scholarly journals Volume reduction and water reclamation of reverse osmosis concentrate from coal chemical industry by forward osmosis with an osmotic backwash strategy

2020 ◽  
Vol 81 (12) ◽  
pp. 2674-2684
Author(s):  
Jiandong Lu ◽  
Xiuheng Wang
Keyword(s):  
Reverse Osmosis ◽  
Active Layer ◽  
Chemical Industry ◽  
Forward Osmosis ◽  
Feed Solution ◽  
Volume Reduction ◽  
Water Reclamation ◽  
High Concentration ◽  
Chemical Cleaning ◽  
Draw Solution

Abstract Coal chemical industry (CCI) generally utilizes reverse osmosis (RO) for water reclamation, which generates a highly concentrated stream containing refractory organic substances and high-concentration total dissolved solids (TDS). To address this issue, the present work focuses on volume reduction of RO concentrate (ROC) produced from CCI by forward osmosis (FO). We investigated the effects of membrane orientation and draw solution (DS) concentration on FO performance. Foulant removal was tested by using chemical cleaning, physical cleaning and osmotic backwash (OB). AL-FS (active layer facing feed solution) mode outcompeted AL-DS (active layer facing draw solution) mode, achieving a flux of 26.4 LMH, 92.5% water reclamation and energy consumption of 0.050 kWh·m−3 with 4 M NaCl as DS. The FO process was able to reject >98% SO42−, Mg2+and Ca2+, 92–98% Si and 33–55% total organic carbon (TOC). Ten-cycle (10 × 20 h) accelerated fouling test demonstrated approximately 30% flux decline in association with Si-containing foulants, which could be removed almost completely through OB with 97.1% flux recovery. This study provides a proof-of-concept demonstration of FO for volume reduction and water reclamation of ROC produced from CCI, making the treatment of ROC more efficient and more energy effective.

scholarly journals Removal of Chromium from Water Environment by Forward Osmosis System

2021 ◽  
Vol 333 ◽  
pp. 04007
Author(s):  
Minh Tuan Pham ◽  
Syouhei Nishihama ◽  
Kazuharu Yoshizuka
Keyword(s):  
Removal Efficiency ◽  
Active Layer ◽  
Water Environment ◽  
Forward Osmosis ◽  
Feed Solution ◽  
Operational Conditions ◽  
Draw Solution

Forward osmosis (FO) technology has been applied for removal of chromium (Cr) from water environment. Comparison of the removal efficiency of Cr(VI) and Cr(III) was investigated by changing several operational conditions. The pH of feed solution plays an important role in rejection of Cr. The Cr(VI) rejection was increased with increasing pH, while Cr(III) rejection was stable. It also demonstrated that the rejection of Cr was higher when the membrane active layer faces the feed solution compared to the rejection when the membrane active layer faces the draw solution.

scholarly journals Structural investigation and application of Tween 80-choline chloride self-assemblies as osmotic agent for water desalination

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Yasamin Bide ◽  
Marzieh Arab Fashapoyeh ◽  
Soheila Shokrollahzadeh
Keyword(s):  
Nonionic Surfactant ◽  
Choline Chloride ◽  
Water Flux ◽  
Forward Osmosis ◽  
Tween 80 ◽  
Average Diameter ◽  
Feed Solution ◽  
Water Desalination ◽  
Draw Solution ◽  
Osmotic Agent

AbstractForward osmosis (FO) process has been extensively considered as a potential technology that could minimize the problems of traditional water desalination processes. Finding an appropriate osmotic agent is an important concern in the FO process. For the first time, a nonionic surfactant-based draw solution was introduced using self-assemblies of Tween 80 and choline chloride. The addition of choline chloride to Tween 80 led to micelles formation with an average diameter of 11.03 nm. The 1H NMR spectra exhibited that all groups of Tween 80 were interacted with choline chloride by hydrogen bond and Van der Waals’ force. The influence of adding choline chloride to Tween 80 and the micellization on its osmotic activity was investigated. Despite the less activity of single components, the average water flux of 14.29 L m‒2 h‒1 was obtained using 0.15 M of Tween 80-choline chloride self-assembly as draw solution in the FO process with DI water feed solution. Moreover, various concentrations of NaCl aqueous solutions were examined as feed solution. This report proposed a possible preparation of nonionic surfactant-based draw solutions using choline chloride additive with enhanced osmotic activities that can establish an innovative field of study in water desalination by the FO process.

scholarly journals Using Reverse Osmosis Membrane at High Temperature for Water Recovery and Regeneration from Thermo-Responsive Ionic Liquid-Based Draw Solution for Efficient Forward Osmosis

Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 588
Author(s):  
Eiji Kamio ◽  
Hiroki Kurisu ◽  
Tomoki Takahashi ◽  
Atsushi Matsuoka ◽  
Tomohisa Yoshioka ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
High Temperature ◽  
Energy Saving ◽  
Osmotic Pressure ◽  
Reverse Osmosis ◽  
Forward Osmosis ◽  
Solution Temperature ◽  
Water Recovery ◽  
Temperature Dependent ◽  
Draw Solution

Forward osmosis (FO) membrane process is expected to realize energy-saving seawater desalination. To this end, energy-saving water recovery from a draw solution (DS) and effective DS regeneration are essential. Recently, thermo-responsive DSs have been developed to realize energy-saving water recovery and DS regeneration. We previously reported that high-temperature reverse osmosis (RO) treatment was effective in recovering water from a thermo-responsive ionic liquid (IL)-based DS. In this study, to confirm the advantages of the high-temperature RO operation, thermo-sensitive IL-based DS was treated by an RO membrane at temperatures higher than the lower critical solution temperature (LCST) of the DS. Tetrabutylammonium 2,4,6-trimethylbenznenesulfonate ([N4444][TMBS]) with an LCST of 58 °C was used as the DS. The high-temperature RO treatment was conducted at 60 °C above the LCST using the [N4444][TMBS]-based DS-lean phase after phase separation. Because the [N4444][TMBS]-based DS has a significantly temperature-dependent osmotic pressure, the DS-lean phase can be concentrated to an osmotic pressure higher than that of seawater at room temperature (20 °C). In addition, water can be effectively recovered from the DS-lean phase until the DS concentration increased to 40 wt%, and the final DS concentration reached 70 wt%. From the results, the advantages of RO treatment of the thermo-responsive DS at temperatures higher than the LCST were confirmed.

scholarly journals Application of forward osmosis in reusing the brackish concentrate produced in reverse osmosis plants with secondary treated wastewater as feed solution: a case study

2016 ◽  
Vol 6 (4) ◽  
pp. 533-543 ◽  
Author(s):  
W. D. Wang ◽  
M. Esparra ◽  
H. Liu ◽  
Y. F. Xie
Keyword(s):  
Reverse Osmosis ◽  
Membrane Fouling ◽  
Water Flux ◽  
Forward Osmosis ◽  
Pump Energy ◽  
Feed Solution ◽  
Disinfection Byproducts ◽  
Treated Wastewater ◽  
Membrane Flux ◽  
Flux Decline

This study evaluated the feasibility of forward osmosis (FO) in diluting and reusing the concentrate produced in a reverse osmosis (RO) plant in James City County, VA. Secondary treated wastewater (STW) was used as the feed solution. Findings indicated that pH had slight effects on the water flux of the FO membrane. As the concentration of total dissolved solids (TDS) in the concentrate was diluted from 12.5 to 1.0 g/L or the temperature in the STW decreased from 23 to 10 °C, the membrane flux decreased from 2.2 to 0.59 and 0.81 L/(m2 h), respectively. The FO membrane showed a good performance in the rejection of organic pollutants, with only a small part of the protein-like substances and disinfection byproducts permeating to the diluted concentrate. During an 89-hour continuous operation, water flux decline due to membrane fouling was not observed. Controlling the TDS in the second-stage FO effluent at 1.5 g/L, approximately 8.3% of the pump energy input could be saved. The consumption of groundwater was reduced from 22.7 × 103 to 10.6 × 103 m3/d. FO was proved to be an effective method in both diluting the discharged concentrate and reducing the energy consumption of RO.

scholarly journals Electricity generation and pollutants removal of landfill leachate by osmotic microbial fuel cells with different forward osmosis membranes

2021 ◽  
Author(s):  
Nan Jiang ◽  
Li Huang ◽  
Manhong Huang ◽  
Teng Cai ◽  
Jialing Song ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Active Layer ◽  
Landfill Leachate ◽  
Microbial Fuel Cells ◽  
Forward Osmosis ◽  
Feed Solution ◽  
Cellulose Triacetate ◽  
Ammonia Nitrogen ◽  
Pollutant Removal ◽  
Leachate Treatment

Abstract In this study, thin-film composite with embedded polyester screen, cellulose triacetate with a cast nonwoven and cellulose triacetate with embedded polyester screen (CTA-ES) were examined as the intermediate membranes in osmotic microbial fuel cells (OsMFCs). The reactors were fed with actual landfill leachate and the performance was studied in two operation modes: active layer facing draw solution and active layer facing feed solution (AL-FS). The OsMFC with CTA-ES exhibited the best energy generation (maximum power density: 0.44 W m-2) and pollutant removal efficiency (ammonia nitrogen: 70.12 ± 0.28%, total nitrogen: 74.04 ± 0.33%) in the AL-FS mode, which could be ascribed to the lowest internal resistance (236.75 ohm) and highest microbial richness. Pseudomonas was the highest proportion of microbial in OsMFCs. The results of this study has demonstrated the potential of OsMFCs for landfill leachate treatment.

Deliberate Salinization of Seawater for Desalination of Seawater

2017 ◽  
Vol 140 (3) ◽  
Author(s):  
Francisco J. Arias
Keyword(s):  
Volume Fraction ◽  
Feed Solution ◽  
Economic Feasibility ◽  
Seawater Desalination ◽  
High Concentration ◽  
Electrical Grid ◽  
Draw Solution ◽  
Cost Of Energy ◽  
Salt Deposits ◽  
The Cost

The basis of a novel method for seawater desalination is outlined. In this work, pressure-retarded osmosis (PRO) energy is obtained and used posteriorly for the reverse osmosis (RO) process for seawater desalination. Although PRO process coupled with an RO process has been studied in the past, however, in this work, there is a fundamental difference. Instead of bringing river or wastewaters with low salinity to the coast to be mixed with the seawater to run the PRO process, here is the seawater which is deliberately salinized. This technique has one important consequence, namely, that it is no longer required to be in places where rivers or wastewaters flow into the sea. This important difference eliminates this until now somehow paradoxical requirement if one considers that regions needing desalination are generally poor of water resources. On the other hand, it is not a coincidence that regions needing desalination plants are also regions with rich open salt deposits in the neighborhood; high evaporation, high concentration of salt deposits, and the need for freshwater are all of them directly correlated. Therefore, the idea proposed in the paper is consistent with the problem. The high evaporation in the region which is causing the need for desalination also is creating the solution to do this by using the salt deposits created. The economic feasibility of this method is preliminarily assessed in terms of the thermodynamic limits of extractable energy and then with the cost of the salt required to obtain this energy which is compared with the price from electrical grid. It was found that in order to reduce the amount of salt required for the process, and to make the cost of energy competitive, it is necessary to direct the hypersaline draw solution (draw solution) in a cyclic loop and to have the highest possible volume fraction for the nonsalinized solution (feed solution). Additional R&D is required to explore the possibilities of this concept.

Water recovery from sewage using forward osmosis

2011 ◽  
Vol 64 (7) ◽  
pp. 1443-1449 ◽  
Author(s):  
Kerusha Lutchmiah ◽  
Emile R. Cornelissen ◽  
Danny J. H. Harmsen ◽  
Jan W. Post ◽  
Keith Lampi ◽  
...  
Keyword(s):  
Renewable Energy ◽  
Reverse Osmosis ◽  
Energy Content ◽  
Water Flux ◽  
Forward Osmosis ◽  
Feed Solution ◽  
Water Recovery ◽  
High Quality ◽  
Mining Project ◽  
Quality Water

This research is part of the Sewer Mining project aimed at developing a new technological concept by extracting water from sewage by means of forward osmosis (FO). FO, in combination with a reconcentration system, e.g. reverse osmosis (RO) is used to recover high-quality water. Furthermore, the subsequent concentrated sewage (containing an inherent energy content) can be converted into a renewable energy (RE) source (i.e. biogas). The effectiveness of FO membranes in the recovery of water from sewage has been evaluated. Stable FO water flux values (>4.3 LMH) were obtained with primary effluent (screened, not treated) used as the feed solution. Fouling of the membrane was also induced and further investigated. Accumulated fouling was found to be apparent, but not irreversible. Sewer Mining could lead to a more economical and sustainable treatment of wastewater, facilitating the extraction of water and energy from sewage and changing the way it is perceived: not as waste, but as a resource.

Sustainable Water Reclamation from Different Feed Streams by Forward Osmosis Process Using Deep Eutectic Solvents as Reusable Draw Solution

2017 ◽  
Vol 56 (49) ◽  
pp. 14623-14632 ◽  
Author(s):  
Ashesh Mahto ◽  
Dibyendu Mondal ◽  
Veerababu Polisetti ◽  
Jitkumar Bhatt ◽  
Nidhi M. R ◽  
...  
Keyword(s):  
Forward Osmosis ◽  
Deep Eutectic Solvents ◽  
Water Reclamation ◽  
Draw Solution
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