Visible light induced photocatalytic degradation of rhodamine B by magnetic bentonite

2016 ◽  
Vol 73 (10) ◽  
pp. 2345-2352 ◽  
Author(s):  
Wenbing Li ◽  
Dong Wan ◽  
Guanghua Wang ◽  
Lulu Lu ◽  
Xiaobi Wei

The photocatalytic activity of magnetic bentonite, Fe3O4 nanoparticles decorated Al-pillared bentonite (Fe3O4/Al-B), for the degradation of rhodamine B (RhB) in the presence of H2O2 under visible light (VL) was evaluated. The effects of different reaction parameters such as catalyst dose, dye concentration and externally added H2O2 were also investigated. The magnetic bentonite showed good photocatalytic activity, magnetic separability and stability for repeated use. More than 95% of 40 mg/L RhB was converted within 3 h under VL with a catalyst dose of 0.5 g/L. Suitable mechanisms have been proposed to account for the photocatalytic activities in the presence and absence of H2O2. The efficiency of H2O2 in VL process was much higher than that of the dark process. Results obtained in the current study may be useful to develop a suitable photocatalyst for photocatalytic remediation of different water contaminants including organic dyes.

2016 ◽  
Vol 852 ◽  
pp. 1473-1476
Author(s):  
Yan Ding ◽  
Liang Fang Fu ◽  
Yu Huan Wang ◽  
Liang Chao Li ◽  
Juan Bi Li

A series of photocatalyst Bi1-xLaxVO4 (0.1, 0.3, 0.5, 0.7) powders were prepared by hydrothermal method. The composition, structure, morphology and photocatalytic activity of the samples were researched by means of modern testing techniques. Bi1-xLaxVO4 showed excellent visible-light sensitivity and photocatalytic activities. The degradation rate of sample with x = 0.5 on rhodamine B reached 90 %, which was much higher than that of pure BiVO4.


NANO ◽  
2017 ◽  
Vol 12 (06) ◽  
pp. 1750072 ◽  
Author(s):  
Tao Wang ◽  
Changchang Ma ◽  
Dan Wu ◽  
Xinlin Liu ◽  
Yang Liu ◽  
...  

In this paper, a novel heterostructure of 0D/3D-CdSe/Bi[Formula: see text]TiO[Formula: see text] pyramidal photocatalyst was synthesized and characterized. It exhibited significantly photocatalytic efficiency in photocatalytic degradation of the tetracycline than pure Bi[Formula: see text]TiO2 and CdSe and showed high stability. The enhanced photocatalytic activity might be attributed to the formation of heterostructure between CdSe QDs and 3D Bi[Formula: see text]TiO[Formula: see text], in which CdSe QDs served as electron trapper to improve the separation of photodegradation electron–hole pairs, and provided a number of active adsorption sites for the photogenerated of pollutants. The photocatalytic mechanism of 0D/3D-CdSe/Bi[Formula: see text]TiO[Formula: see text] pyramidal heterostructure was also proposed.


2013 ◽  
Vol 423-426 ◽  
pp. 163-166 ◽  
Author(s):  
Bao Wei Cao ◽  
Yun Hua Xu

Bi2WO6 doped with iodine ions were synthesized using hydrothermal method and their photocatalytic activities to degrade Rhodamine B (RhB) under visible-light was investigated. The successful incorporation of I ions in Bi2WO6 was proved by XRD and XPS. UV-vis absorption spectra results show that I ion was successfully doped into Bi2WO6 and a red shift for I-doped Bi2WO6 appeared when compared to pure Bi2WO6. The photocatalytic activities of the photocatalysts were evaluated by the decolorization of RhB under visible-light irradiation. The results showed that the photocatalytic activity of I-doped Bi2WO6 was much higher than the undoped Bi2WO6.


2021 ◽  
Author(s):  
Rui Zhang ◽  
ziyin chen ◽  
Chen Zhao ◽  
Kunlin Zeng ◽  
Lu Cai ◽  
...  

Abstract A novel binary BiSI/Ag2CO3 photocatalyst with excellent visible light-driven photocatalytic performance was prepared. The products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) and electrochemical impedance spectroscopy (EIS). The photocatalytic activity of the samples were evaluated by photocatalytic degradation of rhodamine B(RhB) under the irradiation of visible light. The results showed that the BiSI improves the photocatalytic activity of BiSI/Ag2CO3. Moreover, when the mass ratio of BiSI in BiSI/Ag2CO3 composites was 40%, the as-prepared BiSI/Ag2CO3 composite exhibited the best photocatalytic activity for degrading RhB. Finally, the possible mechanism for photodegradation over the BiSI/Ag2CO3 composites is also proposed.


2020 ◽  
Vol 42 (6) ◽  
pp. 827-827
Author(s):  
Yun Xuan Fu Yun Xuan Fu ◽  
Yan Li Yan Li ◽  
Tian Long Chang Tian Long Chang ◽  
Xu Tao Liu Xu Tao Liu ◽  
Xiang Feng Wu Xiang Feng Wu ◽  
...  

Visible-light-driven WO3and#183;0.33H2O/Ag2MoO4 composites have been prepared by using an in-situ growth of Ag2MoO4 nanoparticles on the surfaces of WO3and#183;0.33H2O. The photocatalytic activities of the samples were studied by degradation of rhodamine B and levofloxacin dilute solution. The synergistic photocatalytic mechanism was also analyzed. Experimental results reveal that the as-developed hybrids have higher photocatalytic activity than pure samples. When the theoretical molar ratio of WO3and#183;0.33H2O to Na2MoO4and#183;2H2O is 1:0.15, the as-developed hybrids have the highest photocatalytic degradation efficiency of 99.0% for rhodamine B in 45 min and 40.9% for levofloxacin in 120 min. Furthermore, there are chemical bonds between WO3and#183;0.33H2O and Ag2MoO4. In addition, the super oxide radicals play the leading role during the photocatalytic degradation process of the samples. This work will provide reference for treatment of organic dyes and antibiotics pollution in water with using solar energy.


2018 ◽  
Vol 47 (27) ◽  
pp. 9103-9113 ◽  
Author(s):  
Tian-Rui Zheng ◽  
Lin-Lu Qian ◽  
Min Li ◽  
Zhi-Xiang Wang ◽  
Ke Li ◽  
...  

A bifunctional cationic MOF showed fast and highly efficient Cr2O72− and CrO42− trapping, and highly efficient photocatalytic activity.


2013 ◽  
Vol 562-565 ◽  
pp. 1319-1324 ◽  
Author(s):  
Xi Li Shangand ◽  
Tian Yong Zhang ◽  
Chang Hai Li ◽  
Bin Li ◽  
Xiao Wang

In this paper, two newly explored TiO2 photocatalyst sensitized with commercial stable pigment (BYH3G and PR254) were prepared and characterized by FT–IR, UV–Vis, XRD and N2 adsorption-desorption isotherms. The adsorption capacities and the photocatalytic activities of as-prepared photocatalysts were evaluated by photocatalytic degradation of Methyl Orange and Rhodamine B under visible light irradiation. The as-prepared photocatalysts displayed high visible light photocatalytic activity than pure TiO2 under the same conditions. The photocatalytic activity can be reproduced commendably demonstrates that the as-prepared photocatalysts are stable and renewable, which are potentially important properties in the application of industrial wastewater treatment.


RSC Advances ◽  
2021 ◽  
Vol 11 (31) ◽  
pp. 19283-19293
Author(s):  
S. Harish ◽  
P. Bharathi ◽  
Prachi Prasad ◽  
R. Ramesh ◽  
S. Ponnusamy ◽  
...  

The photocatalytic performance of MoS2/NiS2 nanocomposites was studied by the degradation of rhodamine B (RhB). Ni-4 sample shows higher photocatalytic activity with a maximum degradation of 90.61% under visible light irradiation for 32 min.


Catalysts ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 235 ◽  
Author(s):  
Chitiphon Chuaicham ◽  
Radheshyam Pawar ◽  
Keiko Sasaki

The photocatalytic activity of sepiolite was examined for degradation of several dye compounds under visible light irradiation. Higher adsorption capacities and greater photocatalytic performance of cationic dyes (rhodamine B and methylene blue) were observed on sepiolite, in comparison with anionic dyes (orange II and trypan blue). Superiority in the photocatalytic activity of cationic dyes is attributed to the strong electrostatic attraction and photosensitization properties of cationic dye molecules. Sepiolite has degraded 45.3% rhodamine B within 120 min, which is the greatest photocatalytic degradation efficiency when compared with other dyes. Subsequently, the reusability of spent sepiolite after adsorption of rhodamine B was evaluated by the degradation of trypan blue under the visible light irradiation. The photocatalytic degradation performance of trypan blue by spent sepiolite after adsorption of rhodamine B increased about twice as much as with pristine sepiolite, indicating that the dye-sensitized photocatalytic process could enhance the photocatalytic degradation ability of sepiolite. Through radical scavenger tests, it was found that a superoxide radical is mainly responsible for rhodamine B degradation. The possible mechanism of rhodamine B degradation under visible light irradiation was proposed. The sepiolite could be a potential catalyst for the degradation of organic pollutants in wastewater under solar light.


2011 ◽  
Vol 236-238 ◽  
pp. 2080-2085 ◽  
Author(s):  
Chen Feng ◽  
Liu Ping Zheng ◽  
Gui Yang Yan ◽  
Meiu Qin Zheng

Nanocrystalline ZnS particles were prepared by hydrothermal method and characterized by XRD, FT-IR, TEM and UV-vis DRS and their photocatalytic activities were evaluated by the photodegradation of Eosin B under visible light. The results showed that the ZnS nanoparticles we prepared were in hexagonal phase, their average size of the complex particles varies from 10 nm to 20 nm, and also revealed well photocatalytic activity under visible light, the photocatalytic decolouration rate of Eosin B in 3 h reached 70 %.


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