Adsorption characteristics of ammonium exchange by zeolite and the optimal application in the tertiary treatment of coking wastewater using response surface methodology

2013 ◽  
Vol 67 (3) ◽  
pp. 619-627 ◽  
Author(s):  
Cui Zhao ◽  
Zhongyuan Zheng ◽  
Jing Zhang ◽  
Donghui Wen ◽  
Xiaoyan Tang

Natural zeolite is a favorable NH4+-ion exchanger in the tertiary wastewater treatment. In this study, a natural Chinese zeolite was anatomized using the mercury injection method, X-ray diffraction, and scanning electron micrographs. The kinetic process of ammonium adsorption onto the zeolite was best described by the pseudo second order model; the adsorption equilibrium data fitted better to the Freundlich isotherm; and the exchange between ammonium and alkali/alkaline earth cations was in the order of Na+ > Ca2+ > K+ > Mg2+. Finally, the zeolite powder was applied for the tertiary treatment of coking wastewater, which still contained high concentration of ammonium after the secondary treatment by a sequencing batch reactor. The Box–Behnken design was used to design the experimental protocol, and the response surface methodology (RSM) was used for the optimization of adsorption factors. The RSM analysis showed the optimal adsorption factors as particle size, 0.03 mm; initial dosage of zeolite powder, 50.0 g/L; and contact time, 24 h. The highest ammonium removal rate was 75.0% predicted by the RMS. Considering settleability of the zeolite powder, the particle size of 0.25 mm was recommended in practice with a little loss of the ammonium removal: 70.9% as the RMS predicted.

2011 ◽  
Vol 366 ◽  
pp. 361-365
Author(s):  
Li Ping Wu ◽  
Dian Mo Zheng ◽  
Sheng Gan Zhu

The CCD mathematical model of response surface methodology (RSM) has been used to optimize the process parameters of treating kaolin wastewater, the interaction of the factors on removal rate of turbidity and average particle size of floc such as the flocculation temperature ,the pH value, the dosage of PAC, the dosage of St-PAM were studied. The optimum condition of the effluent disposal via the experiment was as follows: the flocculation temperature was 25°C,the pH value was 6.5, the dosage of PAC was 21.5/mg/L, the dosage of St-PAM was 5/mg/L.In these conditions,the turbidity removal rate of the kaolin wastewater was 97.56%,and the average particle size of flocculation body was 0.994mm. Under the optimum conditions, the removal rate of turbidity and the average particle size of flocculation body was respectively 98.05% and 1.09mm.The model had good prediction effect.


2018 ◽  
Vol 49 (2) ◽  
pp. 62-81 ◽  
Author(s):  
Shailendra Kumar ◽  
Bhagat Singh

Tool chatter is an unavoidable phenomenon encountered in machining processes. Acquired raw chatter signals are contaminated with various types of ambient noises. Signal processing is an efficient technique to explore chatter as it eliminates unwanted background noise present in the raw signal. In this study, experimentally recorded raw chatter signals have been denoised using wavelet transform in order to eliminate the unwanted noise inclusions. Moreover, effect of machining parameters such as depth of cut ( d), feed rate ( f) and spindle speed ( N) on chatter severity and metal removal rate has been ascertained experimentally. Furthermore, in order to quantify the chatter severity, a new parameter called chatter index has been evaluated considering aforesaid denoised signals. A set of 15 experimental runs have been performed using Box–Behnken design of experiment. These experimental observations have been used to develop mathematical models for chatter index and metal removal rate considering response surface methodology. In order to check the statistical significance of control parameters, analysis of variance has been performed. Furthermore, more experiments are conducted and these results are compared with the theoretical ones in order to validate the developed response surface methodology model.


2020 ◽  
Vol 83 (1) ◽  
pp. 85-92
Author(s):  
Mohd Azahar Mohd Ariff ◽  
Muhammad Syafiq Abd Jalil ◽  
Noor ‘Aina Abdul Razak ◽  
Jefri Jaapar

Caesalpinia sappan linn. (CSL) is a plant which is also known as Sepang tree contains various medicinal values such as to treat diarrhea, skin rashes, syphilis, jaundice, drinking water for blood purifying, diabetes, and to improve skin complexion. The aim of this study is to obtain the most optimum condition in terms of the ratio of sample to solvent, particle size, and extraction time to get the highest amount of concentration of the CSL extract. In this study, the ranges of each parameters used were: ratio sample to solvent: 1.0:20, 1.5:20, 2.0:20, 2.5:20, 3.0:20, particle size: 1 mm, 500 um, 250 um, 125 um, 63 um, and extraction time: 1 hr, 2 hr, 3 hr, 4 hr, 5 hr. The concentration was analyzed using a UV-vis spectrophotometer. The optimum conditions were obtained by response surface methodology. From the design, 20 samples were run throughout this experiment. The optimized value from the RSM were 2.0:20 for ratio sample to solvent, 125 µm of particle size and 2.48 hours with the concentration of 37.1184 ppm. The accuracy of the predictive model was validated with 2 repeated runs and the mean percentage error was less than 3%. This confirmed the model’s capability for optimizing the conditions for the reflux extraction of CSL’s wood.


2012 ◽  
Vol 518-523 ◽  
pp. 2073-2078 ◽  
Author(s):  
Qi You Liu ◽  
Yun Bo Zhang ◽  
Dong Feng Zhao ◽  
Chao Cheng Zhao

A response surface methodology was applied to optimize the bioremediation condition of hydrocarbon in soil by microbial consortium KL9-1. A four-level Box-Behnken factorial design was employed to study the relationship of independent variables and dependent variable by applying pH value, inoculation amount of microbial consortium KL9-1, ratio of nitrogen and phosphorus (N/P ) and surfactant (SDBS) concentration as independent variables (factors) and crude oil removal rate as dependent variable (response). Then the statistically significant model was obtained and numerical optimization based on desirability function was carried out for pH 7.0, inoculation amount 50.0 mL, N/P 2: 1 and SDBS concentration 4.0 g, and the hydrocarbon removal rate reached as high as 52.58%. The predictive values showed good agreement with the experimental values under the optimization conditions, by standard variance <1.3%. It showed that the optimal result was reliable.


Processes ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 449
Author(s):  
Panawan Suttiarporn ◽  
Nalin Wongkattiya ◽  
Kittisak Buaban ◽  
Pisit Poolprasert ◽  
Keerati Tanruean

The main goal of the research was to optimize microwave-assisted simultaneous distillation and extraction (MA-SDE) using response surface methodology (RSM), based on Box–Behnken design (BBD). A process was designed to extract the essential oil from the leaf sheath of Siam cardamom. The experimental data were fitted to quadratic equations, and the experiment conditions for optimal extraction of 1,8-cineole were extraction time 87.68 min, material-to-water ratio 1:13.18 g/mL and microwave power 217.77 W. Under such conditions, the content of 1,8-cineole was 157.23 ± 4.23 µg/g, which matched with the predicted value. GC–MS results indicated the presence of predominant oxygenated monoterpenes including 1,8-cineole (20.63%), iso-carveol (14.30%), cis-p-mentha-1(7),8-dien-2-ol (12.27%) and trans-p-2,8-menthadien-1-ol (9.66%), and oxygenated contents were slightly higher in the MA-SDE and extraction compared to usual SDE. In addition, the essential oil extracted by MA-SDE exhibited strong antibacterial effects against the tested Gram-positive bacteria. Scanning electron micrographs provided more evidence of destruction of the leaf sheath treated by MA-SDE. Conclusively, microwave-assisted simultaneous distillation and solvent extraction appear to be an effective technique for the separation of essential oils enriched 1,8-cineole from Siam cardamom leaf sheath in a shorter time.


2018 ◽  
Vol 7 (3.1) ◽  
pp. 162 ◽  
Author(s):  
Ramanan. G ◽  
Rajesh Prabha.N ◽  
Diju Samuel.G ◽  
Jai Aultrin. K. S ◽  
M Ramachandran

This manuscript presents the influencing parameters of CNC turning conditions to get high removal rate and minimal response of surface roughness in turning of AA7075-TiC-MoS2 composite by response surface method. These composites are particularly suited for applications that require higher strength, dimensional stability and enhanced structural rigidity. Composite materials are engineered materials made from at least two or more constituent materials having different physical or chemical properties. In this work seventeen turning experiments were conducted using response surface methodology. The machining parameters cutting speed, feed rate, and depth of cut are varied with respect to different machining conditions for each run. The optimal parameters were predicted by RSM technique. Turning process is studied by response surface methodology design of experiment. The optimal parameters were predicted by RSM technique. The most influencing process parameter predicted from RSM techniques in cutting speed and depth of cut.   


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