scholarly journals Combined electrocoagulation and electro-oxidation of industrial textile wastewater treatment in a continuous multi-stage reactor

2017 ◽  
Vol 76 (9) ◽  
pp. 2515-2525 ◽  
Author(s):  
Edison GilPavas ◽  
Paula Arbeláez-Castaño ◽  
José Medina ◽  
Diego A. Acosta

Abstract A combined electrocoagulation (EC) and electrochemical oxidation (EO) industrial textile wastewater treatment potential is evaluated in this work. A fractional factorial design of experiment showed that EC current density, followed by pH, were the most significant factors. Conductivity and number of electrooxidation cells did not affect chemical oxygen demand degradation (DCOD). Aluminum and iron anodes performed similarly as sacrificial anodes. Current density, pH and conductivity were chosen for a Box–Behnken design of experiment to determine optimal conditions to achieve a high DCOD minimizing operating cost (OC). The optimum to achieve a 70% DCOD with an OC of USD 1.47/m3 was: pH of 4, a conductivity of 3.7 mS/cm and a current density of 4.1 mA/cm2. This study also shows the applicability of a combined EC/EO treatment process of a real complex industrial wastewater.

2018 ◽  
Vol 55 (6A) ◽  
pp. 193-199
Author(s):  
Nguyen Duc Dat Duc

To produce quality textile products, many stable synthetic dyes are invented. However, textile wastewater discharged into the environment contains a large amount of dyes which are bio-recalcitrants and stable to heat and solar radiation. These toxic contaminants impact negatively the environment for a long time and poison plants, animals, and human. In this study, Heterogeneous Electro Fenton  process with Fe3O4-Mn3O4 as a catalyst was used for textile wastewater treatment. Graphite electrodes were chosen for their stability and good conductivity. Three operating factors greatly affected the removal efficiency are current density, pH and catalyst dosage. Response surface methodology was applied to find empirical mathematical models for these factors, then find an accordant operating condition for treatment which provides high removal efficiency and low operating cost. Investigated ranges scaled in previous studies were: current density (10 – 20 mA/cm2), pH (3 – 5), and catalyst dosage (0.5 – 1.5 g/l). At current density of 17.03 mA/cm2, pH of 3.77, catalyst dosage of 1.17 g/l, the treatment reached its optimum condition, COD and Color removal efficiencies were 93.3 % and 99.2 %, respectively, where COD and Color values in the effluent are 56 mg/l and 16 Pt-Co. 


2018 ◽  
Vol 56 (2C) ◽  
pp. 193-199
Author(s):  
Nguyen The Phong

To produce quality textile products, many stable synthetic dyes are invented. However, textile wastewater discharged into the environment contains a large amount of dyes which are bio-recalcitrants and stable to heat and solar radiation. These toxic contaminants impact negatively the environment for a long time and poison plants, animals, and human. In this study, Heterogeneous Electro Fenton  process with Fe3O4-Mn3O4 as a catalyst was used for textile wastewater treatment. Graphite electrodes were chosen for their stability and good conductivity. Three operating factors greatly affected the removal efficiency are current density, pH and catalyst dosage. Response surface methodology was applied to find empirical mathematical models for these factors, then find an accordant operating condition for treatment which provides high removal efficiency and low operating cost. Investigated ranges scaled in previous studies were: current density (10 – 20 mA/cm2), pH (3 – 5), and catalyst dosage (0.5 – 1.5 g/l). At current density of 17.03 mA/cm2, pH of 3.77, catalyst dosage of 1.17 g/l, the treatment reached its optimum condition, COD and Color removal efficiencies were 93.3 % and 99.2 %, respectively, where COD and Color values in the effluent are 56 mg/l and 16 Pt-Co. 


Author(s):  
Fagbenro Oluwakemi Kehinde ◽  
Salem S. Abu Amr ◽  
Hamidi Abdul Aziz

As textile and dyeing industries increase, pollution due to effluent discharges from the same industries also increase and become of great concern to a healthy environment. In an attempt to understand the generation and treatment of textile wastewater, this chapter discusses the processes from which textiles are made, items of importance that are used in the production process which may account for the characteristics of the wastewater and persulfate, applied in the treatment of textile wastewater. Although these wastewaters are generally characterized by color, fluctuating pH, heat, salts, suspended solids (SS), the presence of metal ions, biological oxidation demand (BOD), and chemical oxygen demand (COD), color is the most obvious. The presence of color in the effluents from textile dyeing and finishing is due to the inefficient dyeing processes, resulting in unfixed forms of the dyestuff. To achieve the primary objective of obtaining a clean environment, there is a need for continuous monitoring of textile wastewater discharges, of which major concern is color.


2018 ◽  
Vol 20 (3) ◽  
pp. 449-457

<p>This study explored the best-operating conditions for a novel electrocoagulation (EC) reactor with the rotating anode for textile wastewater treatment. The influence of operating parameters like inter-electrode distance (IED), current density (CD), temperature, pH, operating time (RT), and rotation speed on the removal efficiency of the contaminant was studied. A comparative study was done using conventional model with static electrodes in two phases under same textile wastewater The findings revealed that the optimal conditions for textile wastewater treatment were attained at RT = 10 min, CD = 4 mA/cm2, rotation speed = 150 rpm, temperature = 25oC, IED = 1cm, and pH = 4.57. The removal efficiencies of colour, biological oxygen demand (BOD), turbidity, chemical oxygen demand (COD), and total suspended solid (TSS) were 98.50%, 95.55%, 96%, 98% and 97.10% within the first 10 min of the reaction. The results of the experiment reveal that the newly designed reactor incorporated with cathode rings and rotated anode impellers provide a superior treatment efficiency within a short reaction time. The novel EC reactor with a rotating anode significantly enhanced textile wastewater treatment compared to the conventional model. The values of adsorption and passivation resistance validated the pollutants removal rate.</p>


2009 ◽  
Vol 60 (9) ◽  
pp. 2261-2270 ◽  
Author(s):  
M. Kobya ◽  
E. Demirbas ◽  
A. Akyol

Electrocoagulation (EC) method with iron electrode was used to treat the textile wastewater in a batch reactor. Iron electrode material was used as a sacrificial electrode in monopolar parallel mode in this study. The removal efficiencies of the wastewater by EC were affected by initial pH of the solution, current density, conductivity and time of electrolysis. Under the optimal experimental conditions (initial pH 6.9, current density of 10 mA/cm2, conductivity of 3,990 μS/cm, and electrolysis time of 10 min), the treatment of textile wastewater by the EC process led to a removal capacity of 78% of chemical oxygen demand (COD) and 92% of turbidity. The energy and electrode consumptions at the optimum conditions were calculated to be 0.7 kWh/kg COD (1.7 kWh/m3) and 0.2 kgFe/kg COD (0.5 kgFe/m3), respectively. Moreover, the operating cost was calculated as 0.2 €/kg removed COD or 0.5 €/m3 treated wastewater. Zeta potential measurement was used to determine the charge of particle formed during the EC which revealed that Fe(OH)3 might be responsible for the EC process.


2018 ◽  
Vol 5 (4) ◽  
pp. 241-248 ◽  
Author(s):  
Zabihollah Yousefi ◽  
Ali Zafarzadeh ◽  
Abdolaziz Ghezel

Background: Electro-oxidation is developed as an electrochemical method to overcome the problems of the conventional decolorization technologies and is an appropriate alternative for the treatment of colored wastewater from various industries. The purpose of this study was to evaluate the efficiency of the electrochemical oxidation process in removal of chemical oxygen demand (COD) and Acid Red 18 (AR18) dye from aqueous solutions. Methods: In this research, a laboratory scale of electro-coagulation reactor for the treatment of synthetic wastewater was made and studied. The effects of different variables including pH, current density, dye concentration, and electrolysis time were investigated. The experiment steps were designed by DesignExpert 10 software using the selected variables. Finally, the dye and COD analysis was performed by spectrophotometer. The optimization was performed using Taguchi fractional factorial design during the removal of dye and COD. Results: Maximum removal of dye (89%) and COD (72.2%) were obtained at pH=3, current density=20 mA/cm2 , initial dye concentration=100 mg/L, and reaction time=45 min. ANOVA test showed a significant relationship between statistical model and test data. Also, the results indicate that the distribution of the residues of the model was normal. Conclusion: By designing experiments through Taguchi method, the removal process will be optimized and by decreasing the number of experiments, the optimal conditions for pollutant removal will be prepared. The results suggest that the Electro-oxidation system is a very suitable technique for the enhancement of wastewater treatment.


1994 ◽  
Vol 30 (3) ◽  
pp. 255-263 ◽  
Author(s):  
Frank Gähr ◽  
Frank Hermanutz ◽  
Wilhelm Oppermann

The German textile industry is challenged by the introduction of new governmental regulations in the field of textile wastewater treatment This causes a large increase of water costs in comparison with other European countries. Many economic experts even see Germany seriously endangered as a place of textile production, however there are also opportunities with the development of high performance cleaning technologies as a result of these governmental measures. In particular the required separate treatment of selected wastewaters of different fmishing processes bas some good perspectives since specialized wastewater techniques can be applied efficiently. For instance the separation of unfixed reactive dyes is the ideal basis for ozone oxidation. Ozonation being a sludge-free method to decompose dyestuff, fmishing products, and other organic materials is of increasing importance because of the limited space for disposal of sludges. Other advantages of ozone treatment are the improvement of biodegradability, reduction of aromatic and halogenated organic compounds and also a significant decrease of chemical oxygen demand. The ozonation of textile wastewaters in combination with inexpensive biological processes has the potential to play a major role in the future. Partial replacement of coagulation/precipitation can be expected.


2018 ◽  
Vol 14 (2) ◽  
pp. 257-262
Author(s):  
Mohd Fahmi Muhammad Mubarak ◽  
Muhamad Hanif Md Nor ◽  
Muhamad Firdaus Sabaruddin ◽  
Hui Han Bay ◽  
Chi Kim Lim ◽  
...  

One of the most abundant dyes that are used extensively in the textile manufacturing are azo dyes, which may endanger water bodies since incomplete breakdown of dyes may cause mutagenic and carcinogenic compounds to persist. In this study, BAC-ZS, bacterial mixed culture consisting of three acclimatised decolourising bacteria were grown as biofilm onto macrocomposites. Different time duration between 3 to 14 days of biofilm development was studied to determine the density of biofilm attached onto macrocomposites. Sequencing batch reactors (SBRs) were set up for raw textile wastewater treatment to investigate the effectiveness of the treatment with and without the presence of biofilm (control). The treatment was performed under facultative anaerobic-aerobic condition for 20 days continuously with 48-hour of hydraulic retention time (HRT) cycle (consisting both conditions). Colour and chemical oxygen demand (COD) were monitored throughout the treatment process. Results showed that the colour and COD removal by the developed biofilm were 78.6 ± 1.4% and 76.4 ± 1.12% from initial values of 1400 ADMI and 660 mg/L, respectively while only 47.9 ± 0.9% colour and 38.0 ± 1.5% COD removal for the control. In conclusion, the biofilm of BAC-ZS mixed culture coated onto macrocomposites showed potential applications in the treatment of raw textile wastewater.


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