Post-treatment of palm oil mill effluent (POME) using combined persulphate with hydrogen peroxide (S2O82−/H2O2) oxidation

2016 ◽  
Vol 74 (11) ◽  
pp. 2675-2682 ◽  
Author(s):  
Chia Ken Lin ◽  
Mohammed J. K. Bashir ◽  
Salem S. Abu Amr ◽  
Lan Ching Sim
Keyword(s):  
Hydrogen Peroxide ◽  
Palm Oil ◽  
Suspended Solids ◽  
Oxygen Demand ◽  
Post Treatment ◽  
Palm Oil Mill Effluent ◽  
Operation Conditions ◽  
H2o2 Oxidation ◽  
Palm Oil Mill ◽  
First Time

The aim of the current study is to evaluate the effectiveness of combined persulphate with hydrogen peroxide (S2O82−/H2O2) oxidation as a post-treatment of biologically treated palm oil mill effluent (POME) for the first time in the literature. The removal efficiencies of chemical oxygen demand (COD), ammoniacal nitrogen (NH3-N), and suspended solids (SS) were 36.8%, 47.6%, and 90.6%, respectively, by S2O82− oxidation alone under certain operation conditions (i.e., S2O82− = 0.82 g, pH 11, and contact time 20 min). Nevertheless, the combined process (S2O82−/H2O2) achieved 75.8% and 87.1% removals of NH3-N and SS, respectively, under 2.45/1.63 g/g H2O2/S2O82−, pH 11, and 20 min oxidation. Moreover, 56.9% of COD was removed at pH 8.4.

scholarly journals Simulation and Optimisation of Integrated Anaerobic-Aerobic Bioreactor (IAAB) for the Treatment of Palm Oil Mill Effluent

Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1124
Author(s):  
Jun Wei Roy Chong ◽  
Yi Jing Chan ◽  
Siewhui Chong ◽  
Yeek Chia Ho ◽  
Mardawani Mohamad ◽  
...  
Keyword(s):  
Palm Oil ◽  
Oxygen Demand ◽  
Palm Oil Mill Effluent ◽  
Organic Loading Rate ◽  
Biogas Yield ◽  
Trade Offs ◽  
Payback Time ◽  
Recycle Ratio ◽  
Palm Oil Mill ◽  
First Time

This study highlights an innovative piece of hybrid technology, whereby the combination of anaerobic and aerobic processes into a single reactor, namely, the integrated anaerobic–aerobic bioreactor (IAAB) can surpass the limits of conventional methods treating palm oil mill effluent (POME). Optimisation of IAAB using SuperPro Designer V9 simulator for maximum biogas yield while addressing its economic and environmental trade-offs was conducted for the first time. Parameters such as hydraulic retention time (HRT) and organic loading rate (OLR) were optimised in the anaerobic compartment from 10 days and 6.2 g COD/L day to 9 days and 6.9 g COD/L day, respectively. Furthermore, sludge recycle ratio was optimised from 20% to 50% in the aerobic compartment. The optimisation was successful where the biogas yield increased from 0.24 to 0.29 L CH4/g CODremoved with excellent Chemical Oxygen Demand (COD), and Biological Oxygen Demand (BOD) removal efficiencies up to 99% with 5.8% lower net expenditure. This simulation results were comparable against the pre-commercialized IAAB with 11.4% increase in methane yield after optimisation. Economic analysis had proven the optimised process to be feasible, resulting in return on investment (ROI), payback time, and internal rate of return (IRR) of 24.5%, 4.1 years, and 17.9%, respectively.

Enhancing BOD/COD Ratio of POME Treatment in SBR System

2015 ◽  
Vol 802 ◽  
pp. 437-442 ◽  
Author(s):  
Hossein Farraji ◽  
Nastaein Q. Zaman ◽  
Hamidi Abdul Aziz ◽  
Muhammad Aqeel Ashraf ◽  
Amin Mojiri ◽  
...  
Keyword(s):  
Chemical Oxygen Demand ◽  
Palm Oil ◽  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Biological Oxygen Demand ◽  
Post Treatment ◽  
Palm Oil Mill Effluent ◽  
Treatment Methods ◽  
Palm Oil Mill

Palm oil mill effluent (POME) contains high biological oxygen demand (BOD) and chemical oxygen demand (COD) Agra base wastewater is the concern of biodegradable treatment methods. Consequently, the BOD / COD ratio has a significant effect on the biodegradability of wastewaters. This study investigates effects of aerated sequencing batch reactor (SBR) system augmented by zeolite used for treatment of POME. Not only, the BOD / COD ratio increased from 0.11 in raw POME to mean 68.15% increase after aeration in the SBR system, but also, the most obvious finding to emerge from this study is that, aerated SBR could be considered as an effective method for enhancing BOD/COD ratio for qualifying post treatment by biotreatment methods.

Treatment of Palm Oil Mill Effluent (POME) Supernatants Using Aerobic Attached–Growth System: Trickling Filter as a Case Study

2012 ◽  
Author(s):  
Ahmad Zuhairi Abdullah ◽  
Mohamad Hakimi Ibrahim ◽  
Mohd. Omar Ab. Kadir
Keyword(s):  
Palm Oil ◽  
Colloidal Particles ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Palm Oil Mill Effluent ◽  
Trickling Filter ◽  
Biomass Hydrolysis ◽  
Removal Efficiencies ◽  
Palm Oil Mill ◽  
Hydrolysis Of

Kertas kerja ini membincangkan tentang kecekapan penuras cucur dalam merawat supernatan kumbahan kilang kelapa sawit (POME). Supernatan POME diperoleh menerusi dua jenis perawatan. Dalam perawatan 1, pengendapan graviti digunakan untuk menyingkir pepejal boleh mendak. Perawatan 2 digunakan untuk menyingkir pepejal boleh mendak dan gumpalan partikal dengan menggunakan 350 ppm alum. Influen dialurkan secara titisan pada biojisim yang terlekat pada penyokong pepejal rawak PVC setinggi 1 m. Penuras cucur berupaya menyingkir lebih daripada 90.0% dari keperluan oksigen biologi (BOD) dan keperluan oksigen kimia (COD) di bawah 1 m3/m2–hari. Pada 2.53 m3/m2–hari, influen dengan Perawatan 1 menghasilkan kecekapan penyingkiran COD sebanyak 40.3%, berbanding 83.1% bila Perawatan 2 digunakan. Perkara ini berlaku berikutan penyingkiran bahan organik tak boleh resap semasa Perawatan 2. Kecekapan penyingkiran menurun dengan meningkatnya bebanan hidraulik kerana wujudnya kelemahan dalam hidrolisis bahan tak boleh resap kepada substratum larut. Dengan edaran semula (α=1), penyingkiran BOD dan COD yang lebih tinggi dicapai di bawah 7 m3/m2–hari. Pencapaian ini disebabkan oleh bebanan organik yang lebih rendah serta pergedaran semula enzim dan biojisim yang aktif kepada sistem. Perawatan 2 menghasilkan enap cemar yang lebih tinggi kerana penukaran substratum boleh larut kepada biojisim tak boleh larut. Hidrolisis bahan organik tak boleh resap didapati berlaku secara aktif pada bahagian atas penuras cucur sementara bahagian bawahnya cenderung mengoksidakan substratum organik. Kata kunci: POME, turas cucur, bahan organik bolehresap, penggumpalan, alir semula This paper discusses the efficiency of a trickling filter to treat Palm Oil Mill Effluent (POME) supernatants. POME supernatants were obtained via two treatments. In Treatment 1, gravity sedimentation was used to remove settleable solids. In Treatment 2, both settleable solids and colloidal particles were removed using 350 ppm of alum. The influents were allowed to trickle over biomass attached to 1 m high random PVC solid support. Below 1 m3/m2–day, the filter demonstrated Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) removal efficiencies of more than 90.0%. At 2.53 m3/m2–day, the influent with Treatment 1 gave a COD removal efficiency of 40.3%, but increased to 83.1% when the influent with Treatment 2 was used. This was ascribed to the removal of non–diffusible organics during Treatment 2. The removal efficiencies decreased with an increase in hydraulic loading due to limitations in the hydrolysis of non–diffusibles into soluble substrates. With recirculation (α=1), higher BOD and COD removals were achieved below 7.0 m3/m2–day, attributed to lower organic loading and the recycling of active enzyme and biomass to the system. The influent with Treatment 2 demonstrated higher sludge production due to higher conversion of soluble substrates into insoluble biomass. Hydrolysis of non–diffusible organics mainly took place at upper reaches of the filter column while lower reaches were involved in oxidizing the organic subtrates. Key words: POME, trickling filter, diffusible organic, coagulation, recirculation

scholarly journals Phytoremediation Potential of Vetiver System Technology for Improving the Quality of Palm Oil Mill Effluent

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Negisa Darajeh ◽  
Azni Idris ◽  
Paul Truong ◽  
Astimar Abdul Aziz ◽  
Rosenani Abu Bakar ◽  
...  
Keyword(s):  
Palm Oil ◽  
Oxygen Demand ◽  
Raw Material ◽  
Biofuel Production ◽  
Palm Oil Mill Effluent ◽  
System Technology ◽  
High Concentration ◽  
Low Concentration ◽  
Control Sets ◽  
Palm Oil Mill

Palm oil mill effluent (POME), a pollutant produced by the palm oil industry, was treated by the Vetiver system technology (VST). This technology was applied for the first time to treat POME in order to decrease biochemical oxygen demand (BOD) and chemical oxygen demand (COD). In this study, two different concentrations of POME (low and high) were treated with Vetiver plants for 2 weeks. The results showed that Vetiver was able to reduce the BOD up to 90% in low concentration POME and 60% in high concentration POME, while control sets (without plant) only was able to reduce 15% of BOD. The COD reduction was 94% in low concentration POME and 39% in high concentration POME, while control just shows reduction of 12%. Morphologically, maximum root and shoot lengths were 70 cm, the number of tillers and leaves was 344 and 86, and biomass production was 4.1 kg m−2. These results showed that VST was effective in reducing BOD and COD in POME. The treatment in low concentration was superior to the high concentration. Furthermore, biomass of plant can be considered as a promising raw material for biofuel production while high amount of biomass was generated in low concentration of POME.

Effect of Different Mediators on Bio-Energy Generation and Palm Oil Mill Effluent Treatment in an Air-Cathode Microbial Fuel Cell-Adsorption System

2021 ◽  
Vol 411 ◽  
pp. 67-78
Author(s):  
Ivy Ai Wei Tan ◽  
J.R. Selvanathan ◽  
M.O. Abdullah ◽  
N. Abdul Wahab ◽  
D. Kanakaraju
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Palm Oil ◽  
Oxygen Demand ◽  
Energy Generation ◽  
Effluent Treatment ◽  
Palm Oil Mill Effluent ◽  
Adsorption System ◽  
Air Cathode ◽  
Palm Oil Mill

Palm oil mill effluent (POME) discharged without treatment into watercourses can pollute the water source. Microbial fuel cell (MFC) has gained high attention as a green technology of converting organic wastewater into bio-energy. As an approach to overcome the limitations of the existing POME treatment methods, air-cathode MFC-Adsorption system is introduced as an innovative technology to treat POME and generate bio-electricity simultaneously. However, the use of conventional MFC with proton exchange membrane in large scale applications is restricted by the high cost and low power generation. Addition of mediator in MFC is essential in order to increase the electron transfer efficiency, hence enhancing the system performance. This study therefore aims to investigate the effect of different type of mediators i.e. congo red (CR), crystal violet (CV) and methylene blue (MB) on the performance of an affordable air-cathode MFC-Adsorption system made from earthen pot with POME as the substrate. The addition of different mediators altered the pH of the MFC-Adsorption system, in which more alkaline system showed better performance. The voltage generated in the system with CR, CV and MB mediator was 120.58 mV, 168.63 mV and 189.25 mV whereas the current generated was 2.41 mA, 3.37 mA and 3.79 mA, respectively. The power density of 290.79 mW/m3, 568.72 mW/m3 and 716.31 mW/m3 was produced in the MFC-Adsorption system with CR, CV and MB mediator, respectively. The highest POME treatment efficiency was achieved in MFC-Adsorption system with MB mediator, which resulted in biochemical oxygen demand, chemical oxygen demand, total suspended solids, turbidity and ammoniacal nitrogen removal of 75.3%, 84.8%, 91.5%, 86.1% and 23.31%, respectively. Overall, the air-cathode MFC-Adsorption system with addition of MB mediator was feasible for POME treatment and simultaneous bio-energy generation.

scholarly journals Acclimatization Study for Biohydrogen Production from Palm Oil Mill Effluent (POME) in Continuous-flow System

2018 ◽  
Vol 34 ◽  
pp. 02054 ◽  
Author(s):  
N. Idris ◽  
N.A. Lutpi ◽  
Y. S. Wong ◽  
T.N. Tengku Izhar
Keyword(s):  
Steady State ◽  
Palm Oil ◽  
Continuous Flow ◽  
Flow System ◽  
Oxygen Demand ◽  
Biohydrogen Production ◽  
Palm Oil Mill Effluent ◽  
Continuous Flow System ◽  
Thermophilic Fermentation ◽  
Palm Oil Mill

This research aims to study the acclimatization phase for biohydrogen production from palm oil mill effluent (POME) by adapting the microorganism to the new environment in continuous-flow system of thermophilic bioreactor. The thermophilic fermentation was continuously loaded with 0.4 L/day of raw POME for 35 days to acclimatize the microorganism until a steady state of biohydrogen production was obtained. The significance effect of acclimatization phase on parameter such as pH, microbial growth, chemical oxygen demand (COD), and alkalinity were also studied besides the production of biogas. This study had found that the thermophilic bioreactor reach its steady state with 1960 mL/d of biogas produced, which consist of 894 ppm of hydrogen composition.

scholarly journals Enhancement of Biodegradation of Palm Oil Mill Effluents by local Isolated Fungi

2016 ◽  
Vol 15 (4) ◽  
pp. 23-34 ◽  
Author(s):  
F T Z Jabeen ◽  
J V Shreevathsa
Keyword(s):  
Chemical Oxygen Demand ◽  
Effective Treatment ◽  
Palm Oil ◽  
Biochemical Oxygen Demand ◽  
Oxygen Demand ◽  
Palm Oil Mill Effluent ◽  
Physicochemical Quality ◽  
Palm Oil Mill ◽  
Micro Organisms ◽  
Better Than

This study was designed to investigate the fungi associated with palm oil mill effluent (POME) in Gulur village of Tumkur. Biodegradation of palm oil mill effluents was conducted to measure the discarded POME based on physicochemical quality. The fungi that were isolated are Aspergillusniger, A. flavus, A. fumigatus, A. ochraceus, Rhizopussp, Peniciliumsp and Trichodermavirde. The autoclaved and unautoclaved raw POME samples were incubated for 7 days and the activities of the fungi were observed each for 12 hours. The supernatants of the digested POME were investigated for the removal of chemical oxygen demand (COD), color (ADMI), and biochemical oxygen demand (BOD) at the end of each digestion cycle. The results showed that the unautoclaved raw POME sample degraded better than the inoculated POME sample and this suggests that the microorganisms that are indigenous in the POME are more effective than the introduced micro-organisms. This result, however, indicates the prospect of isolating indigenous microorganisms in the POME for effective biodegradation of POME. Moreover, the effective treatment of POME yields useful products such as reduction of BOD, COD, and color.

scholarly journals IDENTIFIKASI LIMBAH PALM OIL MILL EFFLUENT (POME) MENGGUNAKAN BIOSENSOR BERBASIS ALGA

2021 ◽  
Vol 7 (1) ◽  
pp. 1-6
Author(s):  
Dina Maryani ◽  
Lazuardi Umar
Keyword(s):  
Chemical Oxygen Demand ◽  
Palm Oil ◽  
Biochemical Oxygen Demand ◽  
Oxygen Demand ◽  
Palm Oil Mill Effluent ◽  
Chlorella Sp ◽  
Palm Oil Mill

Palm Oil Mill Effluent (POME) merupakan limbah minyak kelapa sawit yang memiliki kadar Chemical Oxygen Demand (COD) dan Biochemical Oxygen Demand (BOD) yang tinggi dan sehingga merusak ekosistem periairan serta menurunkan kadar oksigen terlarut (DO). Namun, POME memiliki nutrisi untuk sel alga dalam memproduksi oksigen. Berdasarkan hal tersebut diperlukan identifikasi POME yang jatuh kebadan air berdasarkan fotosintesis Chlorella sp. menggunakan biosensor. Biosensor telah banyak dikembangkan dalam aplikasi bidang lingkungan dengan melihat kadar oksigen terlarut sebagai kualitas perairan. Penelitian ini menggunakan biosensor dengan prinsip sensor amperometris  tipe Biochip-G. Sensor amperometris mengukur perubahan arus dari reaksi reduksi dan oksidasi dan menghasilkan potensial keluaran yang terukur. Potensial keluaran yang terukur merupakan kadar oksigen terlarut dari penambahan POME terhadap Chlorella sp. ketika proses fotosintesis terjadi. Identifikasi POME berdasarkan proses fotosintesis Chlorella sp. menggunakan cahaya artifisial LED Putih 380 nm-780 nm dengan tingkat variasi konsentrasi POME sebanyak 10%, 20%, dan 30%. Berdasarkan pengukuran kadar oksigen terlarut (DO) menghasilkan nilai DO sebesar 174.15%, 154.66%, dan 138.98% serta nilai sensitivitas sebesar 4mV/%POME.  

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