Effect of different carriers and operating parameters on degradation of flax wastewater by fluidized-bed Fenton process

2015 ◽  
Vol 71 (12) ◽  
pp. 1760-1767 ◽  
Author(s):  
Mengtian Chen ◽  
Hongqiang Ren ◽  
Lili Ding ◽  
Baotian Gao
Keyword(s):  
Fluidized Bed ◽  
Removal Rate ◽  
Fenton Process ◽  
Fenton Reagent ◽  
Operational Conditions ◽  
Paper Making ◽  
Toc Removal ◽  
Operating Factor ◽  
Bed Expansion ◽  
Kinetics Of

This investigation evaluates the effectiveness of a fluidized-bed Fenton process in treating flax wastewater. Flax wastewater was taken from a paper-making factory in a secondary sedimentation tank effluent of a paper-making factory in Hebei. The performance of three carriers (SiO2, Al2O3, Fe2O3) used in the reactor was compared, and the effects of different operational conditions, and Fenton reagent concentrations were studied. Experimental results indicated that SiO2 was the most appropriate carrier in the system. The dose of Fe2+ and H2O2 was a significant operating factor in the degradation progress. The bed expansion was considered to be another factor influencing the treatment effect. Under the appropriate conditions (300 mg/L Fe2+, 600 mg/L H2O2, and 74.07 g/L SiO2 as the carrier, at pH = 3, 50% bed expansion), the highest removal rate of total organic carbon (TOC) and color was 89% and 94%, respectively. The article also discussed the process of the colority removal of flax wastewater and the kinetics of TOC removal.

Kinetics of nitrobenzene oxidation and iron crystallization in fluidized-bed Fenton process

2009 ◽  
Vol 165 (1-3) ◽  
pp. 874-880 ◽  
Author(s):  
Jin Anotai ◽  
Pasootah Sakulkittimasak ◽  
Nonglak Boonrattanakij ◽  
Ming-Chun Lu
Keyword(s):  
Fluidized Bed ◽  
Fenton Process ◽  
Nitrobenzene Oxidation ◽  
Kinetics Of

The Kinetics of Glucose Decomposition with Sulfate Reduction in the Anaerobic Fluidized Bed Reactor

1993 ◽  
Vol 28 (2) ◽  
pp. 135-144 ◽  
Author(s):  
S. Matsui ◽  
R. Ikemoto Yamamoto ◽  
Y. Tsuchiya ◽  
B. Inanc
Keyword(s):  
Sulfate Reduction ◽  
Fluidized Bed ◽  
Kinetic Equations ◽  
Fluidized Bed Reactor ◽  
Order Reaction ◽  
First Order Reaction ◽  
First Order ◽  
Glucose Decomposition ◽  
Reaction Equations ◽  
Kinetics Of

Using a fluidized bed reactor, experiments on glucose decomposition with and without sulfate reduction were conducted. Glucose in the reactor was mainly decomposed into lactate and ethanol. Lactate was mainly decomposed into propionate and acetate, while ethanol was decomposed into propionate, acetate, and hydrogen. Sulfate reduction was not involved in the decomposition of glucose, lactate, and ethanol, but was related to propionate and acetate decomposition. The stepwise reactions were modeled using either a Monod expression or first order reaction kinetics in respect to the reactions. The coefficients of the kinetic equations were determined experimentally. The modified Monod and first order reaction equations were effective at predicting concentrations of glucose, lactate, ethanol, propionate, acetate, and sulfate along the beight of the reactor. With sulfate reduction, propionate was decomposed into acetate, while without sulfate reduction, accumulation of propionate was observed in the reactor. Sulfate reduction accelerated propionate conversion into acetate by decreasing the hydrogen concentration.

Submerged upflow biotower operation and computer simulation

1994 ◽  
Vol 30 (11) ◽  
pp. 143-146
Author(s):  
Ronald D. Neufeld ◽  
Christopher A. Badali ◽  
Dennis Powers ◽  
Christopher Carson
Keyword(s):  
Computer Simulation ◽  
Benzoic Acid ◽  
Computer Model ◽  
Rate Constants ◽  
Batch Mode ◽  
Operational Conditions ◽  
First Order ◽  
Low Concentrations ◽  
Biological Transformation ◽  
Kinetics Of

A two step operation is proposed for the biodegradation of low concentrations (< 10 mg/L) of BETX substances in an up flow submerged biotower configuration. Step 1 involves growth of a lush biofilm using benzoic acid in a batch mode. Step 2 involves a longer term biological transformation of BETX. Kinetics of biotransformations are modeled using first order assumptions, with rate constants being a function of benzoic acid dosages used in Step 1. A calibrated computer model is developed and presented to predict the degree of transformation and biomass level throughout the tower under a variety of inlet and design operational conditions.

scholarly journals Hydrogen Production by Fluidized Bed Reactors: A Quantitative Perspective Using the Supervised Machine Learning Approach

J ◽  
2021 ◽  
Vol 4 (3) ◽  
pp. 266-287
Author(s):  
Zheng Lian ◽  
Yixiao Wang ◽  
Xiyue Zhang ◽  
Abubakar Yusuf ◽  
Lord Famiyeh ◽  
...  
Keyword(s):  
Machine Learning ◽  
Hydrogen Production ◽  
Fluidized Bed ◽  
Biomass Gasification ◽  
Supervised Machine Learning ◽  
Fluidized Bed Reactors ◽  
Hydrogen Yield ◽  
Carbon Conversion ◽  
Operational Parameters ◽  
Operational Conditions

The current hydrogen generation technologies, especially biomass gasification using fluidized bed reactors (FBRs), were rigorously reviewed. There are involute operational parameters in a fluidized bed gasifier that determine the anticipated outcomes for hydrogen production purposes. However, limited reviews are present that link these parametric conditions with the corresponding performances based on experimental data collection. Using the constructed artificial neural networks (ANNs) as the supervised machine learning algorithm for data training, the operational parameters from 52 literature reports were utilized to perform both the qualitative and quantitative assessments of the performance, such as the hydrogen yield (HY), hydrogen content (HC) and carbon conversion efficiency (CCE). Seven types of operational parameters, including the steam-to-biomass ratio (SBR), equivalent ratio (ER), temperature, particle size of the feedstock, residence time, lower heating value (LHV) and carbon content (CC), were closely investigated. Six binary parameters have been identified to be statistically significant to the performance parameters (hydrogen yield (HY)), hydrogen content (HC) and carbon conversion efficiency (CCE)) by analysis of variance (ANOVA). The optimal operational conditions derived from the machine leaning were recommended according to the needs of the outcomes. This review may provide helpful insights for researchers to comprehensively consider the operational conditions in order to achieve high hydrogen production using fluidized bed reactors during biomass gasification.

scholarly journals Photocatalytic-Fenton Process under Simulated Solar Radiation Promoted by a Suitable Catalyst Selection

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 885
Author(s):  
Aida M. Díez ◽  
Helen E. Valencia ◽  
Maria Meledina ◽  
Joachim Mayer ◽  
Yury V. Kolen'ko
Keyword(s):  
Methylene Blue ◽  
Solar Radiation ◽  
Water Scarcity ◽  
Published Data ◽  
Fenton Process ◽  
Optimal Conditions ◽  
Operational Conditions ◽  
The Future ◽  
Simulated Solar Radiation ◽  
Catalyst Selection

Considering water scarcity, photo-based processes have been presented as a depollution technique, which should be optimized in order to be applied in the future. For that, the addition of an active photocatalyst and the usage of solar radiation are mandatory steps. Thus, Fe3O4–SiO2–TiO2 was synthesized, and its performance was evaluated using simulated solar radiation and methylene blue as a model pollutant. Under optimal conditions, 86% degradation was attained in 1 h. These results were compared to recent published data, and the better performance can be attributed to both the operational conditions selection and the higher photocatalyst activity. Indeed, Fe3O4–SiO2–TiO2 was physico-chemically characterized with techniques such as XRD, N2 isotherms, spectrophotometry, FTIR, electrochemical assays and TEM.

scholarly journals Kinetics of Non-Enzymatic Synthesis of Dipeptide Cbz-Phe-Leu with AOT Reversed Micelles

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1003
Author(s):  
Michiaki Matsumoto ◽  
Tadashi Hano
Keyword(s):  
Enzymatic Synthesis ◽  
Maximum Yield ◽  
Side Reactions ◽  
Experimental Conditions ◽  
Operational Conditions ◽  
Ph Dependency ◽  
Optimum Water Content ◽  
Short Time ◽  
Kinetics Of ◽  
Aot Reversed Micelles

The non-enzymatic synthesis of N-benzyloxycarbonyl-L-phenylalanyl-L-leucine (Cbz-Phe-Leu) from lipophilic N-benzyloxycarbonyl-L-phenylalanine (Cbz-Phe) and hydrophilic L-leucine (Leu), by N, N’-dicyclohexylcarbodiimide (DCC) as a condensing agent, was carried out using a reversed micellar system composed of bis(2-ethylhexyl) sodium sulfosuccinate (AOT) as a surfactant and isooctane. We successfully synthesized Cbz-Phe-Leu in a short time and investigated the effects of its operational conditions, the DCC concentration, w0, and the pH on the kinetic parameters and the maximum yields. For dipeptide synthesis, we had to add an excess of DCC with the substrates because of the side reactions of Cbz-Phe. From the pH dependency of the reactivity, a partially cationic form of Leu was better for a synthesis reaction because of the enrichment of Leu at the interface by anionic AOT. The optimum water content on the dipeptide synthesis was w0 = 28 due to the competition of the peptide synthesis and the side reactions. The maximum yield of Cbz-Phe-Leu was 0.565 at 80 h under optimum experimental conditions.

Improved dark fermentation of cane molasses in mesophilic and thermophilic anaerobic fluidized bed reactors by selecting operational conditions

2020 ◽  
Vol 44 (13) ◽  
pp. 10442-10452 ◽  
Author(s):  
Tiago B. Ferreira ◽  
Gabriel C. Rego ◽  
Lucas R. Ramos ◽  
Camila A. Menezes ◽  
Edson L. Silva
Keyword(s):  
Fluidized Bed ◽  
Dark Fermentation ◽  
Fluidized Bed Reactors ◽  
Cane Molasses ◽  
Operational Conditions

Treatment of recalcitrant organic silicone wastewater by fluidized-bed Fenton process

2014 ◽  
Vol 132 ◽  
pp. 16-22 ◽  
Author(s):  
Jun Liu ◽  
Jun Li ◽  
Rongwu Mei ◽  
Fuchao Wang ◽  
Balasubramanian Sellamuthu
Keyword(s):  
Fluidized Bed ◽  
Fenton Process
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