scholarly journals Cost Effective Polymer Solar Cells Research and Education

2015 ◽  
Author(s):  
Sam-Shajing Sun
2018 ◽  
Vol 1 (3) ◽  
pp. 1226-1232 ◽  
Author(s):  
Abid Ali ◽  
Mehmet Kazici ◽  
Sinem Bozar ◽  
Bahadir Keskin ◽  
Murat Kaleli ◽  
...  

2015 ◽  
Vol 788 ◽  
pp. 301-305 ◽  
Author(s):  
Vladimir Andreevich Bataev ◽  
Vladimir G. Burov ◽  
Souren Grigorian ◽  
Dimitri A. Ivanov ◽  
Natalya V. Plotnikova ◽  
...  

The widespread use of polymeric semiconductor compositions for creating flexible and inexpensive solar cells can be achieved by providing the higher values of the coefficient of efficiency. The cost-effective production of polymer solar cells is expected at the efficiency of them not less than 10 %, while now its real level does not exceed 4 %. Many laboratories work to develop semiconductor compositions of organic materials as donors and acceptors which are fullerene derivatives or nanosize particles of semiconductor inorganic compounds [1-6]. The prospect of polymer used depends on the photovoltaic materials and the polymer purity and to a greater extent on the structure of the films formed from the compositions under development. In the search for ways to achieve higher performance of solar cells it is essential to optimize the technology of polymeric composition preparation, of which the active layer is formed, as well as optimization of the layer formation. In order to get information about the relationship between the structure of formed layer and its photovoltaic characteristics it is suggested to analyze the structure of the active layer simultaneously with the monitoring of its current-voltage characteristics. The study of the material structure directly in the process of its evolution seems an urgent task, since the majority of modern methods of structure investigation (light and electron microscopy, X-ray analysis) is not able to detect structural changes occurring in a short period of time. The most useful tool for monitoring the structure of polymer active layer is high intensity X-ray diffraction.


2020 ◽  
Vol 8 (26) ◽  
pp. 13049-13058 ◽  
Author(s):  
Youdi Zhang ◽  
Yongjoon Cho ◽  
Jungho Lee ◽  
Jiyeon Oh ◽  
So-Huei Kang ◽  
...  

Two solid additives, BDT-1 and BDT-2, in non-fullerene polymer solar cells enhance photovoltaic efficiencies up to 16.26% with improved thermal and photoinduced stabilities.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
MirKazem Omrani ◽  
Hamidreza Fallah ◽  
Kwang-Leong Choy ◽  
Mojtaba Abdi-Jalebi

AbstractThe solution processable polymer solar cells have shown a great promise as a cost-effective photovoltaic technology. Here, the effect of carrier mobility changes has been comprehensively investigated on the performance of P3HT:PCBM polymer solar cells using electro-optical coupled simulation regimes, which may result from the embedding of SiO2@Ag@SiO2 plasmonic nanoparticles (NPs) in the active layer. Firstly, the active layer thickness, stemmed from the low mobility of the charge carriers, is optimized. The device with 80 nm thick active layer provided maximum power conversion efficiency (PCE) of 3.47%. Subsequently, the PCE has increased to 6.75% and 6.5%, respectively, along with the benefit of light scattering, near-fields and interparticle hotspots produced by embedded spherical and cubic nanoparticles. The PCE of the devices with incorporated plasmonic nanoparticles are remarkably enhanced up to 7.61% (for spherical NPs) and 7.35% (for cubic NPs) owing to the increase of the electron and hole mobilities to $${\upmu }_{e}=8\times {10}^{-7} \,{\text{m}}^{2}/\text{V}/\text{s}$$ μ e = 8 × 10 - 7 m 2 / V / s and $${\upmu }_{h}=4\times {10}^{-7} \,{\text{m}}^{2}/\text{V}/\text{s}$$ μ h = 4 × 10 - 7 m 2 / V / s , respectively (in the optimum case). Furthermore, SiO2@Ag@SiO2 NPs have been successfully synthesized by introducing and utilizing a simple and eco-friendly approach based on electroless pre-treatment deposition and Stober methods. Our findings represent a new facile approach in the fabrication of novel plasmonic NPs for efficient polymer solar cells.


2008 ◽  
Vol 80 (10) ◽  
pp. 2151-2161 ◽  
Author(s):  
Sergey A. Zapunidy ◽  
Dmitry S. Martyanov ◽  
Elena M. Nechvolodova ◽  
Marina V. Tsikalova ◽  
Yuri N. Novikov ◽  
...  

Polymer solar cells have shown high potential to convert solar energy into electricity in a cost-effective way. One of the basic reasons limiting the polymer solar cell efficiency is insufficient absorption of the solar radiation by the active layer that limits the photocurrent. To increase the photocurrent, one needs low-bandgap materials with strong absorption below 2 eV. In this work, we study two types of low-bandgap materials: ground-state charge-transfer complexes (CTCs) of a conjugated polymer, MEH-PPV (poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylenevinylene]), and an exohedral metallocomplex of fullerene, (η2-C60)IrH(CO)[(+)DIOP] (IrC60). We demonstrate that the CTC formed between MEH-PPV and conjugated molecules with high electron affinity, namely, 2,4,7-trinitrofluorenone (TNF) and 1,5-dinitroantraquinone (DNAQ), can have strong optical absorption extending down to the near infrared. We have observed that the photoexcited CTC can generate free charges. We also report on optical studies of IrC60 as a possible acceptor for polymer/fullerene solar cells. IrC60 strongly absorbs in the visible spectral range, in particular in the red part, and therefore has a potential for increasing the photocurrent as compared with polymer/methanofullerene solar cells. Our studies of MEH-PPV/IrC60 blended films show that long-lived charges are efficiently generated at MEH-PPV upon photoexcitation of the blend.


2016 ◽  
Vol 7 (4) ◽  
pp. 926-932 ◽  
Author(s):  
Tao Jiang ◽  
Jie Yang ◽  
Youtian Tao ◽  
Cong Fan ◽  
Lingwei Xue ◽  
...  

A new random terpolymer PTB7-Th-T2 was designed and synthesized for high performance PSCs by incorporating a significantly lower-cost 2,2′-bithiophene monomer to the famous PTB7-Th skeleton.


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