scholarly journals High-Performance Palladium Based Membrane for Hydrogen Separation and Purification

2012 ◽  
Author(s):  
Scott Hopkins
Keyword(s):  
High Performance ◽  
Hydrogen Separation ◽  
Separation And Purification

Separation and purification of individual neurofilament proteins by reverse-phase high-performance liquid chromatography

1986 ◽  
Vol 153 (2) ◽  
pp. 230-234 ◽  
Author(s):  
Koon-Sea Hui ◽  
Maria Hui ◽  
Fung-Chow Chiu ◽  
Miriam Banay-Schwartz ◽  
Teresita Deguzman ◽  
...  
Keyword(s):  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
High Performance ◽  
Separation And Purification ◽  
Neurofilament Proteins ◽  
Reverse Phase

scholarly journals Hydrogen Separation and Purification from Various Gas Mixtures by Means of Electrochemical Membrane Technology in the Temperature Range 100–160 °C

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 282
Author(s):  
Leandri Vermaak ◽  
Hein W. J. P. Neomagus ◽  
Dmitri G. Bessarabov
Keyword(s):  
Hydrogen Permeability ◽  
Gas Mixtures ◽  
Open Circuit ◽  
Hydrogen Separation ◽  
Proton Exchange ◽  
Limiting Current ◽  
Separation Performance ◽  
Separation And Purification ◽  
Irreversible Damage ◽  
Temperature Range

This paper reports on an experimental evaluation of the hydrogen separation performance in a proton exchange membrane system with Pt-Co/C as the anode electrocatalyst. The recovery of hydrogen from H2/CO2, H2/CH4, and H2/NH3 gas mixtures were determined in the temperature range of 100–160 °C. The effects of both the impurity concentration and cell temperature on the separation performance of the cell and membrane were further examined. The electrochemical properties and performance of the cell were determined by means of polarization curves, limiting current density, open-circuit voltage, hydrogen permeability, hydrogen selectivity, hydrogen purity, and cell efficiencies (current, voltage, and power efficiencies) as performance parameters. High purity hydrogen (>99.9%) was obtained from a low purity feed (20% H2) after hydrogen was separated from H2/CH4 mixtures. Hydrogen purities of 98–99.5% and 96–99.5% were achieved for 10% and 50% CO2 in the feed, respectively. Moreover, the use of proton exchange membranes for electrochemical hydrogen separation was unsuccessful in separating hydrogen-rich streams containing NH3; the membrane underwent irreversible damage.

Thermal Degradation Behavior of Hydrogen Permeability of Pd-Coated V-Alloy Membrane for Hydrogen Separation and Purification

2021 ◽  
Vol 1016 ◽  
pp. 1710-1714
Author(s):  
Hiroshi Yukawa ◽  
Tomonori Nambu ◽  
Yoshihisa Matsumoto
Keyword(s):  
Thermal Activation ◽  
Hydrogen Permeability ◽  
Testing Temperature ◽  
Hydrogen Separation ◽  
Activation Process ◽  
Degradation Behavior ◽  
Separation And Purification ◽  
Accelerated Degradation ◽  
Thermal Degradation Behavior ◽  
Thermal Activation Process

A series of accelerated degradation experiments at high temperatures have been performed for Pd-coated V-10 mol% Fe alloy membranes in order to investigate the degradation behavior of hydrogen permeability. The degradation of the membrane becomes severer with increasing testing temperature. The temperature dependence of the 20% degradation rate almost obeys the Arrhenius relationship, suggesting that the degradation phenomenon occurs by a kind of thermal activation process. It is found that the addition of a small amount of W into Pd overlayer improves the durability of the membrane significantly.

Stereosequenced crystalline polyhydroxyalkanoates from diastereomeric monomer mixtures

Science ◽  
2019 ◽  
Vol 366 (6466) ◽  
pp. 754-758 ◽  
Author(s):  
Xiaoyan Tang ◽  
Andrea H. Westlie ◽  
Eli M. Watson ◽  
Eugene Y.-X. Chen
Keyword(s):  
Energy Cost ◽  
High Performance ◽  
Polymeric Materials ◽  
Powerful Method ◽  
Purification Process ◽  
Separation And Purification ◽  
Material Loss ◽  
Stereogenic Centers

Stereoselective polymerization of chiral or prochiral monomers is a powerful method to produce high-performance stereoregular crystalline polymeric materials. However, for monomers with two stereogenic centers, it is generally necessary to separate diastereomers before polymerization, resulting in substantial material loss and added energy cost associated with the separation and purification process. Here we report a diastereoselective polymerization methodology enabled by catalysts that directly polymerize mixtures of eight-membered diolide (8DL) monomers with varying starting ratios of chiral racemic (rac) and achiral meso diastereomers into stereosequenced crystalline polyhydroxyalkanoates with isotactic and syndiotactic stereodiblock or stereotapered block microstructures. These polymers show enhanced ductility and toughness relative to polymers of pure rac-8DL, subject to tuning by variation of the diastereomeric ratio and structure of the 8DL monomers.

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