Sorption of paracetamol onto biomaterials

2016 ◽  
Vol 74 (1) ◽  
pp. 287-294
Author(s):  
Maroua Ferchichi ◽  
Hatem Dhaouadi

Pharmaceutical residues released into the environment are posing more and more public health problems. It is worthwhile to study the retention of pharmaceuticals residues by adsorption on solid supports. Batch sorption experiments are intended to identify the adsorption isotherms of the pharmaceutically active ingredient on the biomaterials. The results obtained in this study have shown that the retention possibilities of these compounds by bio-adsorbents (clay and sand) are not significant. The negligible sorption for these media is explained by the low hydrophobicity of paracetamol (Log Kow = 0.46). The retention of paracetamol on the dehydrated sewage sludge and on Posidonia oceanica showed a relatively significant adsorption with a maximal quantity of 0.956 mg g−1 and 1.638 mg g−1 for the dehydrate sludge and P. oceanica, respectively. On the other hand, the study of paracetamol retention on the powdered activated carbon showed a high adsorption capacity of about 515.27 mg g−1. Isotherm data show a good fit with Langmuir's model. An infrared analysis is carried out. It shows identical bands before and after adsorption, with some modifications.

2021 ◽  
Vol 16 (2) ◽  
pp. 113-121
Author(s):  
Orléans Ngomo ◽  
Joseph Sieliechi ◽  
Etienne Dongo

Avocado is a versatile and valuable product. Its oil is comparable to olive oil in terms of nutritional quality. It can also be used in cosmetics, in particular, in soaps, shampoos and lotions. Despite all these important attributes that avocado has, it is highly perishable and coupled with the lack of farm-to-market roads, a lot of it is lost after harvest during the peak season. The introduction of methods that will transform avocado to products with a long shelf life and added value will go a long way to solving the problem of post-harvest losses and poverty. One of these methods is the production of avocado oil. In addition, in order to reduce the colour of the pigments without altering their quality, discoloration tests were carried out by adsorption on bleaching grounds (a montmorillonite, a kaolinite and activated carbon). The colour intensities of the oils before and after adsorption were determined using two complementary methods: a UV-Vis spectrophotometer and a Konica Minolta spectrophotometer CM-5. The UV-Vis spectrophotometer show that the activated carbon has a best fixing capacity of the pigments; According to the Colorimetric parameters (CIE-Lab) the coordinates L* a* b* that showed brightness (L*) of the avocado oil was half of the olive oil (41.13±0.02 vs 84.85±0.02). The activated carbon was better in fixing the red (a*) (4.99±0.01vs 15.73±0.01 before adsorption) and yellow (b*) (63.71±0.09 vs 70.07±0.09 before adsorption) pigments, while the other two adsorbents have very little influence on the red colour of avocado oil. RésuméL’avocat est un produit versatile et de grande valeur. Son huile est comparable à huile d’olive en terme de qualité nutritionnelle ; elle peut également être utilisée en cosmétique en occurrence dans les savons, champoings et lotions. En pleine saison, l’on fait face à une abondance des avocats dans les zones de production qui sont très souvent enclavées ; c’est ainsi que face aux difficultés de transport et les routes peu praticables pour l’importation, l’on se retrouve en train de perdre de très importantes quantités d’avocats après les récoltes. Or la production d’huile d’avocats permettrait de réduire les pertes post récolte, réduirait le chômage et permettrait de lutter contre la pauvreté après la vente des huiles extraites. De plus, dans le but de réduire les pigments colorés, des tests de décolorations effectués par adsorption sur des terres décolorantes (une montmorillonite en provenance de Maroua, une kaolinite en provenance de Douala et le charbon actif) sont effectués. Les couleurs des huiles mesurées avant et après adsorption à l’aide deux appareils complémentaires : Le spectrophotomètre UV-Vis et du Konica Minolta spectrophotomètre CM-5 montrent. Les analyses spectrophotométriques UV-Vis montrent que c’est le charbon activé qui présente la meilleure adsorption des pigments ; D’après les coordonnées L*a*b*, la clarté de l’huile d’avocat est pratiquement la moitié de celle de l’huile d’olive (41,13±0,02 contre 84,85±0,02), le charbon activé fixe mieux les pigments rouges (a*) (4,99±0,01 contre 15,73±0,01 avant adsorption) et jaunes (b*) (63,71±0,09 contre 70,07±0,09 après adsorption), tandis que les deux autres adsorbants influencent très peu sur la coloration des huiles.


2012 ◽  
Vol 610-613 ◽  
pp. 259-263 ◽  
Author(s):  
Fei Shang ◽  
Xiao Lv Zhou ◽  
Zhen Xing Zhou ◽  
Chen Yan Hu ◽  
Jing Zhang ◽  
...  

In this paper,granular activated carbon GAC was used to investigate the adsorption capacity and adsorption rate of a typical nitrogen-containing organic compounds L-phenylalanine. GAC shows a high adsorption capacity for the L-phenylalanine and the adsorption isotherms conform to with Langmuir model.The pseudo-first-order equation shows the best fitting for adsorption kinetics in L-phenylalanine adsorption by GAC. Besides the factors such as the temperature, adsorption time and activated carbon quantity were studied.


1985 ◽  
Vol 2 (4) ◽  
pp. 219-228 ◽  
Author(s):  
E. V. Zagorevskaya ◽  
N. V. Ishchenko ◽  
A. V. Kiselev ◽  
N. V. Kovaleva

Adsorption properties of carbon black before and after modification to polyhalogenohydrocarbons, including polyorganochlorine pesticides, have been investigated. It has been shown that graphitised thermal carbon blacks and carbochroms possess high adsorption capacity relative to the above compounds and can be used as supporting adsorbents to analyse these airborne chemicals. Modification raises the selectivity of adsorbents to the compounds being investigated and lowers retention volumes and heats of adsorption, which makes it possible to carry out thermal desorption of the accumulated species at lower temperatures.


Investigate the possibility of treating wastewater containing heavy metals Zn2+ with activated carbon material prepared from macadamia shell with chemical activating agent H3PO4, showing high efficiency of adsorption of Zn2+. The results of the study showed that activated carbon with H3PO4 activating agent has high adsorption capacity, capable of handling Zn2+ best at pH = 4.5, dosage 1.8 g/L and time is 120 minutes. . The results show similarities with other research results and are capable of treating wastewater containing heavy metals Zn2+.


2017 ◽  
Vol 102 ◽  
pp. 443-450 ◽  
Author(s):  
Li Zhou ◽  
Qunyan Yu ◽  
Ying Cui ◽  
Fei Xie ◽  
Wenjiang Li ◽  
...  

2018 ◽  
Vol 42 (17) ◽  
pp. 14612-14619 ◽  
Author(s):  
Cínthia Soares de Castro ◽  
Luísa Nagyidai Viau ◽  
Júlia Teixeira Andrade ◽  
Thais A. Prado Mendonça ◽  
Maraísa Gonçalves

Activated carbons of high mesoporosity were prepared from PET wastes and presented high adsorption capacity, including relatively large-molecule dyes.


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