Study on mitigating membrane fouling based on precursor and flocculant Alb matching in EC/O-UF system

2019 ◽  
Vol 80 (9) ◽  
pp. 1715-1724
Author(s):  
Fei Su ◽  
Ying-Hua Li ◽  
Wen-He Deng ◽  
Hai-Bo Li ◽  
Lei Yang ◽  
...  

Abstract One of the effective ways to remove halogenated disinfection by-products (DBPs) from drinking water is the application of ultrafiltration technology. However, membrane fouling is an important factor affecting the service life and treatment effect. In this study, the electrocoagulation/oxidation-ultrafiltration (EC/O-UF) process was used to remove the precursor substance that produced DBPs, i.e. dissolved organic matters (DOMs). Operating parameters were optimized from the matching of different flocculant morphology to low concentration DOM. The degree of membrane fouling was characterized by analyzing DOMs concentration and membrane flux. The results showed that the optimal conditions for the production of Alb were: current density 10 A/m2, hydraulic retention time 10 min, and initial pH 5.0–7.0. Under these conditions, the production of flocculant Alb could reach 58–61%, 94–97% DOMs were removed by EC/O-UF.

2013 ◽  
Vol 68 (10) ◽  
pp. 2301-2308 ◽  
Author(s):  
N. Kayaalp ◽  
C. Kinaci

In this study, various parameter manipulation methods, variable sludge retention time (SRT)–variable mixed liquor suspended solids (MLSS) concentration, constant SRT–variable MLSS concentration and variable SRT–constant MLSS concentration, were compared based on the interrelationships among the following membrane bioreactor operating parameters: SRT, food to microorganisms (biomass) (F/M) ratio, MLSS concentration, volumetric organic loading rate (OLR) and membrane flux. Although it is the most applied method, concurrent change of SRT (or F/M ratio) and MLSS concentration is not a good parameter manipulation method because it causes unnecessary changes in many other parameters such as viscosity, oxygen transfer efficiency and oxygen utilization rate. The method of constant SRT–variable MLSS concentration has similar disadvantages to the method of variable SRT–variable MLSS concentration. The best alternative parameter manipulation method to study membrane fouling is the method of variable SRT–constant MLSS concentration because this method eliminates unnecessary changes in other parameters. In addition, while changing OLR or hydraulic retention time (HRT), contrary to the common application, membrane flux should be kept constant because any change in flux overrides changes in other parameters. Accordingly, required changes in OLR or HRT should be made by adjusting membrane area rather than membrane flux.


2013 ◽  
Vol 14 (4) ◽  
pp. 393-398

The occurrence of trihalomethanes (THMs) was studied in the drinking water samples from urban water supply network of Karachi city that served more than 18 million people. Drinking water samples were collected from 58 locations in summer (May-August) and winter (November-February) seasons. The major constituent of THMs detected was chloroform in winter (92.34%) and summer (93.07%), while the other THMs determined at lower concentrations. Summer and winter concentrations of total THMs at places exceed the levels regulated by UEPA (80 μg l-1) and WHO (100 μg l-1). GIS linked temporal variability in two seasons showed significantly higher median concentration (2.5%-23.06%) of THMs compared to winter.


2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.


2003 ◽  
Vol 3 (5-6) ◽  
pp. 15-22
Author(s):  
P. Kouadio ◽  
M. Tétrault

Three colored surface water nanofiltration pilot-scale projects were conducted in the province of Quebec (eastern Canada), between November 2000 and March 2002, by the company H2O Innovation (2000) inc., for the municipalities of Lac Bouchette, Latulipe-et-Gaboury and Charlesbourg (now part of Quebec City). Results indicated that nanofiltration permeate quality has an advance on present drinking water regulation standard in Quebec, but important membrane fouling occurred. Fouling can be controlled by pretreatment and optimization of the operating conditions.


Author(s):  
Sara Díaz ◽  
Antonio N. Benítez ◽  
Sara Ramírez-Bolaños ◽  
Lidia Robaina ◽  
Zaida Ortega

AbstractThe aim of this work is the optimization of phenolic compound extraction from three by-products of banana crops (rachis, discarded banana, and banana’s pseudostem pulp), as a way to valorize them through a green extraction process. The influence of the temperature and aqueous ethanol concentration (Et-OH) on extract properties (total phenol content (TPC) and antioxidant activity) was firstly analyzed. 78 ℃ and ethanol concentrations close to 50% yielded the best results for the three materials. The equations obtained by the response surface methodology gave a satisfactory description of the experimental data, allowing optimizing the extraction conditions. Under optimized conditions, time influence was then assessed, although this parameter seemed not influence results. Among the three by-products, rachis extract (60% Et-OH, 78 ℃, and 30 min) presented the highest TPC (796 mg gallic acid/100 g of dried material) and antioxidant activity (6.51 mg Trolox equivalents/g of dried material), followed by discarded banana, and pseudostem pulp. Under the optimal conditions, experiments were performed at a larger scale, allowing to determine the extraction yields (EY) and to characterize the extracts. The highest EY was obtained for the rachis (26%), but the extract with the highest activity was obtained for discarded banana (50% Et-OH, 78 ℃, and 60 min), which presented a TPC of 27.26 mg/g extract corresponding to 54.59 mg Trolox equivalents/g extract. This study contributes to the valorization of banana crops residues as a source of polyphenolic compounds with bioactive functions that can be extracted under economic extraction conditions. Graphical abstract


Author(s):  
Ling Luo ◽  
Hui Zhong ◽  
Ye Yuan ◽  
Wenwang Zhou ◽  
Changming Zhong

Correction for ‘Membrane fouling characteristics of membrane bioreactors (MBRs) under salinity shock: extracellular polymeric substances (EPSs) and the optimization of operating parameters’ by Changming Zhong et al., Environ. Sci.: Water Res. Technol., 2021, DOI: .


Membranes ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 380
Author(s):  
Yan Chen ◽  
Huiping Li ◽  
Weihai Pang ◽  
Baiqin Zhou ◽  
Tian Li ◽  
...  

Nanofiltration (NF) is a promising post-treatment technology for providing high-quality drinking water. However, membrane fouling remains a challenge to long-term NF in providing high-quality drinking water. Herein, we found that coupling pre-treatments (sand filtration (SF) and ozone–biological activated carbon (O3-BAC)) and NF is a potent tactic against membrane fouling while achieving high-quality drinking water. The pilot results showed that using SF+O3-BAC pre-treated water as the feed water resulted in a lower but a slowly rising transmembrane pressure (TMP) in NF post-treatment, whereas an opposite observation was found when using SF pre-treated water as the feed water. High-performance size-exclusion chromatography (HPSEC) and three-dimensional excitation–emission matrix (3D-EEM) fluorescence spectroscopy determined that the O3-BAC process changed the characteristic of dissolved organic matter (DOM), probably by removing the DOM of lower apparent molecular weight (LMW) and decreasing the biodegradability of water. Moreover, amino acids and tyrosine-like substances which were significantly related to medium and small molecule organics were found as the key foulants to membrane fouling. In addition, the accumulation of powdered activated carbon in O3-BAC pre-treated water on the membrane surface could be the key reason protecting the NF membrane from fouling.


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