scholarly journals Bulk and surface electronic structure of actinide, rare earth, and transition metal elements and compounds

1996 ◽  
Author(s):  
J.W. Wills ◽  
O. Eriksson
Keyword(s):  
Electronic Structure ◽  
Rare Earth ◽  
Transition Metal ◽  
Metal Elements ◽  
Surface Electronic Structure ◽  
Transition Metal Elements

scholarly journals Facile Chemical Synthesis of Doped ZnO Nanocrystals Exploiting Oleic Acid

Nanomaterials ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 1150 ◽  
Author(s):  
Sugata Barui ◽  
Roberto Gerbaldo ◽  
Nadia Garino ◽  
Rosaria Brescia ◽  
Francesco Laviano ◽  
...  
Keyword(s):  
Magnetic Resonance Imaging ◽  
Rare Earth ◽  
Oleic Acid ◽  
Magnetic Resonance ◽  
Transition Metal ◽  
Rare Earth Elements ◽  
Resonance Imaging ◽  
Metal Elements ◽  
Doped Zno ◽  
Transition Metal Elements

Zinc oxide nanocrystals (ZnO-NCs) doped with transition metal elements or rare earth elements can be probed for magnetic resonance imaging to be used as a molecular imaging technique for accurate diagnosis of various diseases. Herein, we use Mn as a candidate of transition metal elements and Gd as a presenter of rare earth elements. We report an easy and fast coprecipitation method exploiting oleic acid to synthesize spherical-shaped, small-sized doped ZnO-NCs. We show the improved colloidal stability of oleate-stabilized doped ZnO-NCs compared to the doped ZnO-NCs synthesized by conventional sol–gel synthesis method, i.e., without a stabilizing agent, especially for the Mn dopant. We also analyze their structural, morphological, optical, and magnetic properties. We are able to characterize the persistence of the crystalline properties (wurtzite structure) of ZnO in the doped structure and exclude the formation of undesired oxides by doping elements. Importantly, we determine the room-temperature ferromagnetism of the doped ZnO-NCs. This oleate-stabilized coprecipitation method can be subjected as a standard procedure to synthesize doped and also co-doped ZnO-NCs with any transition metal elements or rare earth elements. In the future, oleate-stabilized Gd/Mn-doped ZnO-NCs can be exploited as magnetic resonance imaging (MRI) contrast agents and possibly increase the signal intensity on T1-weighted images or reduce the signal intensity on T2-weighted images.

scholarly journals CASPT2 study of inverse sandwich-type dinuclear 3d transition metal complexes of ethylene and dinitrogen molecules: similarities and differences in geometry, electronic structure, and spin multiplicity

2015 ◽  
Vol 17 (25) ◽  
pp. 16294-16305 ◽  
Author(s):  
Masayuki Nakagaki ◽  
Shigeyoshi Sakaki
Keyword(s):  
Electronic Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Spin Multiplicity ◽  
Metal Elements ◽  
Sandwich Type ◽  
Similarities And Differences ◽  
Transition Metal Elements

The spin multiplicities and coordination structures of inverse sandwich-type complexes of ethylene and dinitrogen molecules with 3d transition metal elements (Sc to Ni) were investigated by the CASPT2 method.

Selected multiferroic perovskite oxides containing rare earth and transition metal elements

2014 ◽  
Vol 59 (36) ◽  
pp. 5170-5179 ◽  
Author(s):  
Shunbo Hu ◽  
Lei Chen ◽  
Yabei Wu ◽  
Liming Yu ◽  
Xinluo Zhao ◽  
...  
Keyword(s):  
Rare Earth ◽  
Transition Metal ◽  
Perovskite Oxides ◽  
Metal Elements ◽  
Transition Metal Elements

Handy waveguide TXRF spectrometer for nanogram sensitivity

2008 ◽  
Vol 23 (2) ◽  
pp. 146-149 ◽  
Author(s):  
Shinsuke Kunimura ◽  
Jun Kawai
Keyword(s):  
Rare Earth ◽  
Transition Metal ◽  
Rare Earth Elements ◽  
Beam Size ◽  
X Ray ◽  
Metal Elements ◽  
Transition Metal Elements

A specimen containing nanograms of sulfur, calcium, and 3d transition metal elements was measured by incident X-ray beams of various sizes restricted by a waveguide placed in a portable TXRF spectrometer. The signal to background ratios of spectra decreased with an increase in incident X-ray beam size. The portable spectrometer was also applied to rainwater and a specimen containing antimony and rare earth elements. Nanograms of elements in these specimens were detected by K-line or L-line excitation.

New Class of Diluted Ferromagnetic Semiconductors based on CaO without Transition Metal Elements

2004 ◽  
Vol 43 (No. 7A) ◽  
pp. L934-L936 ◽  
Author(s):  
Kazuhide Kenmochi ◽  
Masayoshi Seike ◽  
Kazunori Sato ◽  
Akira Yanase ◽  
Hiroshi Katayama-Yoshida
Keyword(s):  
Transition Metal ◽  
Ferromagnetic Semiconductors ◽  
Metal Elements ◽  
New Class ◽  
Transition Metal Elements

scholarly journals Polarizable Charge Equilibration Model for Transition-Metal Elements

2018 ◽  
Vol 122 (48) ◽  
pp. 9350-9358 ◽  
Author(s):  
Soonho Kwon ◽  
Saber Naserifar ◽  
Hyuck Mo Lee ◽  
William A. Goddard
Keyword(s):  
Transition Metal ◽  
Metal Elements ◽  
Charge Equilibration ◽  
Equilibration Model ◽  
Transition Metal Elements

scholarly journals Preparation and Magnetic Properties of X-type Hexaferrites with Transition Metal Elements

2010 ◽  
Vol 57 (12) ◽  
pp. 809-813
Author(s):  
Nobuyuki Hosaka ◽  
Kenji Kamishima ◽  
Koichi Kakizaki ◽  
Nobuyuki Hiratsuka
Keyword(s):  
Magnetic Properties ◽  
Transition Metal ◽  
Metal Elements ◽  
Transition Metal Elements
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