scholarly journals Isotopic fractionation as in-situ sensor of subsurface reactive flow and precursor for rock failure.

2021 ◽  
Author(s):  
Anastasia Ilgen ◽  
Robert Choens ◽  
Andrew Knight ◽  
Jacob Harvey ◽  
Mario Martinez ◽  
...  
Keyword(s):  
Isotopic Fractionation ◽  
Rock Failure ◽  
Reactive Flow ◽  
In Situ Sensor

In Situ Sensor Monitoring of the Processing and Cure Properties of Solid Propellants

1993 ◽  
Author(s):  
D. E. Kranbuehl ◽  
S. Hart ◽  
Y. Wang ◽  
D. F. Schwartz
Keyword(s):  
Solid Propellants ◽  
In Situ Sensor ◽  
Sensor Monitoring

scholarly journals Significant Zr isotope variations in single zircon grains recording magma evolution history

2020 ◽  
Vol 117 (35) ◽  
pp. 21125-21131 ◽  
Author(s):  
Jing-Liang Guo ◽  
Zaicong Wang ◽  
Wen Zhang ◽  
Frédéric Moynier ◽  
Dandan Cui ◽  
...  
Keyword(s):  
Isotopic Fractionation ◽  
Major Type ◽  
Strong Temperature Dependence ◽  
Calc Alkaline ◽  
Southern Tibet ◽  
Rayleigh Distillation ◽  
Single Zircon ◽  
Magmatic History ◽  
Fractionation Factors

Zircons widely occur in magmatic rocks and often display internal zonation finely recording the magmatic history. Here, we presented in situ high-precision (2SD <0.15‰ for δ94Zr) and high–spatial-resolution (20 µm) stable Zr isotope compositions of magmatic zircons in a suite of calc-alkaline plutonic rocks from the juvenile part of the Gangdese arc, southern Tibet. These zircon grains are internally zoned with Zr isotopically light cores and increasingly heavier rims. Our data suggest the preferential incorporation of lighter Zr isotopes in zircon from the melt, which would drive the residual melt to heavier values. The Rayleigh distillation model can well explain the observed internal zoning in single zircon grains, and the best-fit models gave average zircon–melt fractionation factors for each sample ranging from 0.99955 to 0.99988. The average fractionation factors are positively correlated with the median Ti-in-zircon temperatures, indicating a strong temperature dependence of Zr isotopic fractionation. The results demonstrate that in situ Zr isotope analyses would be another powerful contribution to the geochemical toolbox related to zircon. The findings of this study solve the fundamental issue on how zircon fractionates Zr isotopes in calc-alkaline magmas, the major type of magmas that led to forming continental crust over time. The results also show the great potential of stable Zr isotopes in tracing magmatic thermal and chemical evolution and thus possibly continental crustal differentiation.

Temperature and Viscosity in-Situ Sensor for Hostile Processes

1999 ◽  
pp. 1163-1170 ◽  
Author(s):  
Krishnan Balasubramaniam ◽  
V. Vimal ◽  
Gary Boudreaux ◽  
R. Daniel Costley ◽  
Clinton Menezes ◽  
...  
Keyword(s):  
In Situ Sensor

scholarly journals LSSVM-Based Rock Failure Criterion and Its Application in Numerical Simulation

2015 ◽  
Vol 2015 ◽  
pp. 1-13 ◽  
Author(s):  
Changxing Zhu ◽  
Hongbo Zhao ◽  
Zhongliang Ru
Keyword(s):  
Rock Mass ◽  
Failure Criterion ◽  
Nonlinear Problems ◽  
Failure Criteria ◽  
Rock Failure ◽  
Support Vector ◽  
Failure Behavior ◽  
Circular Tunnel ◽  
Vector Machines

A rock failure criterion is very important for the prediction of the failure of rocks or rock masses in rock mechanics and engineering. Least squares support vector machines (LSSVM) are a powerful tool for addressing complex nonlinear problems. This paper describes a LSSVM-based rock failure criterion for analyzing the deformation of a circular tunnel under differentin situstresses without assuming a function form. First, LSSVM was used to represent the nonlinear relationship between the mechanical properties of rock and the failure behavior of the rock in order to construct a rock failure criterion based on experimental data. Then, this was used in a hypothetical numerical analysis of a circular tunnel to analyze the mechanical behavior of the rock mass surrounding the tunnel. The Mohr-Coulomb and Hoek-Brown failure criteria were also used to analyze the same case, and the results were compared; these clearly indicate that LSSVM can be used to establish a rock failure criterion and to predict the failure of a rock mass during excavation of a circular tunnel.

The chlorine-isotopic composition of lunar KREEP from magnesian-suite troctolite 76535

2020 ◽  
Vol 105 (8) ◽  
pp. 1270-1274
Author(s):  
Francis M. McCubbin ◽  
Jessica J. Barnes
Keyword(s):  
Isotopic Composition ◽  
Melt Inclusions ◽  
Melt Inclusion ◽  
Isotopic Fractionation ◽  
Magma Ocean ◽  
Geochemical Composition ◽  
Isotopic Compositions ◽  
Stable Isotopic ◽  
Lunar Samples

Abstract We conducted in situ Cl isotopic measurements of apatite within intercumulus regions and within a holocrystalline olivine-hosted melt inclusion in magnesian-suite troctolite 76535 from Apollo 17. These data were collected to place constraints on the Cl-isotopic composition of the last liquid to crystallize from the lunar magma ocean (i.e., urKREEP, named after its enrichments in incompatible lithophile trace elements like potassium, rare earth elements, and phosphorus). The apatite in the olivine-hosted melt inclusion and within the intercumulus regions of the sample yielded Cl-isotopic compositions of 28.3 ± 0.9‰ (2σ) and 30.3 ± 1.1‰ (2σ), respectively. The concordance of these values from both textural regimes we analyzed indicates that the Cl-isotopic composition of apatites in 76535 likely represents the Cl-isotopic composition of the KREEP-rich magnesian-suite magmas. Based on the age of 76535, these results imply that the KREEP reservoir attained a Cl-isotopic composition of 28–30‰ by at least 4.31 Ga, consistent with the onset of Cl-isotopic fractionation at the time of lunar magma ocean crystallization or shortly thereafter. Moreover, lunar samples that yield Cl-isotopic compositions higher than the value for KREEP are likely affected by secondary processes such as impacts and/or magmatic degassing. The presence of KREEP-rich olivine-hosted melt inclusions within one of the most pristine and ancient KREEP-rich rocks from the Moon provides a new opportunity to characterize the geochemistry of KREEP. In particular, a broader analysis of stable isotopic compositions of highly and moderately volatile elements could provide an unprecedented advancement in our characterization of the geochemical composition of the KREEP reservoir and of volatile-depletion processes during magma ocean crystallization, more broadly.

scholarly journals A new in situ sensor for large-scale snow-cover monitoring

2004 ◽  
Vol 38 ◽  
pp. 273-278 ◽  
Author(s):  
Manfred Stähli ◽  
Markus Stacheder ◽  
David Gustafsson ◽  
Stefan Schlaeger ◽  
Martin Schneebeli ◽  
...  
Keyword(s):  
Large Scale ◽  
Snow Water Equivalent ◽  
Soil Surface ◽  
Test Site ◽  
Liquid Water Content ◽  
Flat Band ◽  
Snow Layer ◽  
In Situ Sensor ◽  
Set Up

AbstractA new in situ sensor for the simultaneous measurement of snow water equivalent, snow density and liquid-water content is presented in this paper. The system consists of radio frequency transmission lines of up to 25 m length cast in a flat PVC band, which can be set up either horizontally to monitor single snow-layer properties or sloping from a mast to the soil surface to determine vertical snowpack properties. The dielectric coefficient along the flat-band cable is measured with a time-domain reflectometer at high frequencies, and with a low-frequency impedance analyzer. The performance of the sensor system was tested during two winter seasons (2001–03) at the high-alpine test site Weissfluhjoch, Davos, Switzerland. The cable suspension and set-up of the sloping cable was shown to be critical with regard to stability and the formation of unwanted air gaps along the cable. Overall, the sensing system proved quite robust and produced results in agreement with manual snowpack observations.

scholarly journals Hydrogen isotopic anomalies in extraterrestrial organic matter: role of cosmic ray irradiation and implications for UCAMMs

2019 ◽  
Vol 627 ◽  
pp. A122 ◽  
Author(s):  
B. Augé ◽  
E. Dartois ◽  
J. Duprat ◽  
C. Engrand ◽  
G. Slodzian ◽  
...  
Keyword(s):  
Organic Matter ◽  
Infrared Spectroscopy ◽  
Spatial Scale ◽  
Secondary Ion Mass Spectrometry ◽  
Isotopic Fractionation ◽  
Cosmic Ray ◽  
High Energy ◽  
Galactic Cosmic Rays ◽  
Ex Situ

Context. Micrometeorites represent, at timescales shorter than a few million years, the dominant source of extraterrestrial matter at the surface of the Earth. Analyses of ultracarbonaceous micrometeorites recovered from Antarctica, known as UCAMMs reveal an exceptionally N-rich organic matter associated with spatially extended high D enrichments. Experiments show that this specific organic matter might have been formed in the outer solar system by energetic irradiation of N-rich icy surfaces. Aims. We experimentally investigate the hydrogen isotopic fractionation resulting from irradiation of normal and D-rich N2-CH4 ices by high energy ions, simulating the exposition to Galactic cosmic rays of icy bodies surfaces orbiting at large heliocentric distances. Methods. Films of N2-CH4 ices and a N2-CH4/CD4/N2-CH4 “sandwich” ice were exposed to 129Xe13+ ion beams at 92 and 88 MeV. The chemical evolution of the samples was monitored using in situ Fourier transform infrared spectroscopy. After irradiation, targets were annealed to room temperature. The solid residues of the whole process left after ice sublimation were characterized in situ by infrared spectroscopy, and the hydrogen isotopic composition measured ex situ by imaging secondary ion mass spectrometry at the sub-micron scale (NanoSIMS). Results. Irradiation leads to the formation of new molecules and radicals. After annealing, the resulting poly-HCN-like macro-molecular residue exhibits an infrared spectrum close to that of UCAMMs. The residue resulting from irradiation of N2-CH4 ices does not exhibit a significant deuterium enrichment comparable to that found in extraterrestrial organic matter. The residue formed by irradiation of D-rich ices shows the formation of isotopic heterogeneities with localised hotspots and an extended contribution likely due to the diffusion of the radiolytic products from the D-rich layer. Conclusions. These results show that high-energy cosmic ray irradiation does not induce the large hydrogen isotopic fractionation observed at small spatial scale in interplanetary organics. By contrast, large D/H ratio heterogeneities at the sub-micron spatial scale in extraterrestrial organic matter can result from isotopically heterogeneous ices mixtures (i.e. condensed with different D/H ratios), which were transformed into refractory organic matter upon irradiation.

MiniPINS - Miniature in situ sensor packages for Mars and Moon

2020 ◽  
Author(s):  
Maria Hieta ◽  
Maria Genzer ◽  
Harri Haukka ◽  
Antti Kestilä ◽  
Ignacio Arruego ◽  
...  
Keyword(s):  
In Situ Sensor
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