A built-in zero valent iron anaerobic reactor to enhance treatment of azo dye wastewater

2011 ◽  
Vol 63 (4) ◽  
pp. 741-746 ◽  
Author(s):  
Yaobin Zhang ◽  
Yanwen Jing ◽  
Xie Quan ◽  
Yiwen Liu ◽  
Pascal Onu
Keyword(s):  
Azo Dye ◽  
Visible Spectrum ◽  
Zero Valent Iron ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Dye Wastewater ◽  
Absorption Bands ◽  
Anaerobic Reactor ◽  
Anaerobic Sludge Blanket

Waste scrap iron was packed into an upflow anaerobic sludge blanket (UASB) reactor to form a zero valent iron (ZVI) - UASB reactor system for treatment of azo dye wastewater. The ZVI acted as a reductant to decrease ORP in the reactor by more than 40 mv and functioned as an acid buffer to increase the pH in the reactor from 5.44 to 6.29, both of which improved the performance of the anaerobic reactor. As a result, the removal of color and COD in this reactor was 91.7% and 53%, respectively, which was significantly higher than that of a reference UASB reactor without ZVI. The UV-visible spectrum demonstrated that absorption bands of the azo dye from the ZVI-UASB reactor were substantially reduced. The ZVI promoted methanogenesis, which was confirmed by an increase in CH4 content in the biogas from 47.9% to 64.8%. The ZVI bed was protected well from rusting, which allowed it to function stably. The effluent could be further purified only by pH adjustment because the Fe2+ released from ZVI served as a flocculent.

scholarly journals Decolorization enhancement by optimizing azo dye loading rate in an anaerobic reactor

RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 49995-50001 ◽  
Author(s):  
Min-Hua Cui ◽  
Dan Cui ◽  
Bin Liang ◽  
Thangavel Sangeetha ◽  
Ai-Jie Wang ◽  
...  
Keyword(s):  
Microbial Community ◽  
Azo Dye ◽  
Loading Rate ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Anaerobic Reactor ◽  
Dye Loading ◽  
Anaerobic Sludge Blanket

An up-flow anaerobic sludge blanket (UASB) reactor was developed to investigate the effect of azo dye loading rate on the decolorization performance and microbial community.

scholarly journals Microbial Removal of Pb(II) Using an Upflow Anaerobic Sludge Blanket (UASB) Reactor

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 512
Author(s):  
Jeremiah Chimhundi ◽  
Carla Hörstmann ◽  
Evans M. N. Chirwa ◽  
Hendrik G. Brink
Keyword(s):  
Treatment Process ◽  
Removal Rate ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Reduction Potentials ◽  
Oxidation Reduction ◽  
Anaerobic Sludge Blanket ◽  
Microbial Removal ◽  
Maximum Removal

The main objective of this study was to achieve the continuous biorecovery and bioreduction of Pb(II) using an industrially obtained consortia as a biocatalyst. An upflow anaerobic sludge blanket reactor was used in the treatment process. The bioremediation technique that was applied made use of a yeast extract as the microbial substrate and Pb(NO3)2 as the source of Pb(II). The UASB reactor exhibited removal efficiencies of between 90 and 100% for the inlet Pb concentrations from 80 to 2000 ppm and a maximum removal rate of 1948.4 mg/(L·d) was measured. XRD and XPS analyses of the precipitate revealed the presence of Pb0, PbO, PbS and PbSO4. Supporting experimental work carried out included growth measurements, pH, oxidation–reduction potentials and nitrate levels.

KINETIC MODELS FOR PREDICTION OF COD EFFLUENT FROM UPFLOW ANAEROBIC SLUDGE BLANKET (UASB) REACTOR FOR CANNERY SEAFOOD WASTEWATER TREATMENT

2016 ◽  
Vol 78 (5-6) ◽  
Author(s):  
Sunwanee Jijai ◽  
Chairat Siripatana ◽  
Sompong O-Thong ◽  
Norli Ismail
Keyword(s):  
Palm Oil ◽  
Kinetic Models ◽  
Second Order ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Substrate Removal ◽  
Reactor Kinetic ◽  
Palm Oil Mill ◽  
Anaerobic Sludge Blanket

The three identical lab-scale upflow anaerobic sludge blanket (UASB) reactors were operated continuously for treating cannery seafood wastewater at seven hydraulic retention times (HRTs) of 5, 4, 3, 2, 1, 0.5 and 0.25 days. The different of granule sizes from three sources: a cassava factory (CS), a seafood factory (SS), and a palm oil mill (PS), average sizes in the range 1.5-1.7, 0.7-1.0 and 0.1-0.2 mm respectively were used as inocula for anaerobic digestion. The UASB-R1 used only granules from seafood factory (R1-SS), the UASB-R2 used mixed granules from seafood with cassava factory (R2-SS+CS) and the UASB-R3 used mixed granules from seafood factory with palm oil mill (R3-SS+PS). In this study selected mathematical models including Monod, Contois, Grau second-order and modified Stover-Kicannon kinetic models were applied to determine the substrate removal kinetics of UASB reactor. Kinetic parameters were determined through linear regression using experimental data obtained from the steady-state experiment and subsequently used to predict effluent COD. The results showed that Grau second-order and modified Stover-Kicannon kinetic models were more suitable than that of others for predicting the effluent COD, with high the correlation coefficient (R2). In addition, the UASB-R2 from mixed granules with cassava factory (SS+CS) gave the best performance and highest coefficient value.

Treatment of raw sewage in a temperate climate using a UASB reactor and the hanging sponge cubes process

1997 ◽  
Vol 36 (6-7) ◽  
pp. 433-440 ◽  
Author(s):  
Lalit K. Agrawal ◽  
Yasuhiro Ohashi ◽  
Etsuo Mochida ◽  
Hiroyuki Okui ◽  
Yasuko Ueki ◽  
...  
Keyword(s):  
Ammonia Oxidation ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Temperate Climate ◽  
Anaerobic Sludge ◽  
Treatment Efficiency ◽  
Oxidation Rates ◽  
Air Intake ◽  
Anaerobic Sludge Blanket ◽  
Digested Sewage Sludge

The treatability of raw sewage in a temperate climate (wintertime around 10–20°C) using an upflow anaerobic sludge blanket (UASB) reactor and the hanging sponge cubes process was evaluated. After being seeded with digested sewage sludge, a 47.1 L UASB reactor was continuously operated for more than 2 years by feeding raw sewage, which had average COD around 300 mg/L (41% soluble). During summertime at an HRT of 7 h, effluent COD approximately 70 mg/L total, 50 mg/L soluble and BOD5 20 mg/L total, 12 mg/L soluble was obtained. During wintertime also, treatment efficiency and process stability was good. With the hanging sponge cubes process using the effluent of the UASB reactor treating raw sewage, the following results were obtained. The ammonia oxidation rates of 1.9 and 3.5 g NH4-N·m−2·d−1 in a downflow hanging sponge cubes biofilter, under natural air intake only were obtained during wintertime and summertime, respectively. With post-denitrification and an external carbon source, 84% in average N (NO3+NO2) was removed with an HRT of less than 1 hour and in the temperature range of 13 to 30°C using an upflow submerged hanging sponge bed bioreactor, under anaerobic conditions. The overall system using a UASB reactor and the hanging sponge cubes process could be quite an attractive treatment alternative.

The biobed® EGSB (expanded granular sludge bed) system covers shortcomings of the upflow anaerobic sludge blanket reactor in the chemical industry

1997 ◽  
Vol 35 (10) ◽  
pp. 183-188 ◽  
Author(s):  
George R. Zoutberg ◽  
Peter de Been
Keyword(s):  
Waste Water ◽  
Chemical Industry ◽  
Granular Sludge ◽  
Upflow Anaerobic Sludge Blanket ◽  
Anaerobic Sludge ◽  
Special Configuration ◽  
Anaerobic Reactor ◽  
High Concentrations ◽  
Anaerobic Sludge Blanket ◽  
Brewery Yeast

In this paper a new type of anaerobic reactor is presented. The system has been developed by Biothane Systems and is marketed under the name Biobed® EGSB reactor (Expanded Granular Sludge Bed). In this reactor it is possible to grow and maintain a granular sludge under high liquid (10 m/h) and gas velocities (7 m/h). The most striking feature is the growth of biomass in a granular form, similar to the UASB granules: no carrier material is used. The process is specially suitable to treat waste water that contains compounds that are toxic in high concentrations and that only can be degraded in low concentrations (chemical industry). An example is given for a waste water originating from a chemical factory (Caldic Europoort) in the Netherlands. In this factory formaldehyde is produced from methanol. The waste water is characterised by high concentrations of these compounds (formaldehyde to 10 g/l and methanol to 20 g/l). Due to the special configuration of the anaerobic reactor it is possible to realise a removal efficiency for both compounds of more than 98%. It is also possible to operate the reactor as an ultra high loaded anaerobic reactor (to 30 kg COD/m3.day) for applications in other sectors of industry (e.g. brewery, yeast, sugar, corn ethanol production etc).

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