Adsorption of methyl orange from aqueous solution using chitosan/diatomite composite

2017 ◽  
Vol 75 (7) ◽  
pp. 1633-1642 ◽  
Author(s):  
Peng Zhao ◽  
Runhu Zhang ◽  
Jianglin Wang
Keyword(s):  
Aqueous Solution ◽  
Methyl Orange ◽  
Removal Rate ◽  
Ph Effect ◽  
Aqueous Media ◽  
Freundlich Isotherm ◽  
Electron Microscopy Analysis ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption And Desorption Performance

A novel chitosan/diatomite composite was prepared by a simple mixture in the mass ratio to remove methyl orange (MO) from aqueous media in this study. The composite adsorbent was characterized by Fourier transform infrared spectroscopy and scanning electron microscopy analysis. The parameters to influence the adsorption of MO were studied under such conditions as kinetics, adsorption isotherm, pH effect, and thermodynamics. The results revealed that adsorption of MO was initially rapid and the equilibrium time was reached after 40 min. The optimal value of the pH was 5.0 for better adsorption. The equilibrium data were well fitted to the Langmuir isotherm compared to the Freundlich isotherm, and exhibited the highest capacity and a removal rate of 88.37% under an initial dye concentration of 50 mg/L. The kinetic data were well described by the pseudo-second order model. The thermodynamic calculations revealed that the sorption was viable, spontaneous, and exothermic under the conditions studied. In addition, the chitosan/diatomite composite had good adsorption and desorption performance with respect to reusability after six cycles. These results showed that the chitosan/diatomite could be considered as a potential adsorbent for the removal of MO in aqueous solution.

scholarly journals Adsorption of As(V) from Aqueous Solution on Chitosan-Modified Diatomite

2020 ◽  
Vol 17 (2) ◽  
pp. 429 ◽  
Author(s):  
Qintao Yang ◽  
Liang Gong ◽  
Lili Huang ◽  
Qinglin Xie ◽  
Yijian Zhong ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Removal Efficiency ◽  
Ph Effect ◽  
Freundlich Isotherm ◽  
Xrd Analysis ◽  
Optimal Value ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption Desorption ◽  
Modified Diatomite

A novel chitosan (CS)-modified diatomite (Dt) was prepared by a simple mixture in the mass ratio to remove As(V) from aqueous solution in this research. The CS-modified Dt adsorbent was characterized by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and X-ray powder diffraction (XRD) analysis. The parameters to influence the adsorption of As(V) ion were studied under such conditions as kinetics, adsorption isotherm, and pH effect. The results revealed that adsorption of As(V) was initially rapid and the equilibrium time was reached after 40 min. The optimal value of the pH was 5.0 for better adsorption. The equilibrium data were well fitted to the Langmuir isotherm compared to the Freundlich isotherm, and exhibited the highest capacity and removal efficiency of 94.3% under an initial As(V) concentration of 5 mg/L. The kinetic data were well described by the pseudo-second-order model. In addition, 0.1 M NaOH has the best desorption efficiency of As(V) adsorbed on CS-modified Dt, and the removal efficiency of As(V) was still higher than 90% when after six adsorption-desorption cycles. These results showed that the CS-modified Dt could be considered as a potential adsorbent for the removal of As(V) in aqueous solution.

Study on Adsorption of U(VI) From Aqueous Solution by Activated MgO

2017 ◽  
Author(s):  
Qingqing Liu ◽  
Xiaoyan Li
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Adsorption Process ◽  
Removal Rate ◽  
Freundlich Isotherm ◽  
Batch System ◽  
15Mg Dose ◽  
Pseudo Second Order ◽  
Ft Ir ◽  
Kinetics Of

The activated MgO was synthesized by microwave homo-precipitator method and characterized by SEM, EDS and FT-IR methods. It was used to adsorption of U(VI) from aqueous solution with batch system. The paper discussed the effect of pH, temperature, contact time, adsorbent dose and initial U(VI) concentration on the adsorption. The results showed that activated MgO has good adsorption capacity for U(VI), the removal rate and equilibrium adsorption capacity reached 83.5% and 84.04mg·g−1 at pH 5.0, 15mg dose and 313K,respectively. The adsorption kinetics of U(VI) onto activated MgO were better fitted with pseudo-second-order kinetic.The adsorption isotherm data were fitted well to Freundlich isotherm model.The thermodynamic parameters showed that the adsorption process is endothermic and spontaneous.

scholarly journals Fabrication of magnetic lignin-based adsorbent for removal of methyl orange dye from aqueous solution

BioResources ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. 5436-5449
Author(s):  
Chao Cao ◽  
Lupeng Shao ◽  
Lucian A. Lucia ◽  
Yu Liu
Keyword(s):  
Aqueous Solution ◽  
Methyl Orange ◽  
Influence Factors ◽  
Maximum Adsorption Capacity ◽  
X Ray Diffraction ◽  
Adsorption Mechanisms ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Methyl Orange Dye ◽  
Adsorption Desorption

Magnetic lignin-based adsorbent (MLA) was successfully fabricated to remove methyl orange dye from aqueous solution. The synthesized MLA was characterized by means of Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). In the process of adsorption, influence factors and recycling performance were considered, and the adsorption mechanisms such as isotherm and kinetics were investigated. The result showed that the equilibrium data was consisted with the Langmuir model with a maximum adsorption capacity of 85.0 mg/g. The adsorption kinetics followed a pseudo-second-order model. Based the adsorption performance, MLA showed good recyclability. Therefore, these results demonstrate that MLA could offer a great potential as an efficient and reusable adsorbent in the wastewater treatments.

Synthesis and characterization of a novel magnetic biochar from sewage sludge and its effectiveness in the removal of methyl orange from aqueous solution

2017 ◽  
Vol 75 (7) ◽  
pp. 1539-1547 ◽  
Author(s):  
Jing Zhang ◽  
Mao Liu ◽  
Tao Yang ◽  
Kai Yang ◽  
Hongyu Wang
Keyword(s):  
Aqueous Solution ◽  
Methyl Orange ◽  
Sewage Sludge ◽  
Kinetic Studies ◽  
Second Order ◽  
Environmental Cleanup ◽  
Magnetic Biochar ◽  
Freundlich Isotherms ◽  
Equilibrium Data ◽  
Pseudo Second Order

A novel magnetic biochar from sewage sludge (MSBC) using SrFe12O19 as magnetic substrate was successfully synthesized under high-temperature and oxygen-free conditions. Several techniques and methodologies (X-ray diffraction, Fourier transform infrared spectroscopy and vibrating sample magnetometer) were used to determine the surface functional groups and physicochemical properties of MSBC, which showed that the MSBC combined the features of both SrFe12O19 and sludge biochar (SBC). And then the adsorption behavior of methyl orange (MO) from aqueous solution onto the MSBC was investigated. And the influence of variables including pH, initial concentration of MO, adsorbent dosage and contact time was studied in detail. The optimal adsorption amount of MO (149.18 mg·g−1) was obtained with 600 MO mg·L−1, 2 MSBC g·L−1, at pH of 5 for 40 min. The equilibrium data were evaluated using Langmuir and Freundlich isotherms. The Langmuir model better described the absorption of MO. Besides, the kinetic data were analyzed using pseudo-first-order and pseudo-second-order equations, and the pseudo-second order exhibited the better fit for the kinetic studies (R2 = 0.9982). This study showed that MSBC could be utilized as an efficient, magnetically separable adsorbent for the environmental cleanup.

Adsorption of methyl orange dye onto biochar adsorbent prepared from chicken manure

2018 ◽  
Vol 77 (5) ◽  
pp. 1303-1312 ◽  
Author(s):  
Jiangang Yu ◽  
Xingwen Zhang ◽  
Dong Wang ◽  
Ping Li
Keyword(s):  
Aqueous Solution ◽  
Methyl Orange ◽  
Chicken Manure ◽  
Maximum Adsorption Capacity ◽  
Solution Ph ◽  
Equilibrium Data ◽  
Intra Particle Diffusion ◽  
Endothermic Process ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

Abstract In this work, the biochar adsorbent carboxymethyl cellulose (CMC), was prepared from the pyrolysis (600 °C, 120 min) of chicken manure for the removal of methyl orange (MO) from aqueous solution, and its physicochemical properties were characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectra (FTIR). The experimental parameters including agitation speed, initial solution pH, biochar dosage and contact time on the adsorption properties of MO from aqueous solution onto CMC were investigated in batch experiments. The kinetic adsorption of different initial concentration could be accurately described by the pseudo-second-order model and the overall rate process was apparently influenced by external mass transfer and intra-particle diffusion. Furthermore, the Langmuir isotherm model showed a better fit with equilibrium data (R2 > 0.99), with the maximum adsorption capacity of 39.47 mg·g−1 at 25 °C. Moreover, the thermodynamic parameters indicated that the adsorption of MO onto CMC was a spontaneous and endothermic process. The results of this study indicated that CMC could be used as a promising biomass adsorbent material for aqueous solutions containing MO.

scholarly journals Removal of Pb(II) by Pellicle-Like Biofilm-Producing Methylobacterium hispanicum EM2 Strain from Aqueous Media

Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2081 ◽  
Author(s):  
Sun-Wook Jeong ◽  
Hyo Kim ◽  
Jung Yang ◽  
Yong Choi
Keyword(s):  
Aqueous Media ◽  
Freundlich Isotherm ◽  
Infrared Analysis ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Multilayer Adsorption ◽  
Drinking Water Contamination ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

As concerns are increasing about drinking water contamination with heavy metals, we investigated the possible use of a pellicle (floating biofilm)-like biofilm-producing microorganism as a biosorbent for the treatment of Pb(II) in aqueous solutions. The bacterial pellicle-producing Methylobacterium hispanicum EM2 strain (EM2) was newly isolated from mine tailing soil, and we investigated its use as a biosorbent for treating a Pb(II)-contaminated aqueous solution. The EM2 strain was strongly resistant to Pb(II) up to a concentration of 800 mg/L, and achieved remarkable adsorption performance (adsorption rate and maximum adsorption capacity of 96% ± 3.2% and 79.84 mg/g, respectively) under optimal conditions (pH, biomass content, contact time, and initial Pb(II) concentration of 7.1 g/L, 60 min, and 10 mg/L, respectively). The adsorption of Pb(II) was characterized by scanning electron microscopy-energy dispersive x-ray spectroscopy and Fourier-transform infrared analysis. The equilibrium data matched the Freundlich isotherm model well, indicating the occurrence of multilayer adsorption of Pb(II) onto the heterogeneous surface of the EM2 strain, which was also consistent with the pseudo-second-order kinetic model (R2 = 0.98). The high Pb(II) removal efficiency was also confirmed by conducting an adsorption experiment using Pb(II)-contaminated industrial wastewater.

scholarly journals Batch Adsorption of Maxilon Red GRL from Aqueous Solution by Natural Sugarcane Stalks Powder

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Gamal Owes El-Sayed ◽  
Talaat Younis Mohammed ◽  
Ashraf Abd-Allah Salama
Keyword(s):  
Aqueous Solution ◽  
Dye Removal ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Textile Dye ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Pseudo Second Order

Sugarcane stalks powder was tested for its efficiency of removing a textile dye Maxilon Red GRL from aqueous solution. Different parameters affecting dye removal efficiency were studied. These parameters include contact time, initial dye concentration, adsorbent dose, ionic strength, pH, and temperature. Langmuir and Freundlich isotherm models were applied to the equilibrium data. The data fitted well with the Langmuir isotherm (). The maximum monolayer adsorption capacity () was found to be 20.96 mg/g at an initial pH of 7.2. The temperature variation study showed that dye adsorption is exothermic and spontaneous with increased randomness at the solid solution interface. The results indicated that sugarcane stalks could be an alternative for more costly adsorbents used for dye removal. The kinetic of the adsorption process followed the pseudo second-order kinetics model.

scholarly journals Malachite Green Dye Removal Using the Seaweed Enteromorpha

2011 ◽  
Vol 8 (2) ◽  
pp. 649-656 ◽  
Author(s):  
R. Jayaraj ◽  
M. Chandra Mohan ◽  
P. Martin Deva Prasath ◽  
T. Hidhayathullah Khan
Keyword(s):  
Aqueous Solution ◽  
Malachite Green ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Model Parameters ◽  
Adsorption Method ◽  
Malachite Green Dye ◽  
Equilibrium Data ◽  
Pseudo Second Order

Malachite green adsorption from an aqueous solution onto activatedEnteromorphacarbon has been studied experimentally using batch adsorption method. Adsorption kinetics and equilibrium were investigated as a function of initial dye concentration, pH, contact time and adsorbent dosage. Kinetics studies indicated that the adsorption followed pseudo second order reaction. Equilibrium data was analyzed using Langmuir and Freundlich isotherm models. The adsorption capacity ofEnteromorphawas found to be 94.74%. On the basis of experimental results and the model parameters, it can be inferred that the carbonaceousEnteromorphais effective for the removal of malachite green from aqueous solution.

Adsorption of Congo Red on AB-8 Macroporous Resin

2012 ◽  
Vol 550-553 ◽  
pp. 2138-2141
Author(s):  
Xin Dong Zhai ◽  
Jie Yan Wu
Keyword(s):  
Waste Water ◽  
Aqueous Solution ◽  
Congo Red ◽  
Freundlich Isotherm ◽  
Macroporous Resin ◽  
Order Model ◽  
Initial Concentration ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Agitation Time

Waste water containing Congo red in industrial production has caused many serious environmental problems worldwide. In this paper, AB-8 macroporous resin was used to remove Congo red from an aqueous solution by adsorption technique under varying conditions of pH, adsorbent dosage, agitation time, temperature and initial concentration. The results show the adsorption kinetics is well described by pseudo-second-order model. It was found that the equilibrium data was better represented by the Freundlich isotherm model.

scholarly journals Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material

2019 ◽  
Vol 25 (4) ◽  
pp. 55-69
Author(s):  
Omar Hisham Fadhil ◽  
Mohammed Y. Eisa
Keyword(s):  
Methyl Orange ◽  
Contact Time ◽  
Freundlich Isotherm ◽  
Order Kinetic ◽  
Order Model ◽  
Several Variables ◽  
Adsorption Data ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

A comparative study was done on the adsorption of methyl orange dye (MO) using non-activated and activated corn leaves with hydrochloric acid as an adsorbent material. Scanning electron microscopy (SEM) and Fourier Transform Infrared spectroscopy (FTIR) were utilized to specify the properties of adsorbent material. The effect of several variables (pH, initial dye concentration, temperature, amount of adsorbent and contact time) on the removal efficiency was studied and the results indicated that the adsorption efficiency increases with the increase in the concentration of dye, adsorbent dosage and contact time, while inversely proportional to the increase in pH and temperature for both the treated and untreated corn leaves. The equilibrium data is best fitted to Freundlich isotherm for untreated adsorbent, while Langmuir isotherm show best agreement with the data when the treated adsorbent is used. The rate of adsorption was found to follow the pseudo first order kinetic model (PFO) when non-activated adsorbent is used, while the pseudo second order model (PSO) is fitted to the adsorption data using activated adsorbent.  

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