Imprinted polymers for the removal of heavy metal ions from water

2011 ◽  
Vol 64 (6) ◽  
pp. 1325-1332 ◽  
Author(s):  
Syed Ashraf ◽  
Angela Cluley ◽  
Ckarlos Mercado ◽  
Anja Mueller

In wastewater treatment, the removal of heavy metals is difficult due to the limited affinity of heavy metal ions to ion exchange resins. Here imprinting polymerization is used to develop resins with high capacity and selectivity for heavy metal ions for water treatment. A random copolymer of methacrylate and methacrylamide was found to be most effective for the removal of hydrophilic metal complexes, like CdCl2, ZnCl2, and the metalloid NaH2AsO4, particularly when the porosity of these resins is increased. For hydrophobic complexes imprinting emulsion polymerization was developed and data for the effective removal of mercury dithizonate will be described. Complete removal for up to 80 ppm of cadmium and mercury with only 200 mg of imprinted resin was obtained; competition and co-imprinting experiments are described as well.

2018 ◽  
Vol 77 (10) ◽  
pp. 2355-2368 ◽  
Author(s):  
Khalida Naseem ◽  
Zahoor H. Farooqi ◽  
Muhammad Z. Ur Rehman ◽  
Muhammad A. Ur Rehman ◽  
Robina Begum ◽  
...  

Abstract This review is based on the adsorption characteristics of sorghum (Sorghum bicolor) for removal of heavy metals from aqueous media. Different parameters like pH, temperature of the medium, sorghum concentration, sorghum particle size, contact time, stirring speed and heavy metal concentration control the adsorption efficiency of sorghum biomass for heavy metal ions. Sorghum biomass showed maximum efficiency for removal of heavy metal ions in the pH range of 5 to 6. It is an agricultural waste and is regarded as the cheapest biosorbent, having high adsorption capacity for heavy metals as compared to other reported adsorbents, for the treatment of heavy metal polluted wastewater. Adsorption of heavy metal ions onto sorghum biomass follows pseudo second order kinetics. Best fitted adsorption isotherm models for removal of heavy metal ions on sorghum biomass are Langmuir and Freundlich adsorption isotherm models. Thermodynamic aspects of heavy metal ions adsorption onto sorghum biomass have also been elaborated in this review article. How adsorption efficiency of sorghum biomass can be improved by different physical and chemical treatments in future has also been elaborated. This review article will be highly useful for researchers working in the field of water treatment via biosorption processing. The quantitative demonstrated efficiency of sorghum biomass for various heavy metal ions has also been highlighted in different sections of this review article.


2014 ◽  
Vol 14 (4) ◽  
pp. 2937-2946 ◽  
Author(s):  
K. Rajakumar ◽  
S. Dinesh Kirupha ◽  
S. Sivanesan ◽  
Rajamaniccam L. Sai

2018 ◽  
Vol 6 (4) ◽  
pp. 4623-4633 ◽  
Author(s):  
Mirabbos Hojamberdiev ◽  
Shahlo S. Daminova ◽  
Zukhra C. Kadirova ◽  
Khasan T. Sharipov ◽  
Felix Mtalo ◽  
...  

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