scholarly journals Coproduction of hydrogen and methane in a CSTR-IC two-stage anaerobic digestion system from molasses wastewater

2019 ◽  
Vol 79 (2) ◽  
pp. 270-277 ◽  
Author(s):  
Qiaoyan Li ◽  
Yongfeng Li
Keyword(s):  
Hydrogen Production ◽  
Production Rate ◽  
Methane Production ◽  
Oxygen Demand ◽  
Organic Loading Rate ◽  
Continuous Stirred Tank Reactor ◽  
Two Stage ◽  
Molasses Wastewater ◽  
Methane Production Rate ◽  
Stage Process

Abstract A continuous hydrogen and methane production system in a two-stage process has been investigated to increase energy recovery rate from molasses wastewater in this study. This system consisted of a continuous stirred-tank reactor for hydrogen production and an internal circulation (IC) reactor for methane production, and was studied under the influent organic loading rate (OLR) of 18, 24, 30 and 36kg COD/(m3·d) (COD: chemical oxygen demand). The maximum volumetric hydrogen production rate of 2.41 L/(L·d) was obtained at the OLR of 30kg COD/(m3·d) with a hydrogen content of 42%, and the maximum volumetric methane production rate of 2.4 L/(L·d) with a methane content of 74.45% was obtained at the OLR of 36kg COD/(m3·d) using the effluents of hydrogen fermentation as substrate. The maximum of 71.06% of the molasses wastewater energy was converted to biogas (hydrogen and methane) at the OLR of 30kg COD/(m3·d).

scholarly journals Assessment of Single- vs. Two-Stage Process for the Anaerobic Digestion of Liquid Cow Manure and Cheese Whey

Energies ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5423
Author(s):  
Margarita Andreas Dareioti ◽  
Aikaterini Ioannis Vavouraki ◽  
Konstantina Tsigkou ◽  
Michael Kornaros
Keyword(s):  
Anaerobic Digestion ◽  
Production Rate ◽  
Methane Production ◽  
Cheese Whey ◽  
Biogas Production ◽  
Single Stage ◽  
Cow Manure ◽  
Two Stage ◽  
Methane Production Rate ◽  
Stage Process

The growing interest in processes that involve biomass conversion to renewable energy, such as anaerobic digestion, has stimulated research in this field in order to assess the optimum conditions for biogas production from abundant feedstocks, like agro-industrial wastes. Anaerobic digestion is an attractive process for the decomposition of organic wastes via a complex microbial consortium and subsequent conversion of metabolic intermediates to hydrogen and methane. The present study focused on the exploitation of liquid cow manure (LCM) and cheese whey (CW) as noneasily and easily biodegradable sources, respectively, using continuous stirred-tank reactors for biogas production, and a comparison was presented between single- and two-stage anaerobic digestion systems. No significant differences were found concerning LCM treatment, in a two-stage system compared to a single one, concluding that LCM can be treated by implementing a single-stage process, as a recalcitrant substrate, with the greatest methane production rate of 0.67 L CH4/(LR·d) at an HRT of 16 d. On the other hand, using the easily biodegradable CW as a monosubstrate, the two-stage process was considered a better treatment system compared to a single one. During the single-stage process, operational problems were observed due to the limited buffering capacity of CW. However, the two-stage anaerobic digestion of CW produced a stable methane production rate of 0.68 L CH4/(LR·d) or 13.7 L CH4/Lfeed, while the total COD was removed by 76%.

Co-production of hydrogen and methane from herbal medicine wastewater by a combined UASB system with immobilized sludge (H2 production) and UASB system with suspended sludge (CH4 production)

2015 ◽  
Vol 73 (1) ◽  
pp. 130-136 ◽  
Author(s):  
Caiyu Sun ◽  
Ping Hao ◽  
Bida Qin ◽  
Bing Wang ◽  
Xueying Di ◽  
...  
Keyword(s):  
Herbal Medicine ◽  
Hydrogen Production ◽  
Production Rate ◽  
Methane Production ◽  
Oxygen Demand ◽  
H2 Production ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Organic Loading ◽  
Production Of Hydrogen

An upflow anaerobic sludge bed (UASB) system with sludge immobilized on granular activated carbon was developed for fermentative hydrogen production continuously from herbal medicine wastewater at various organic loading rates (8–40 g chemical oxygen demand (COD) L−1 d−1). The maximum hydrogen production rate reached 10.0 (±0.17) mmol L−1 hr−1 at organic loading rate of 24 g COD L−1 d−1, which was 19.9% higher than that of suspended sludge system. The effluents of hydrogen fermentation were used for continuous methane production in the subsequent UASB system. At hydraulic retention time of 15 h, the maximum methane production rate of 5.49 (±0.03) mmol L−1 hr−1 was obtained. The total energy recovery rate by co-production of hydrogen and methane was evaluated to be 7.26 kJ L−1 hr−1.

Continuous hydrogen and methane production in a two-stage cheese whey fermentation system

2011 ◽  
Vol 64 (2) ◽  
pp. 367-374 ◽  
Author(s):  
C. B. Cota-Navarro ◽  
J. Carrillo-Reyes ◽  
G. Davila-Vazquez ◽  
F. Alatriste-Mondragón ◽  
E. Razo-Flores
Keyword(s):  
Methane Production ◽  
Cheese Whey ◽  
Continuous Production ◽  
Uasb Reactor ◽  
Organic Loading Rate ◽  
Stable Operation ◽  
Operational Parameters ◽  
Two Stage ◽  
Production Of Hydrogen ◽  
Stage Process

The feasibility of integrating biological hydrogen and methane production in a two-stage process using mixed cultures and cheese whey powder (CWP) as substrate was studied. The effect of operational parameters such as hydraulic retention time (HRT) and organic loading rate (OLR) on the volumetric hydrogen (VHPR) and methane (VMPR) production rates was assessed. The highest VHPR was 28 L H2/L/d, obtained during stable operation in a CSTR at HRT and OLR of 6 h and 142 g lactose/L/d, respectively. Moreover, hydrogen (13 L/L/d) was produced even at HRT as low as 3.5 h and OLR of 163 g lactose/L/d, nonetheless, the reactor operation was not stable. Regarding methane production in an UASB reactor, the acidified effluent from the hydrogen-producing bioreactor was efficiently treated obtaining COD removals above 90% at OLR and HRT of 20 g COD/L/d and 6 h, respectively. The two-stage process for continuous production of hydrogen and methane recovered over 70% of the energy present in the substrate. This study demonstrated that hydrogen production can be efficiently coupled to methane production in a two-stage system and that CWP is an adequate substrate for energy production.

Rapid Start-Up of Ethanol-Type Fermentation in Biological Hydrogen Production Reactor from Molasses Wastewater

2010 ◽  
Vol 113-116 ◽  
pp. 623-631
Author(s):  
Li Ran Yue ◽  
Yong Feng Li ◽  
Wei Han ◽  
Jing Li Xu ◽  
Hong Chen ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Ph Value ◽  
Anaerobic Fermentation ◽  
Oxygen Demand ◽  
Low Ph ◽  
Continuous Stirred Tank Reactor ◽  
Fermentation Products ◽  
Biological Hydrogen Production ◽  
Molasses Wastewater ◽  
Start Up

Research on anaerobic fermentation biohydrogen production from molasses wastewater in a continuous stirred-tank reactor (CSTR) was conducted. Emphasis was focused on the rapid start-up of ethanol-type fermentation in biological hydrogen production reactor. It was found that an initial biomass of 17.71 g/L, temperature of 35°C±1°C, hydraulic retention time (HRT) of 6 h, the reactor could start-up the ethanol-type fermentation at the range of 2000-4000 mg/L and at pH from 3.23 to 4.39 in 12 days with COD (chemical oxygen demand), respectively. The content of hydrogen was 45.77% in the fermentation biogas and the COD removal was 8%. As the hydrogen production system experienced low pH (3.23-4.0), the ethanol-produce bacterial can resume easier compared with other fermentation bacteria which are difficult to restore. In addition, when the pH value ranged from 4.0 to 4.63, the hydrogen production increased with the content of ethanol in liquid fermentation products increased. However, it was detected that the yield of hydrogen decreased with a high content of ethanol in the pH value ranged from 3.23 to 4.0, which demonstrated pH value played the most important role on hydrogen production within low pH.

Continuous Biohydrogen Production with CSTR Reactor under High Organic Loading Rate Condition

2013 ◽  
Vol 864-867 ◽  
pp. 225-228
Author(s):  
Zhi Qin ◽  
Qing Qin ◽  
Ying Yang
Keyword(s):  
Hydrogen Production ◽  
Production Rate ◽  
Loading Rate ◽  
Ph Value ◽  
Biogas Production ◽  
Organic Loading Rate ◽  
Organic Loading ◽  
Molasses Wastewater ◽  
Biogas Production Rate ◽  
Fermentative Products

A continuous stirred-tank reactor (CSTR) was used to produce biohydrogen gas from organic wastewater. The hydrogen producing reactor was operated under high organic loading rate of 21 kgCOD/m3·d, and molasses wastewater was used as substrate. Hydrogen production rate, pH value, sugar utilizing rate and fermentative products in effluent were investigated in continuous fermentation. When Organic Loading Rate was controlled at 21 kgCOD/m3·d, the average concentrations of acetic acid, ethanol, propionic acid, butyric acid and valeric acid in liquid fermentative products were 833, 748, 482, 484 and 256mg/L respectively. There is not any fermentation product playing dominant role absolutely in hydrogen production fermentation. The pH value in effluent was about 4.7~4.9, the average utilizing rate of sugar reached 92.1%, most of the sugar in molasses wastewater was utilized. The biogas production rate in hydrogen producing fermentation was from 21.2 to 27.1L/d, and the average biogas production rate was about 25.1L/d. The hydrogen content was about 37%.

scholarly journals Two-Stage Anaerobic Co-digestion of Landfill Leachate and Starch Wastes Using Anaerobic Biofilm Reactor for Methane Production

2019 ◽  
Vol 15 (1) ◽  
pp. 53-70
Author(s):  
◽  
Ulfa Triovanta ◽  
Ridho Rinaldi
Keyword(s):  
Landfill Leachate ◽  
Methane Production ◽  
Loading Rate ◽  
Biofilm Reactor ◽  
Single Stage ◽  
Organic Loading Rate ◽  
Volatile Solid ◽  
Two Stage ◽  
Stage Process ◽  
Bod Removal

Abstract The study aims to evaluate two-stage anaerobic co-digestion of leachate and starch waste using anaerobic biofilm bioreactor to enhance methane production. The anaerobic digestion process was operated under the mesophilic condition at 35 ± 1 °C. Hydraulic retention time (HRT) applied to the acidogenesis and methanogenesis reactors were 5 and 25 days, respectively. The organic loading rate (OLR) used in the process of acidogenesis was 2.91 gram volatile solid /L.day, while methanogenesis was 0.58 gram volatile solid (VS) per liter per day. Results showed that two-stage process using biofilm was an effective method for operating anaerobic co-digestion of starch waste and landfill leachate in which the system produced higher methane yield at 125.11 mL methane (CH4) per gram volatile solid (VS) added (mL.CH4/g.VS.added) in comparison to the single-stage process (20.57 mL CH4/g.VS.added) and two-stage process (77.60 mL CH4/g.VS.added) without using biofilm. Two-stage process using biofilm also effectively reduced organic matters in the culture in which the system reached 61% BOD removal in comparison to the single-stage process and two-stage process without biofilm that only had 27.6 and 39.3% BOD removal, respectively. This study suggested that the two-stage process using biofilm would be the preferred technique for treating starch waste and landfill leachate.

scholarly journals Διεργασίες ενεργειακής αξιοποίησης γλυκερόλης με παραγωγή βιοαερίου, βιοϋδρογόνου ή/και ηλεκτρικού ρεύματος με μικροβιακή κυψελίδα καυσίμου

2011 ◽  
Author(s):  
Θεόφιλος Βλάσσης
Keyword(s):  
Anaerobic Digestion ◽  
Hydrogen Production ◽  
Electric Current ◽  
Production Rate ◽  
Methane Production ◽  
Continuous Production ◽  
Maximum Yield ◽  
Glycerol Concentration ◽  
Production Of Hydrogen ◽  
Methane Production Rate

This study focused on the valorization of glycerol which is an important by-product of the biodiesel industry corresponding to 10 % of the produced biodiesel amount. This fact contributed to the increase of the global production of biodiesel, to a point at which the industries which traditionally consumed glycerol could not absorb. This situation should be overcome through new outlets on glycerol exploitation. Usually, glycerol is treated by chemical processes in order to form new chemical compounds.On the other side, biochemical processes like anaerobic digestion and fermentation or the technology of microbial fuel cells could potentially transform glycerol into methane, hydrogen and electric current respectively. These processes, which are the subject of this Ph.D, are preferable to their chemical counterparts due to the low energy demand and reduced environmental pollution.The anaerobic digestion process was conducted in a conventional CSTR reactor and in a high rate reactor, the PABR. The experiments dealt with the effect of glycerol concentration on the methane production rate. The obtained results showed that the CSTR could not withstand organic loadings above 0.25 g COD/L/d, however PABR operated at organic loading 10 times higher than CSTR such as 3 g COD/L/d and resulted to a methane production rate of 0.982 ± 0.089 L/L/d. A model was developed for both the CSTR and the PABR digesters. Fermentative hydrogen production was conducted successfully in batch reactors. The effect of the initial glycerol concentration and initial pH on hydrogen production was studied. A maximum yield, 27.3 mL H2/ g COD glycerol, was obtained when glycerol concentration was 8.3 g COD/L and the pH 6.5. Moreover, the fermentation of glycerol took place in a CSTR in order to investigate the continuous production of hydrogen. Hydrogen production was unstable, possibly due to the washout of proper biomass from the reactor.For electricity generation from glycerol, an H-type microbial fuel cell was used in batch mode. The effect of the initial glycerol on the electric current was studied. A maximum Coulombic efficiency (CE) 34.09% was obtained at a glycerol concentration of 3.2 g COD/L. A further increase of glycerol drove to a drop of the CE. Probably, this happened since the electrochemical microorganisms were inhibited by the high glycerol concentration.

scholarly journals Characterization and anaerobic digestion of highly concentrated Mexican wine by-products and effluents

2020 ◽  
Vol 81 (1) ◽  
pp. 190-198 ◽  
Author(s):  
M. Vital-Jacome ◽  
M. Cazares-Granillo ◽  
J. Carrillo-Reyes ◽  
G. Buitron
Keyword(s):  
Anaerobic Digestion ◽  
Oxygen Demand ◽  
Anaerobic Treatment ◽  
Single Stage ◽  
Organic Load ◽  
Organic Loading Rate ◽  
Two Stage ◽  
Wine Production ◽  
Stage Process ◽  
By Products

Abstract Wine production has increased in recent years, especially in developing countries such as Mexico. This increase is followed by an increase of winery effluents that must be treated to avoid environmental risks. However, little information is available about the characteristics of these effluents and the possible treatments. This paper aimed to characterize the effluents and by-products generated by the Mexican winery industry and to evaluate the performance and stability of the anaerobic treatment using a single-stage and a two-stage process. Results showed that the winery effluents had a high content of biodegradable organic matter, with chemical oxygen demand (COD) values ranging from 221 to 436 g COD/L. The single-stage anaerobic process was able to treat an organic loading rate of 9.6 kg COD/(m3 d); however, it was unstable and highly dependent on the addition of bicarbonate alkalinity (0.31 g NaHCO3/g COD removed). The two-stage process was more stable working at a higher organic load (12.1 kg COD/(m3 d)) and was less dependent on the addition of bicarbonate (0.17 g NaHCO3/g COD removed). The results highlight the potential of the winery effluents to produce methane through anaerobic digestion in a two-stage process, making wine production more sustainable.

Sign in / Sign up

Export Citation Format

Share Document