scholarly journals Collaborative Project: Understanding the Chemical Processes tat Affect Growth rates of Freshly Nucleated Particles

2015 ◽  
Author(s):  
Peter McMurry ◽  
James Smuth
1986 ◽  
Vol 84 ◽  
Author(s):  
S.M. Sharland

AbstractUnder repository conditions, it is likely that radioactive waste canisters will be subjected to both uniform and localised corrosion. Localised corrosion can take many forms depending on the precise physical and chemical environment of the metal at the time of attack, but generally the rates of penetration are much greater than those associated with uniform corrosion. The most likely forms under aerated repository conditions are pitting and crevice corrosion. To ensure adequate radionuclide containment an allowance for these rates must be included in the final canister dimensions. It is considered the best way to predict long term penetration rates is to develop mathematical models, which include all the physical and chemical processes necessary to describe the system and use experimentally determined input parameters relating to these processes. These models must then draw on further experimental data for validation over short timescales. In this paper, we discuss several techniques of modelling long term pit propagation in waste canisters. The complexity of the problem has lead to a number of physical and chemical approximations in the modelling. We investigate the applicability and ranges of validity of several of the more common approximations, both in our own models and in the literature, and compare the predictions with experimental pit growth rates. An investigatation of the sensitivity of the models to the various empirical input parameters indicates which need to be determined most accurately.


1966 ◽  
Vol 94 (4) ◽  
pp. 491-498 ◽  
Author(s):  
F. D. Malkinson
Keyword(s):  

2005 ◽  
pp. 4-18 ◽  
Author(s):  
K. Sonin

In unequal societies, the rich may benefit from shaping economic institutions in their favor. This paper analyzes the dynamics of institutional subversion by focusing on public protection of property rights. If this institution functions imperfectly, agents have incentives to invest in private protection of property rights. The ability to maintain private protection systems makes the rich natural opponents of public protection of property rights and precludes grass-roots demand to drive the development of the market-friendly institution. The economy becomes stuck in a bad equilibrium with low growth rates, high inequality of income, and wide-spread rent-seeking. The Russian oligarchs of the 1990s, who controlled large stakes of newly privatized property, provide motivation for this paper.


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