Different types of carbon nanotube-based anodes to improve microbial fuel cell performance

2014 ◽  
Vol 69 (9) ◽  
pp. 1900-1910 ◽  
Author(s):  
N. Thepsuparungsikul ◽  
T. C. Ng ◽  
O. Lefebvre ◽  
H. Y. Ng
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Open Circuit ◽  
Hydroxyl Group ◽  
Innovative Technology ◽  
Carboxyl Group ◽  
Carbon Cloth ◽  
Filtration Method ◽  
Oh Groups ◽  
Fuel Cell Performance

The microbial fuel cell (MFC) is an innovative technology for producing electricity directly from biodegradable organic matter using bacteria. Among all the influenceable factors, anode materials play a crucial role in electricity generation. Recently, carbon nanotubes (CNTs) have exhibited promising properties as electrode material due to their unique structural, and physical and chemical properties. In this study, the impacts of CNT types in CNT-based anodes were investigated to determine their effect on both efficiency of wastewater treatment and power generation. The CNTs, namely single-walled CNT with carboxyl group (SWCNT), multi-walled CNT with carboxyl group (MWCNT-COOH) and multi-walled CNT with hydroxyl group (MWCNT-OH) were used to fabricate CNT-based anodes by a filtration method. Overall, MWCNTs provided better results than SWCNTs, especially in the presence of the -OH groups. The highest power and treatment efficiencies in MFC were achieved with an anode made of MWCNT-OH filtered on Poreflon membrane; the open circuit voltage attained was 0.75 V and the maximum power density averaged 167 mW/m2, which was 130% higher than that obtained with plain carbon cloth. In addition, MWCNT-OH is more cost-effective, further suggesting its potential to replace plain carbon cloth generally used for the MFC anode.

scholarly journals INFLUENCE OF CARBON BASED ELECTRODES ON THE PERFORMANCE OF THE MICROBIAL FUEL CELL

2017 ◽  
Vol 5 (4RAST) ◽  
pp. 7-16
Author(s):  
Omkar S Powar ◽  
Lakshminarayana Bhatta ◽  
Raghavendra Prasad ◽  
Krishna Venkatesh ◽  
A.V. Raghu
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
High Power ◽  
Microbial Fuel Cells ◽  
Bacillus Coagulans ◽  
Open Circuit ◽  
Carbon Cloth ◽  
Anode Chamber ◽  
Graphite Sheet ◽  
Fuel Cell Performance

In this study electricity generation was evaluated in a two chambered microbial fuel cell. Performance of microbial fuel cells using two bacteria, Klebsiella pneumoniae and Bacillus coagulans and using three different electrodes namely graphite blocks, carbon cloth and graphite sheet was studied. The device was operated under anaerobic condition in the anode chamber and parameters were recorded for a period of 48 hours. The performance of MFC was analyzed by the measurement of open circuit voltage, polarization curves, impedance curves and cyclic voltammetry. Among different combinations of electrode tested, carbon cloth electrode produced high power density (80 mW/m2). Graphite block gave much high power compared to sheet. Finally, performance was compared with Shewanellaputrefaciens. The current study explores the applicability of carbon electrode for MFC applications.

scholarly journals A Carbon-Cloth Anode Electroplated with Iron Nanostructure for Microbial Fuel Cell Operated with Real Wastewater

2020 ◽  
Vol 12 (16) ◽  
pp. 6538 ◽  
Author(s):  
Enas Taha Sayed ◽  
Hussain Alawadhi ◽  
Khaled Elsaid ◽  
A. G. Olabi ◽  
Maryam Adel Almakrani ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
Anode Surface ◽  
Carbon Cloth ◽  
Steady State Current ◽  
Real Wastewater ◽  
Improved Performance

Microbial fuel cell (MFC) is an emerging method for extracting energy from wastewater. The power generated from such systems is low due to the sluggish electron transfer from the inside of the biocatalyst to the anode surface. One strategy for enhancing the electron transfer rate is anode modification. In this study, iron nanostructure was synthesized on a carbon cloth (CC) via a simple electroplating technique, and later investigated as a bio-anode in an MFC operated with real wastewater. The performance of an MFC with a nano-layer of iron was compared to that using bare CC. The results demonstrated that the open-circuit voltage increased from 600 mV in the case of bare CC to 800 mV in the case of the iron modified CC, showing a 33% increase in OCV. This increase in OCV can be credited to the decrease in the anode potential from 0.16 V vs. Ag/AgCl in the case of bare CC, to −0.01 V vs. Ag/AgCl in the case of the modified CC. The power output in the case of the modified electrode was 80 mW/m2—two times that of the MFC using the bare CC. Furthermore, the steady-state current in the case of the iron modified carbon cloth was two times that of the bare CC electrode. The improved performance was correlated to the enhanced electron transfer between the microorganisms and the iron-plated surface, along with the increase of the anode surface- as confirmed from the electrochemical impedance spectroscopy and the surface morphology, respectively.

scholarly journals Acid Black 172 Dye Decolorization and Bioelectricity Generation by Microbial Fuel Cell with Filamentous Fungi on Anode

2018 ◽  
Vol 15 (4) ◽  
pp. 981-986 ◽  
Author(s):  
Mohamed E. Osman ◽  
Om-Kolthoum H. Khattab ◽  
Abo Elnasr A.A. ◽  
Abdel Basset S.
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Filamentous Fungi ◽  
Dye Decolorization ◽  
Open Circuit ◽  
Anode Chamber ◽  
Variable Parameters ◽  
Fuel Cell Performance ◽  
Maximum Current ◽  
Double Chamber

A microbial fuel cell (MFC) has great potential for azo dyes decolorization and electricity generation by using filamentous fungi as biocatalysts. In this study, Aspergillus niger and Trichoderma harzianum were inoculated in anode chamber of double-chamber MFC to decolorize azo dye acid black 172 with Potassium Ferricyanide in the cathode chamber. During MFC operations, Acid black 172 oxidized and produced a maximum open-circuit voltage of 890 mV, and maximum current density of 163 mA/m2 with an external resistance of 1000Ω. Also, variable parameters such as dye concentration, Co-substrate and dye as a sole carbon source were studied to improve microbial fuel cell performance.

A Study on Polythiophene Modified Carbon Cloth as Anode in Microbial Fuel Cell for Lead Removal

2021 ◽  
Author(s):  
Rajkumar Rajendran ◽  
Gnana Prakash Dhakshina Moorthy ◽  
Haribabu Krishnan ◽  
Sumisha Anappara
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Lead Removal ◽  
Carbon Cloth

Improved microbial fuel cell performance by encapsulating microbial cells with a nickel-coated sponge

2013 ◽  
Vol 41 ◽  
pp. 848-851 ◽  
Author(s):  
Xueying Liu ◽  
Xiaoyu Du ◽  
Xia Wang ◽  
Naiqiang Li ◽  
Ping Xu ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Cell Performance ◽  
Microbial Cells ◽  
Fuel Cell Performance

A Model of a High-Temperature Direct Methanol Fuel Cell

2013 ◽  
Vol 10 (5) ◽  
Author(s):  
K. Scott ◽  
S. Pilditch ◽  
M. Mamlouk
Keyword(s):  
Fuel Cell ◽  
Direct Methanol Fuel Cell ◽  
Proton Exchange Membrane ◽  
Open Circuit ◽  
Proton Exchange ◽  
Cell Performance ◽  
Effect Of Temperature ◽  
Fuel Cell Performance ◽  
Direct Methanol ◽  
Methanol Fuel Cell

A steady-state, isothermal, one-dimensional model of a direct methanol proton exchange membrane fuel cell (PEMFC), with a polybenzimidazole (PBI) membrane, was developed. The electrode kinetics were represented by the Butler–Volmer equation, mass transport was described by the multicomponent Stefan–Maxwell equations and Darcy's law, and the ionic and electronic resistances described by Ohm's law. The model incorporated the effects of temperature and pressure on the open circuit potential, the exchange current density, and diffusion coefficients, together with the effect of water transport across the membrane on the conductivity of the PBI membrane. The influence of methanol crossover on the cathode polarization is included in the model. The polarization curves predicted by the model were validated against experimental data for a direct methanol fuel cell (DMFC) operating in the temperature range of 125–175 °C. There was good agreement between experimental and model data for the effect of temperature and oxygen/air pressure on cell performance. The fuel cell performance was relatively poor, at only 16 mW cm−2 peak power density using low concentrations of methanol in the vapor phase.

Role of Biocatalyst in Microbial Fuel Cell Performance

2019 ◽  
pp. 85-105
Author(s):  
M. Amirul Islam ◽  
Ahasanul Karim ◽  
Puranjan Mishra ◽  
Che Ku Mohammad Faizal ◽  
Maksudur Rahman Khan ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Cell Performance ◽  
Fuel Cell Performance
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