Detection of semi-volatile organic compounds (SVOCs) in surface water, soil, and groundwater in a chemical industrial park in Eastern China

2015 ◽  
Vol 73 (5) ◽  
pp. 1175-1189 ◽  
Author(s):  
Benhua Liu ◽  
Yuehua Li ◽  
Jianfeng Ma ◽  
Linxian Huang ◽  
Liang Chen
Keyword(s):  
Surface Water ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Eastern China ◽  
Industrial Park ◽  
Chemical Production ◽  
The North ◽  
Detection Frequency ◽  
Volatile Organic ◽  
Chemical Industrial Park

China is suffering from serious water and soil pollution, especially in the North China Plain. This work investigated semi-volatile organic compounds (SVOCs) in surface water, groundwater and soil within a chemical industrial park in Eastern China, for which the volatile organic compound (VOC) results have been previously reported. A total of 20 samples were collected from the field, and analyzed in the laboratory. A 100% detection frequency of SVOCs in samples from this chemical industrial park was observed (same as VOCs). Moreover, the detection frequency of 113 SVOCs in each sample reached 15.93, 12.39 and 20.35% for surface water, groundwater and soil, respectively. The most detected SVOCs in the park included N-containing SVOCs, polycyclic aromatic hydrocarbons, phthalates, organic pesticides and polychlorodiphenyls. The elevated detecting frequencies and concentration levels of SVOCs identified in the groundwater were attributed to the intensive chemical production activities in the park. In addition, the agricultural activities in the area might also have contributed to the SVOCs to the groundwater. The results of VOCs and SVOCs from this and previous studies suggest that the groundwater in this industrial park has been severely contaminated, and the contamination likely spreads beyond the park. Imminent hydrogeological assessments and remedial actions are warranted to eliminate the source and mitigate the potential plume expansion beyond the park boundary.

scholarly journals Investigation on Distribution and Risk Assessment of Volatile Organic Compounds in Surface Water, Sediment, and Soil in a Chemical Industrial Park and Adjacent Area

Molecules ◽  
2021 ◽  
Vol 26 (19) ◽  
pp. 5988
Author(s):  
Rongrong Lei ◽  
Yamei Sun ◽  
Shuai Zhu ◽  
Tianqi Jia ◽  
Yunchen He ◽  
...  
Keyword(s):  
Volatile Organic Compounds ◽  
River Water ◽  
Organic Compounds ◽  
Water Samples ◽  
Soil Samples ◽  
Industrial Park ◽  
Adjacent Area ◽  
Chemical Production ◽  
Volatile Organic ◽  
Chemical Industrial Park

The occurrences, distributions, and risks of 55 target volatile organic compounds (VOCs) in water, sediment, sludge, and soil samples taken from a chemical industrial park and the adjacent area were investigated in this study. The Σ55-VOCs concentrations in the water, sediment, sludge, and soil samples were 1.22–5449.21 μg L−1, ND–52.20 ng g−1, 21.53 ng g−1, and ND–11.58 ng g−1, respectively. The main products in this park are medicines, pesticides, and novel materials. As for the species of VOCs, aromatic hydrocarbons were the dominant VOCs in the soil samples, whereas halogenated aliphatic hydrocarbons were the dominant VOCs in the water samples. The VOCs concentrations in water samples collected at different locations varied by 1–3 orders of magnitude, and the average concentration in river water inside the park was obviously higher than that in river water outside the park. However, the risk quotients for most of the VOCs indicated a low risk to the relevant, sensitive aquatic organisms in the river water. The average VOCs concentration in soil from the park was slightly higher than that from the adjacent area. This result showed that the chemical industrial park had a limited impact on the surrounding soil, while the use of pesticides, incomplete combustion of coal and biomass, and automobile exhaust emissions are all potential sources of the VOCs in the environmental soil. The results of this study could be used to evaluate the effects of VOCs emitted from chemical production and transportation in the park on the surrounding environment.

scholarly journals Characteristics and Sources of Selected Halocarbon and Hydrocarbon Volatile Organic Compounds in Surface Water of the Han River Basin

Water ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 2568
Author(s):  
Jong Kwon Im ◽  
Sujin Kim ◽  
Young Seuk Kim ◽  
Hye Ran Noh ◽  
Young-Min Lee ◽  
...  
Keyword(s):  
Surface Water ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Rural Areas ◽  
Total Concentration ◽  
Average Concentration ◽  
Gas Chromatography Mass Spectrometry ◽  
Han River ◽  
Detection Frequency ◽  
Volatile Organic

Volatile organic compounds (VOCs) are ubiquitous pollutants in surface water, which is the main source of drinking water in South Korea. We investigated the behavior (concentration, distribution, and environmental risk) of eleven selected VOCs in the surface water of the Han River tributaries using purge-and-trap gas chromatography/mass spectrometry. The average concentration of VOCs was 0.29 ± 0.47 μg/L. Chloroform and trichloroethylene (TCE) were the major pollutants, accounting for approximately 64.2% and 25.6% of the total concentration, respectively, and showing that halocarbons accounted for 94%. Chloroform was positively correlated with TCE and xylenes, and TCE was positively correlated with tetrachloroethylene (PCE). No differences were observed in the temporal average concentrations of total VOCs, but the concentrations differed significantly among sub-watershed areas. The Imjin-Hantan River, Han River mainstream, and Anseong Stream watersheds had a high positive association with TCE, whereas the Bukhan and Namhan River watersheds had a strong positive link with chloroform. The contamination and detection frequency of VOCs were highest in industrial complexes, followed by urban and rural areas. Thus, point source pollution significantly contributed to VOC contamination of these tributaries. Risk quotients for most VOCs were <1, suggesting negligible risk. Considering the relatively high occurrence of VOCs and their potential ecological risks, continuous environmental monitoring and study of environmental impacts based on ecotoxicity studies of domestic aquatic species are warranted.

Distribution of volatile organic compounds (VOCs) in surface water, soil, and groundwater within a chemical industry park in Eastern China

2014 ◽  
Vol 71 (2) ◽  
pp. 259-267 ◽  
Author(s):  
Benhua Liu ◽  
Liang Chen ◽  
Linxian Huang ◽  
Yongseng Wang ◽  
Yuehua Li
Keyword(s):  
Surface Water ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Chemical Industry ◽  
Boiling Point ◽  
Eastern China ◽  
Boiling Points ◽  
Volatile Organic ◽  
Industry Wastewater

This paper focuses on the distribution of volatile organic compounds (VOCs) in the surface water, soil, and groundwater within a chemical industry park in Eastern China. At least one VOC was detected in each of the 20 sampling sites, and the maximum number of VOCs detected in the surface water, groundwater, and soil were 13, 16, and 14, respectively. Two of the 10 VOCs with elevated concentrations detected in surface water, groundwater, and soil were chloroform and 1,2-dichloroethane. The characteristics of VOCs, which include volatility, boiling point, and solubility, could significantly affect their distribution in surface water, soil, and groundwater. However, due to the direct discharging of chemical industry wastewater into surface water, higher concentrations of VOCs (except chloroform) were detected in surface water than in soil and groundwater. Fortunately, the higher volatility of VOCs prevents the VOCs from impacting groundwater, which helps to maintain a lower concentration of VOCs in the groundwater than in both surface water and soil. This is because pollutants with relatively higher boiling points and lower solubilities have higher detection frequencies in soil, and contaminants with relatively lower boiling points and higher solubilities have higher detection frequencies in water, notably in surface water.

scholarly journals Geographical Distribution and Risk Assessment of Volatile Organic Compounds in Tributaries of the Han River Watershed

Agronomy ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 956
Author(s):  
Jong-Kwon Im ◽  
Yong-Chul Cho ◽  
Hye-Ran Noh ◽  
Soon-Ju Yu
Keyword(s):  
Volatile Organic Compounds ◽  
South Korea ◽  
Organic Compounds ◽  
Control Strategies ◽  
Anthropogenic Activities ◽  
River Watershed ◽  
Han River ◽  
Detection Frequency ◽  
Volatile Organic ◽  
Mean Concentration

Volatile organic compounds (VOCs), with negative impacts on the aquatic ecosystem, are increasingly released into the environment by anthropogenic activities. Water samples were collected from five areas of the Han River Watershed (HRW) tributaries, South Korea, to detect 11 VOCs, which were classified as halogenated aliphatic hydrocarbons (HAHs) and aromatic hydrocarbons (AHs). Among the 11 VOCs, 1,1-dichloroethylene, 1,1,1-trichloroethane, and vinyl chloride were undetected. The highest concentration compounds were chloroform (0.0596 ± 0.1312 µg/L), trichloroethylene (0.0253 ± 0.0781 µg/L), and toluene (0.0054 ± 0.0139 µg/L). The mean concentration (0.0234 µg/L) and detection frequency (37.0%) of HAHs were higher than those of AHs (0.0036 µg/L, 21.0%, respectively). The Imjin Hantan River area exhibited the highest mean concentration (0.2432 µg/L) and detection frequency (22.9%), because it is located near industrial complexes, thus, highlighting their role as important VOC sources. However, the detected VOCs had lower concentrations than those permitted by the EU, WHO, USA, and South Korea drinking water guidelines. Ecological risks associated with the VOCs were estimated by risk quotient (RQ); consequently, the predicted no-effect concentration was 0.0029 mg/L, and the toluene and styrene RQ values were >1 and >0.5, respectively. The findings may facilitate policymakers in designing pollution control strategies.

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