Heavy metal adsorption changes of EAF steel slag after phosphorus adsorption

2012 ◽  
Vol 65 (9) ◽  
pp. 1570-1576 ◽  
Author(s):  
Guanling Song ◽  
Lijing Cao ◽  
Xiao Chen ◽  
Wenhua Hou ◽  
Qunhui Wang
Keyword(s):  
Heavy Metal ◽  
Metal Ion ◽  
Steel Slag ◽  
Ion Concentration ◽  
Metal Adsorption ◽  
Heavy Metal Ion ◽  
Heavy Metal Adsorption ◽  
Isothermal Adsorption ◽  
Phosphorus Adsorption ◽  
Cadmium And Lead

A kind of electric arc furnace (EAF) steel slag was phosphated, and its isothermal and dynamic adsorptions of copper, cadmium, and lead ions were measured to determine if heavy metal adsorption changes after phosphorus adsorption. The surface area increased greatly after the slag was phosphated. Isothermal adsorption experiments showed that the theoretical Qmax of the EAF steel slag on Cu2+, Cd2+, and Pb2+ improved 59, 50, and 89% respectively after it was phosphated. Dynamic adsorption results showed that the greatest adsorption capacities of unit volume of Cu2+, Cd2+, and Pb2+ were 2.2, 1.8, and 1.8 times that of the column packed with original EAF steel slag when the column was packed with phosphate EAF steel slag at the same heavy metal ion concentration. The breakthrough time, the exhaustion time and elution efficiency of the column also increased when the column was packed with phosphated EAF steel slag compared with that packed with original EAF steel slag. Phosphorus adsorption could further improve the heavy metal ion adsorption of the EAF steel slag.

scholarly journals Synthesis, Characterization of a New Polyacrylic Acid Superabsorbent, Some Heavy Metal Ion Sorption, the Adsorption Isotherms, and Quantum Chemical Investigation

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4390
Author(s):  
Sevil Savaskan Yilmaz ◽  
Nuri Yildirim ◽  
Murat Misir ◽  
Yasin Misirlioglu ◽  
Emre Celik
Keyword(s):  
Heavy Metal ◽  
Quantum Chemical ◽  
Metal Ion ◽  
Molecular Mechanic ◽  
Ion Concentration ◽  
Heavy Metal Ion ◽  
Competitive Sorption ◽  
Cross Linker ◽  
The Cross

Poly(acrylic acid/Kryptofix 23-Dimethacrylate) superabsorbent polymer [P (AA/Kry23-DM) SAP] was synthesized by solution polymerization to remove Co, Ni, Cu, Cd, Mn, Zn, Pb, Cr, and Fe ions in water and improve the quality of the water. Kry23-DM cross-linker (1,4,7,13,16-Pentaoxa-10,19 diazo cyclohexene icosane di methacrylate) was synthesized using Kry23 and methacryloyl chloride. The characterization of the molecules was done by FTIR, TGA, DSC, and SEM techniques. The effects of parameters such as pH, concentration, and the metal ion interaction on the heavy metal ions uptaking of SAP was investigated. It was observed that P (AA/Kry23-DM) SAP has maximum water absorption, and the absorption increases with the pH increase. Adsorption rates and sorption capacity, desorption ratios, competitive sorption (qcs), and distribution coefficient (log D) of P(AA/Kry23-DM) SAP were studied as a function of time and pH with the heavy metal ion concentration. Langmuir and Freundlich isotherms of the P (AA/Kry23-DM) SAP were investigated to verify the metal uptake. Molecular mechanic (MM2), Assisted Model Building with Energy Refinement (AMBER), and optimized potentials for liquid simulations (OPLS) methods. were used in quantum chemical calculations for the conformational analysis of the cross-linker and the SAP. ΔH0f calculations of the cross-linker and the superabsorbent were made using Austin Model 1(AM1) method.

scholarly journals Characteristics of Phosphorus Adsorption and Release in Different Types of Sediments

2020 ◽  
Vol 8 (05) ◽  
pp. 342-354
Author(s):  
Pengqiang Yang ◽  
Huanghe ◽  
Rujun Gao
Keyword(s):  
Heavy Metal ◽  
Particle Size ◽  
Organic Matter ◽  
Metal Ion ◽  
Organic Matter Content ◽  
Matter Content ◽  
Heavy Metal Ion ◽  
Phosphorus Adsorption ◽  
Different Types ◽  
Adsorption And Release

Taking different types of sediments as the research object, this research studied the adsorption and release characteristics of phosphorus under different conditions of different temperatures, coexisting heavy metal ion system, organic matter content and sediment particle size. Through used correlation analysis and principal component analysis, it discussed the influence of various factors on the adsorption and release of phosphorus in sediments. The results show that the adsorption of phosphorus by five different types of sediments from different sources reached saturation equilibrium in about 10 hours, and the increasing rates of 0 ℃, 15 ℃ and 30 ℃ are 17.5% ~ 23.7% and 18.2% ~ 38.3%, respectively.  The addition of coexisting heavy metal ion solution accelerated the adsorption of phosphorus in the sediment and reduced the total amount of phosphorus adsorption, that is, heavy metal ions inhibited the adsorption of phosphorus in the sediment; the presence of organic matter in the sediment would reduce its adsorption of phosphorus , Taihu farm and wetland sampling points have the largest sediment organic matter content. Compared with the other three points, the adsorption of phosphorus of these two  points accounted for 20.6% and 22.1%; the adsorption and release of phosphorus by sediment increased with the decrease of particle size. The maximum release rate was 5.216mg/kg-1·h-1. The result of principal component analysis shows that the order of influence on the adsorption and release of phosphorus by sediments is temperature> disturbance> organic matter content> heavy metal ion influence> particle size of sediments.

scholarly journals System Control Scheme and Design Idea of Soft Sensing Model for Heavy Metal Ion Concentration

2021 ◽  
Vol 2033 (1) ◽  
pp. 012193
Author(s):  
Tianqi Wang ◽  
Yucheng Long ◽  
Xingchen Wang ◽  
San Zhang ◽  
Haiming Wang
Keyword(s):  
Heavy Metal ◽  
Metal Ion ◽  
Ion Concentration ◽  
Heavy Metal Ion ◽  
System Control ◽  
Soft Sensing ◽  
Control Scheme ◽  
Sensing Model ◽  
Design Idea

scholarly journals PENGOLAHAN LIMBAH LOGAM BERAT INDUSTRI TEKSTIL MENGGUNAKAN FOTOKATALIS TiO2/ARANG AKTIF

Molekul ◽  
2008 ◽  
Vol 3 (1) ◽  
pp. 40 ◽  
Author(s):  
Kapti Riyani ◽  
Tien Setyaningtyas ◽  
Roy Andreas
Keyword(s):  
Waste Water ◽  
Heavy Metal ◽  
Metal Ion ◽  
Ph Effect ◽  
Ion Concentration ◽  
Heavy Metal Ion ◽  
Active Charcoal ◽  
Textile Waste ◽  
Uv Lamp ◽  
Textile Waste Water

Study about the use of active charcoal rice straws (AAJP) was done in order to decrease heavy metal ion on textile waste water by using photocatalyst AAJP/TiO2. Rice straws were gained from the Banyumas Regency and samples textile waste water from one of textile industry in Pemalang. This study was begun by the making of active charcoal from the rice straws, and then the modification of photocatalyst AAJP/TiO2 was done with the comparison 1:99, 2:98, 3:97, 4:96, 5:95. The test of heavy metal ion photoreduction was done with some parameters such as weight comparison (1:99, 2:98, 3:97, 4:96, 5:95), pH effect (2, 5, 7, 9, 13) and the effect of ray source (sun light and the UV lamp). Analysis of photocatalyst material used SEM and heavy metal ion concentration used AAS. Results show that optimum photocatalyst activity in weight comparison AAJP300oC / TiO2 (1:99) with decrease concentration was 65.02% for heavy metal ion, mean while AAJP700oC / TiO2 (3:97) with decreased concentration of heavy metal ion is 94.50%. Optimal process for heavy metal ion reduction occur at pH 2 with decreased concentration of heavy metal ion for AAJP300oC / TiO2 (1:99) is 99.87% and for AAJP700oC /TiO2 (3:97) is 100%. The source of UV lamp was good for heavy metal ion photoreduction (AAJP300oC/TiO2(1:99) was 99.87% and AAJP700oC/TiO2 (3:97) was 100%)

scholarly journals Enhancement of Separation Efficiency for Nano Filtration Membrane using Water-Soluble Polymer.

2019 ◽  
Vol 8 (2) ◽  
pp. 1470-1474
Keyword(s):  
Heavy Metal ◽  
Flow Rate ◽  
Metal Ion ◽  
Separation Efficiency ◽  
Water Soluble ◽  
Ion Concentration ◽  
Heavy Metal Ion ◽  
Binding Agent ◽  
Water Soluble Polymer ◽  
Filtration Membrane

In this study, an aqueous solution containing a mixture of heavy metal ion Cr(III) were treated by polymer enhanced Nanofiltration using polyethylene glycol as a binding agent polymer. The performance of PEG in removing heavy metal ion Cr (III) was compared with PEG and without PEG addition using polyamide Nano filtrationmembrane. The percentage rejection of heavy metal ions was studied under the different value of pH, metal ion concentration and flow rate. AtpH 10,percentage rejection of heavy metal ion was highest at around 99.2%,whereas,at 200ppm concentration and at 3(l/hm2 )flow rate percentage rejection of heavy metal ion with PEG was highest 99.5%,it was found that PEG gave higher percentage rejection of Cr(III) ion than without the addition of PEG

An integrated prediction model of heavy metal ion concentration for iron electrocoagulation process

2020 ◽  
Vol 391 ◽  
pp. 123628 ◽  
Author(s):  
Fengxue Zhang ◽  
Chunhua Yang ◽  
Hongqiu Zhu ◽  
Yonggang Li ◽  
Weihua Gui
Keyword(s):  
Heavy Metal ◽  
Prediction Model ◽  
Metal Ion ◽  
Ion Concentration ◽  
Heavy Metal Ion ◽  
Electrocoagulation Process

Optical fiber sensors for measurement of heavy metal ion concentration: A review

Measurement ◽  
2020 ◽  
Vol 158 ◽  
pp. 107742 ◽  
Author(s):  
Ya-nan Zhang ◽  
Yang Sun ◽  
Lu Cai ◽  
Yiping Gao ◽  
Yi Cai
Keyword(s):  
Heavy Metal ◽  
Optical Fiber ◽  
Metal Ion ◽  
Optical Fiber Sensors ◽  
Ion Concentration ◽  
Heavy Metal Ion ◽  
Fiber Sensors
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