Application of an anaerobic hybrid reactor for petrochemical effluent treatment

2012 ◽  
Vol 65 (12) ◽  
pp. 2098-2105 ◽  
Author(s):  
Mohammad Taghi Jafarzadeh ◽  
Naser Mehrdadi ◽  
Seyed Jamaladdin Hashemian

An anaerobic hybrid reactor (UASB/Filter) was used for petrochemical wastewater treatment in mesophilic conditions. The seeded flocculent sludge from a UASB plant treating dairy wastewater, acclimatized to the petrochemical wastes in a two-stage operation. After start up, under steady-state conditions, experiments were conducted at OLRs of between 0.5 and 24 kg TCOD m−3 d−1, hydraulic retention times (HRT) of 4–48 h and up-flow velocities 0.021–0.25 mh−1. Removal efficiencies in the range of 42–86% were achieved at feed TCOD concentrations of 1,000–4,000 mg L−1. The results of reactor performance at different operational conditions and its relations are presented and discussed in this paper. Then, the obtained data are used for determination of kinetic models. The results showed that a second-order model and a modified Stover–Kincannon model were the most appropriate models for this reactor. Finally, the biogas production data were used for the determination of biogas production kinetics.

2021 ◽  
Vol 14 ◽  
pp. 51-57
Author(s):  
M.T. Jafarzadeh ◽  
N. Jamshidi ◽  
L. Talebiazar ◽  
R. Aslaniavali

Organic loading rate (OLR), Hydraulic Retention Time (HRT) and up flow velocity are important parameters significantly affecting microbial ecology and characteristics of anaerobic reactors. In this study, Performance of an anaerobic hybrid reactor (UASB/Filter) at mesophilic condition was evaluated in a 15.4 L reactor receiving petrochemical wastewater. The temperature of influent was adjusted by an inline heat exchanger at around 35 ˚C. The reactor was seeded with flocculent sludge from a UASB plant treating dairy wastewater. The sludge was acclimatized to petrochemical wastewater in twostage operation. After 39 weeks, a COD reduction of 70.3% was obtained at OLR=2.0 kg m-3 d-1 and HRT=18 h. Under steady state conditions, experiments were conducted at OLRs of between 0.5 and 24 kg TCOD m-3 d-1 , hydraulic retention times (HRT) of 4-48 h and up flow velocities 0.021-0.25 m h-1. Removal efficiencies in the range of 42-86% were achieved at feed TCOD concentrations of 1000- 4000 mg L-1 . The biogas production data used for determination of biogas production kinetics. The values of Gmax and GB estimated as 11.173 LL-1d -1 and 85.83 g L-1d -1 , respectively.


2015 ◽  
Vol 17 (2) ◽  
pp. 84-88 ◽  
Author(s):  
Kiran D. Bhuyar ◽  
Sanvidhan G. Suke ◽  
S.D. Dawande

Abstract An up-flow anaerobic packed bed (UAPB) bioreactor has been designed on a laboratory-scale and used for treatment of domestic milk wastewater (MWW). The UAPB bioreactor was operated under mesophilic temperature (37-45°C) and reactor performance evaluated at various organic loading rates of MWW effluent at hydraulic retention times (HRT) of 1, 2, and 3 d based on the removal of organic matter COD, BOD, SS, pH changes and biogas production. The kinetic parameters were estimated using the experimental data to develop a reactor model. Empirical relations were generated for the characteristics like COD, BOD, and SS using modeling equations. This study proved that the UAPB reactor performance is excellent for treating domestic MWW and easily biodegradable dairy wastewater influent. Hence, this system can operate at low costs, making it suited for use in the developing countries and rural areas.


2003 ◽  
Vol 48 (8) ◽  
pp. 79-87 ◽  
Author(s):  
B. Suraruksa ◽  
A. Nopharatana ◽  
P. Chaiprasert ◽  
M. Tanticharoen ◽  
S. Bhumiratana

With an aim to shorten start-up time of an Anaerobic Hybrid Reactor (AHR), initial biofilm development was studied, particularly at different upflow feeding velocities. At a low (0.01 m·h-1) upflow velocity, initial biofilm was found to develop via the attachment of suspended biomass in the packed zone, while microbial growth on the film was insignificant. Contrarily, with higher (1.0 m·h-1) upflow velocity, initial biofilm development was from both microbial attachment and growth on supporting media. Biofilm thickness was determined using confocal laser scanning microscopy (CLSM), which indicated that the biofilm developed faster with the higher velocity, due to the contribution of the microbial growth on supporting media. When operated beyond the initial biofilm development with the lower velocity, both the activity of acetogens and the methanogens increased, although there was a lower amount of attached biomass on the supporting media. Whereas, both groups were found to decrease with higher upflow velocity, but acidogenic activity increased. It can be concluded that higher upflow velocity positively affected the initial stage of biofilm development and has the potential to accelerate attached biomass on supporting media during the initial phase. Subsequently, the upflow velocity should be reduced to the normal rate to enhance the methanogenic activity.


2001 ◽  
Vol 44 (4) ◽  
pp. 137-144 ◽  
Author(s):  
M. De Almeida Prado Montenegro ◽  
E. De Mattos Moraes ◽  
H. Moreira Soares ◽  
R. Filomena Vazoller

The present research aimed at evaluating pentachlorophenol (PCP) degradation in a hybrid reactor supplied with a mixture of fatty acids (propionic, butyric, acetic and lactic) and methanol. The performance of the reactor is remarkably stable and efficient during PCP additions at range of 2.0 to 21.0 mg/L. The reduction of chemical oxygen demand (COD) was around 97% and methane was found to be 86% in the biogas production. The efficiency of volatile fatty acids breakdown was 93%, 64% and 74% respectively for butyric, propionic and acetic. PCP total removal of more than 99% was reached by granular sludge activities formed during 21 months of reactor operation. Methanogenic microorganisms predominance was noticed with 105 to 106 cells/mL during enumeration on methanol or lactate added to sulfate culture media. The removal rate was 1.07 mg PCP · g−1 VS · d−1 during the highest PCP concentration addition.


1996 ◽  
Vol 34 (5-6) ◽  
pp. 509-515 ◽  
Author(s):  
Huub J. Gijzen ◽  
Frank Kansiime

The start-up and performance of an Upflow Anaerobic Sludge Blanket (UASB) reactor and a Polyurethane Carrier Reactor (PCR) was investigated under similar operational conditions. The presence of polyurethane cubes as a carrier material in the PCR resulted in fast reactor start-up due to quick immobilization of methanogenic associations. Start-up of the UASB was slower compared to the PCR, which was mainly reflected in a lower biogas production and acetate degradation efficiency. However, when enough biomass had accumulated in the UASB reactor after 15 weeks of operation, the performance of the two reactors was almost the same in terms of biogas production and volatile fatty acids degradation. Efficient VFA degradation (about 90%) and biogas production (5.2 l/l.d) were achieved at an organic loading rate of 13.2 g/l.d) and HRT of 6 h. When hydraulic retention time was subsequently reduced from 6 to 2 h, the performance of the UASB reactor was better than that of the PCR. The inferior performance of the PCR may have been attributed to channelling of the influent in the reactor at high liquid flow rate.


1999 ◽  
Vol 39 (10-11) ◽  
pp. 99-106 ◽  
Author(s):  
Diana Loaiza Cadavid ◽  
Marcelo Zaiat ◽  
Eugenio Foresti

The performance of a bench-scale horizontal-flow anaerobic immobilized sludge (HAIS) reactor treating a synthetic substrate under increasing influent sulfate (SO42-) concentrations was investigated. The synthetic substrate was composed of glucose, methanol and ammonium acetate, besides bicarbonate and trace metal nutritional solution. The reactor was filled with polyurethane foam cubic matrices for biomass immobilization. Influent chemical oxygen demand (COD) was kept almost constant along the experiments (2162 ± 250 mg.l−1) while influent sulfate concentration was increased from 9 to 501 mg.l−1, resulting in COD/SO42- ratio of 249, 66, 19.7 and 4.3 in the four experimental phases tested. After a short start-up period, no significant variations in COD removal efficiency were observed for the COD to sulfate ratios evaluated. Although sulfate reduction was expected to interfere with the methanogenic process, detrimental effects on the overall reactor performance were not observed. Moreover, monitoring parameters indicated that the reactor achieved stable operational conditions immediately after short transient periods following the increase of influent sulfate concentrations. Microscopic analysis of the sludge within the reactor permitted to observe the presence of both methanogenic and sulfate reducing bacteria, indicating that syntrophism and not competition seemed to be the predominant relationship between these two groups under the COD to sulfate ratios assayed.


2002 ◽  
Vol 38 (1) ◽  
pp. 73-79 ◽  
Author(s):  
Nurdan Büyükkamaci ◽  
Ayse Filibeli

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