for the formation of PbBr2 in the molten binary salt systems, PbBr2-KBr, PbBr2,-RbBr and PbBr2-CsBr, have been measured. Activities, activity coefficients and partial molar free energies have been calculated for each component of the three systems. Integral free energies of mixing have also been calculated. Various models of mixing of molten salts have been applied to the results. The systems contain complex ions, probably mixtures of PbBr42-, PbBr64- with some PbBr3-.

SOLUBILITY OF CALCIUM CARBIDE IN FUSED SALT SYSTEMS

1961 ◽  
Vol 65 (11) ◽  
pp. 2026-2028 ◽  
Author(s):  
William A. Barber ◽  
Carol L. Sloan
Keyword(s):  
Calcium Carbide ◽  
Salt Systems ◽  
Fused Salt

Investigation of fused salt systems based on thorium fluoride

Atomic Energy ◽  
1956 ◽  
Vol 1 (5) ◽  
pp. 753-759 ◽  
Author(s):  
V. S. Emelyanov ◽  
A. I. Evstyukhin
Keyword(s):  
Thorium Fluoride ◽  
Salt Systems ◽  
Fused Salt

X-Ray Studies of Fused Salt Systems. III. Tin(IV) Iodide

1952 ◽  
Vol 74 (7) ◽  
pp. 1763-1764 ◽  
Author(s):  
R. E. Wood ◽  
H. L. Ritter
Keyword(s):  
X Ray ◽  
Salt Systems ◽  
Fused Salt
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