scholarly journals Modeling and laboratory investigations of microbial oil recovery mechanisms in porous media

Author(s):  
M.M. Chang ◽  
R.S. Bryant ◽  
A.K. Stepp ◽  
K.M. Bertus
Author(s):  
E. Kowalewski ◽  
I. Rueslåtten ◽  
E. Gilje ◽  
E. Sunde ◽  
G. Bødtker ◽  
...  

Author(s):  
Tiantian Zhang ◽  
Gang Xie ◽  
Shanshan Gao ◽  
Zhiqiang Wang ◽  
Junjie Wei ◽  
...  

Author(s):  
Jianlong Xiu ◽  
Tianyuan Wang ◽  
Ying Guo ◽  
Qingfeng Cui ◽  
Lixin Huang ◽  
...  

2019 ◽  
Vol 6 (6) ◽  
pp. 181902 ◽  
Author(s):  
Junchen Lv ◽  
Yuan Chi ◽  
Changzhong Zhao ◽  
Yi Zhang ◽  
Hailin Mu

Reliable measurement of the CO 2 diffusion coefficient in consolidated oil-saturated porous media is critical for the design and performance of CO 2 -enhanced oil recovery (EOR) and carbon capture and storage (CCS) projects. A thorough experimental investigation of the supercritical CO 2 diffusion in n -decane-saturated Berea cores with permeabilities of 50 and 100 mD was conducted in this study at elevated pressure (10–25 MPa) and temperature (333.15–373.15 K), which simulated actual reservoir conditions. The supercritical CO 2 diffusion coefficients in the Berea cores were calculated by a model appropriate for diffusion in porous media based on Fick's Law. The results show that the supercritical CO 2 diffusion coefficient increases as the pressure, temperature and permeability increase. The supercritical CO 2 diffusion coefficient first increases slowly at 10 MPa and then grows significantly with increasing pressure. The impact of the pressure decreases at elevated temperature. The effect of permeability remains steady despite the temperature change during the experiments. The effect of gas state and porous media on the supercritical CO 2 diffusion coefficient was further discussed by comparing the results of this study with previous study. Based on the experimental results, an empirical correlation for supercritical CO 2 diffusion coefficient in n -decane-saturated porous media was developed. The experimental results contribute to the study of supercritical CO 2 diffusion in compact porous media.


2021 ◽  
Vol 48 (1) ◽  
pp. 169-178
Author(s):  
Xiangguo LU ◽  
Bao CAO ◽  
Kun XIE ◽  
Weijia CAO ◽  
Yigang LIU ◽  
...  

2019 ◽  
Vol 12 (1) ◽  
Author(s):  
Pratik Prashant Pawar ◽  
Annamma Anil Odaneth ◽  
Rajeshkumar Natwarlal Vadgama ◽  
Arvind Mallinath Lali

Abstract Background Recent trends in bioprocessing have underlined the significance of lignocellulosic biomass conversions for biofuel production. These conversions demand at least 90% energy upgradation of cellulosic sugars to generate renewable drop-in biofuel precursors (Heff/C ~ 2). Chemical methods fail to achieve this without substantial loss of carbon; whereas, oleaginous biological systems propose a greener upgradation route by producing oil from sugars with 30% theoretical yields. However, these oleaginous systems cannot compete with the commercial volumes of vegetable oils in terms of overall oil yields and productivities. One of the significant challenges in the commercial exploitation of these microbial oils lies in the inefficient recovery of the produced oil. This issue has been addressed using highly selective oil capturing agents (OCA), which allow a concomitant microbial oil production and in situ oil recovery process. Results Adsorbent-based oil capturing agents were employed for simultaneous in situ oil recovery in the fermentative production broths. Yarrowia lipolytica, a model oleaginous yeast, was milked incessantly for oil production over 380 h in a media comprising of glucose as a sole carbon and nutrient source. This was achieved by continuous online capture of extracellular oil from the aqueous media and also the cell surface, by fluidizing the fermentation broth over an adsorbent bed of oil capturing agents (OCA). A consistent oil yield of 0.33 g per g of glucose consumed, corresponding to theoretical oil yield over glucose, was achieved using this approach. While the incorporation of the OCA increased the oil content up to 89% with complete substrate consumptions, it also caused an overall process integration. Conclusion The nondisruptive oil capture mediated by an OCA helped in accomplishing a trade-off between microbial oil production and its recovery. This strategy helped in realizing theoretically efficient sugar-to-oil bioconversions in a continuous production process. The process, therefore, endorses a sustainable production of molecular drop-in equivalents through oleaginous yeasts, representing as an absolute microbial oil factory.


Author(s):  
Boming Yu

In the past three decades, fractal geometry and technique have received considerable attention due to its wide applications in sciences and technologies such as in physics, mathematics, geophysics, oil recovery, material science and engineering, flow and heat and mass transfer in porous media etc. The fractal geometry and technique may become particularly powerful when they are applied to deal with random and disordered media such as porous media, nanofluids, nucleate boiling heat transfer. In this paper, a summary of recent advances is presented in the areas of heat and mass transfer in fractal media by fractal geometry technique. The present overview includes a brief summary of the fractal geometry technique applied in the areas of heat and mass transfer; thermal conductivities of porous media and nanofluids; nucleate boiling heat transfer. A few comments are made with respect to the theoretical studies that should be made in the future.


2001 ◽  
Vol 4 (06) ◽  
pp. 455-466 ◽  
Author(s):  
A. Graue ◽  
T. Bognø ◽  
B.A. Baldwin ◽  
E.A. Spinler

Summary Iterative comparison between experimental work and numerical simulations has been used to predict oil-recovery mechanisms in fractured chalk as a function of wettability. Selective and reproducible alteration of wettability by aging in crude oil at an elevated temperature produced chalk blocks that were strongly water-wet and moderately water-wet, but with identical mineralogy and pore geometry. Large scale, nuclear-tracer, 2D-imaging experiments monitored the waterflooding of these blocks of chalk, first whole, then fractured. This data provided in-situ fluid saturations for validating numerical simulations and evaluating capillary pressure- and relative permeability-input data used in the simulations. Capillary pressure and relative permeabilities at each wettability condition were measured experimentally and used as input for the simulations. Optimization of either Pc-data or kr-curves gave indications of the validity of these input data. History matching both the production profile and the in-situ saturation distribution development gave higher confidence in the simulations than matching production profiles only. Introduction Laboratory waterflood experiments, with larger blocks of fractured chalk where the advancing waterfront has been imaged by a nuclear tracer technique, showed that changing the wettability conditions from strongly water-wet to moderately water-wet had minor impact on the the oil-production profiles.1–3 The in-situ saturation development, however, was significantly different, indicating differences in oil-recovery mechanisms.4 The main objective for the current experiments was to determine the oil-recovery mechanisms at different wettability conditions. We have reported earlier on a technique that reproducibly alters wettability in outcrop chalk by aging the rock material in stock-tank crude oil at an elevated temperature for a selected period of time.5 After applying this aging technique to several blocks of chalk, we imaged waterfloods on blocks of outcrop chalk at different wettability conditions, first as a whole block, then when the blocks were fractured and reassembled. Earlier work reported experiments using an embedded fracture network,4,6,7 while this work also studied an interconnected fracture network. A secondary objective of these experiments was to validate a full-field numerical simulator for prediction of the oil production and the in-situ saturation dynamics for the waterfloods. In this process, the validity of the experimentally measured capillary pressure and relative permeability data, used as input for the simulator, has been tested at strongly water-wet and moderately water-wet conditions. Optimization of either Pc data or kr curves for the chalk matrix in the numerical simulations of the whole blocks at different wettabilities gave indications of the data's validity. History matching both the production profile and the in-situ saturation distribution development gave higher confidence in the simulations of the fractured blocks, in which only the fracture representation was a variable. Experimental Rock Material and Preparation. Two chalk blocks, CHP8 and CHP9, approximately 20×12×5 cm thick, were obtained from large pieces of Rørdal outcrop chalk from the Portland quarry near Ålborg, Denmark. The blocks were cut to size with a band saw and used without cleaning. Local air permeability was measured at each intersection of a 1×1-cm grid on both sides of the blocks with a minipermeameter. The measurements indicated homogeneous blocks on a centimeter scale. This chalk material had never been contacted by oil and was strongly water-wet. The blocks were dried in a 90°C oven for 3 days. End pieces were mounted on each block, and the whole assembly was epoxy coated. Each end piece contained three fittings so that entering and exiting fluids were evenly distributed with respect to height. The blocks were vacuum evacuated and saturated with brine containing 5 wt% NaCl+3.8 wt% CaCl2. Fluid data are found in Table 1. Porosity was determined from weight measurements, and the permeability was measured across the epoxy-coated blocks, at 2×10–3 µm2 and 4×10–3 µm2, for CHP8 and CHP9, respectively (see block data in Table 2). Immobile water saturations of 27 to 35% pore volume (PV) were established for both blocks by oilflooding. To obtain uniform initial water saturation, Swi, oil was injected alternately at both ends. Oilfloods of the epoxy-coated block, CHP8, were carried out with stock-tank crude oil in a heated pressure vessel at 90°C with a maximum differential pressure of 135 kPa/cm. CHP9 was oilflooded with decane at room temperature. Wettability Alteration. Selective and reproducible alteration of wettability, by aging in crude oil at elevated temperatures, produced a moderately water-wet chalk block, CHP8, with similar mineralogy and pore geometry to the untreated strongly water-wet chalk block CHP9. Block CHP8 was aged in crude oil at 90°C for 83 days at an immobile water saturation of 28% PV. A North Sea crude oil, filtered at 90°C through a chalk core, was used to oilflood the block and to determine the aging process. Two twin samples drilled from the same chunk of chalk as the cut block were treated similar to the block. An Amott-Harvey test was performed on these samples to indicate the wettability conditions after aging.8 After the waterfloods were terminated, four core plugs were drilled out of each block, and wettability measurements were conducted with the Amott-Harvey test. Because of possible wax problems with the North Sea crude oil used for aging, decane was used as the oil phase during the waterfloods, which were performed at room temperature. After the aging was completed for CHP8, the crude oil was flushed out with decahydronaphthalene (decalin), which again was flushed out with n-decane, all at 90°C. Decalin was used as a buffer between the decane and the crude oil to avoid asphalthene precipitation, which may occur when decane contacts the crude oil.


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