Biodegradation of Bisphenol-A in aerobic membrane bioreactor sludge

2013 ◽  
Vol 68 (9) ◽  
pp. 1926-1931 ◽  
Author(s):  
Brahima Seyhi ◽  
Patrick Drogui ◽  
Gerardo Buelna ◽  
Jean François Blais
Keyword(s):  
Bisphenol A ◽  
Chemical Oxygen Demand ◽  
Rate Constant ◽  
Membrane Bioreactor ◽  
Oxygen Demand ◽  
Degradation Process ◽  
Order Kinetic ◽  
Kinetic Rate Constant ◽  
Kinetic Rate ◽  
First Order

Bisphenol-A (BPA) biodegradation was studied in a membrane bioreactor under aerobic conditions. The effects of the initial BPA concentration and initial chemical oxygen demand (COD) concentration on BPA biodegradation were investigated. The degradation process followed a first-order kinetic (more than 98% of BPA was removed) with a kinetic rate constant of 1.134 h−1 using an initial BPA concentration of 1.0 mg L−1. The kinetic rate constant decreased to 0.611 h−1 when the initial BPA concentration increased to 5.0 mg L−1. The initial COD concentration (400 and 2,000 mg L−1) did not affect the biodegradation kinetic of BPA.

The Best Way to Obtain Good Quality CVD-TiN Films from TiCl4 and NH3

1998 ◽  
Vol 514 ◽  
Author(s):  
Hirotaka Hamamura ◽  
Yukihiro Shimogaki ◽  
Yasunobu Akiyama ◽  
Yasuyuki Egashira ◽  
Hiroshi Komiyama
Keyword(s):  
Deposition Rate ◽  
Kinetic Studies ◽  
Chlorine Concentration ◽  
Residual Chlorine ◽  
Order Kinetic ◽  
Kinetic Rate Constant ◽  
Kinetic Rate ◽  
Tin Films ◽  
First Order ◽  
Kinetics Of

ABSTRACTTiN films deposited by CVD utilizing TiCl4 and NH3 are widely used in ULSI processes. The residual chlorine in the film is one of the major issues of TiCl4 based chemistry [1–5]. We have examined the kinetics of TiN-CVD using TiCl4 and NH3 as precursors to determine method for controlling the residual chlorine concentration.We analyzed the deposition rate profiles obtained from a simple tubular isothermal reactor. Deposition was performed over the temperature range from 300°C to 500°C and with varying initial concentrations of TiCl4 and NH3. We found that the deposition rate was independent of the TiCl4 concentration at higher concentrations. The deposition rate was proportional to the TiCl4 concentration in the low concentration range. This phenomenon can be well explained by a Langmuir-Hinshelwood type mechanism. Examination of the deposition rate dependence on the concentration of NH3 showed that both the maximum deposition rate at high TiCl4 concentrations and the first order kinetic rate constant in the lower TiCl4 concentration range were proportional to the NH3 concentration. These results indicate that the deposition was controlled by the Eley-Rideal mechanism. The residual chlorine concentration was found to be proportional to the surface coverage factor of adsorbed TiCl4. We conclude that the best way to obtain good quality TiN films can be obtained theoretically through these kinetic studies.

The in vivo regeneration of goldfish rhodopsin and porphyropsin

1986 ◽  
Vol 122 (1) ◽  
pp. 269-275
Author(s):  
A. T. Tsin ◽  
J. M. Flores
Keyword(s):  
Body Weight ◽  
Rate Constant ◽  
Half Life ◽  
Visual Pigment ◽  
Initial Period ◽  
Direct Result ◽  
Order Kinetic ◽  
Kinetic Rate Constant ◽  
First Order

Goldfish with retinas rich in either rhodopsin or porphyropsin were illuminated with bright light and then placed in the dark room to allow visual pigment regeneration. The kinetics of this in vivo pigment regeneration were followed by sampling these animals at regular time intervals. The first-order kinetic rate constant for the initial period of porphyropsin regeneration at 20 degrees C was 8.3 X 10(−3) nmol kg-1 body weight min-1 and the half-life of this reaction was 83 min. At 30 degrees C, the rate constant was increased to 1.4 X 10(−2) nmol kg-1 body weight min-1, yielding a reduced half-life of 49 min. This suggests that the Q10 of porphyropsin regeneration is about 1.7. In goldfish retinas enriched with rhodopsin (62% rhodopsin and 38% porphyropsin), the initial phase of visual pigment regeneration (at 30 degrees C) proceeded at a slower rate (first-order rate constant: 6.5 X 10(−3) nmol kg-1 body weight min-1; half-life of reaction = 106 min) than the rate of porphyropsin regeneration. This suggests that the high proportion of rhodopsin in the retina of goldfish held at 30 degrees C is not a direct result of a faster rate of regeneration of rhodopsin than of porphyropsin.

scholarly journals Oxidative degradation of gentamicin present in water by an electro-Fenton process and biodegradability improvement

2019 ◽  
Vol 17 (1) ◽  
pp. 1017-1025
Author(s):  
Mohamed Réda Arhoutane ◽  
Muna Shueai Yahya ◽  
Miloud El Karbane ◽  
Kacem El Kacemi
Keyword(s):  
Chemical Oxygen Demand ◽  
Biological Process ◽  
Oxidative Degradation ◽  
Oxygen Demand ◽  
Polluted Water ◽  
Applied Current ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Appropriate Treatment ◽  
By Products

AbstractIn the context of environmental protection, where there is a need to develop effective operations for carrying out appropriate treatment of polluted water by pharmaceuticals. Therefore, the present study aims at evaluating the degradation for gentamicin through electro-Fenton (EF) operation, through taking into consideration the effect of several parameters of experimental in the process, namely, the concentration of initial gentamicin, the applied current and the Fe+2 (II) quantities. The (EF) operation employed involves a carbon-felt as cathode and platinum as anode at pH 3. Studies for the gentamicin kinetics is monitored by HPLC giving a pseudo-first order reaction following by a chemical oxygen demand, with a reached degree of mineralization 96% after of four hours of treatment through current 100 mA/cm2 with 0.1 mM of Fe+2. We find that the degradation for molecule of gentamicin is accompanied by an augmentation of the biodegradability, assesse through the Biochemical Oxygen Demand (BOD5) on chemical oxygen demand (COD) ratio, that augmentation from 0 to 0.41 before treatment after 30 min for EF treatment, showing that there is potential for conjugation of the EF process and the biological process. Furthermore, the by-products have been identified on the basis of HPLC-MS/MS results.

scholarly journals Ozone Application for Tofu Waste Water Treatment and Its Utilisation for Growth Medium of Microalgae Spirulina sp

2018 ◽  
Vol 31 ◽  
pp. 03002 ◽  
Author(s):  
Hadiyanto Hadiyanto
Keyword(s):  
Waste Water ◽  
Waste Water Treatment ◽  
Oxygen Demand ◽  
Ozone Treatment ◽  
Order Kinetic ◽  
Pollution Load ◽  
First Order ◽  
Degradation Rate Constant ◽  
Nitrogen Contents ◽  
Microalgae Growth

Tofu industries produce waste water containing high organic contents and suspendid solid which is harmful if directly discharged to the environment. This waste can lead to disruption of water quality and lowering the environmental carrying capacity of waters around the tofu industries. Besides, the tofu waste water still contains high nitrogen contents which can be used for microalgae growth. This study was aimed to reduce the pollution load (chemical oxygen demand-COD) of tofue wastewater by using ozone treatments and to utilize nutrients in treated tofu waste water as medium growth of microalgae. The result showed that the reduction of COD by implementation of ozone treatment followed first order kinetic. Under variation of waste concentrations between 10-40%, the degradation rate constant was in the range of 0.00237-0.0149 min-1. The microalgae was able to grow in the tofue waste medium by the growth rate constants of 0.15-0.29 day-1. This study concluded that tofu waste was highly potent for microalgae growth.

Degradation of wine distillery wastewaters by the combination of aerobic biological treatment with chemical oxidation by Fenton's reagent

2005 ◽  
Vol 51 (1) ◽  
pp. 167-174 ◽  
Author(s):  
J. Beltran de Heredia ◽  
J. Torregrosa ◽  
J.R. Dominguez ◽  
E. Partido
Keyword(s):  
Chemical Oxygen Demand ◽  
Aromatic Compounds ◽  
Biological Treatment ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Chemical Oxidation ◽  
Utilization Rate ◽  
Fenton’S Reagent ◽  
Kinetic Rate Constant ◽  
Fenton's Reagent

The degradation of wine distillery wastewaters by aerobic biological treatment has been investigated in a batch reactor. The evolution of the chemical oxygen demand, biomass and total contents of polyphenolic and aromatic compounds was followed through each experiment. According to the Contois model, a kinetic expression for the substrate utilization rate is derived, and its biokinetic constant is evaluated. The final effluents of the aerobic biological experiments were oxidized by Fenton's reagent. The evolution of chemical oxygen demand, hydrogen peroxide concentration and total contents of polyphenolic and aromatic compounds was followed through each experiment. A kinetic model to interpret the experimental data is proposed. The kinetic rate constant of the global reaction is determined.

scholarly journals Effect of applied voltage on membrane fouling in the amplifying anaerobic electrochemical membrane bioreactor for long-term operation

RSC Advances ◽  
2021 ◽  
Vol 11 (50) ◽  
pp. 31364-31372
Author(s):  
Mengjing Cao ◽  
Yongxiang Zhang ◽  
Yan Zhang
Keyword(s):  
Chemical Oxygen Demand ◽  
Applied Voltage ◽  
Membrane Fouling ◽  
Membrane Bioreactor ◽  
Glucose Solution ◽  
Oxygen Demand ◽  
Term Operation ◽  
Long Time

A novel and amplifying anaerobic electrochemical membrane bioreactor was constructed and operated for a long time (204 days) with synthetic glucose solution having an average chemical oxygen demand (COD) of 315 mg L−1, at different applied voltages and room temperatures.

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