Removal of endocrine disrupting chemicals in a large scale membrane bioreactor plant combined with anaerobic-anoxic-oxic process for municipal wastewater reclamation

2011 ◽  
Vol 64 (7) ◽  
pp. 1511-1518 ◽  
Author(s):  
Chunying Wu ◽  
Wenchao Xue ◽  
Haidong Zhou ◽  
Xia Huang ◽  
Xianghua Wen
Keyword(s):  
Removal Efficiency ◽  
Large Scale ◽  
Membrane Bioreactor ◽  
Municipal Wastewater ◽  
Estrogenic Activity ◽  
Endocrine Disrupting Compounds ◽  
Gas Chromatography Mass Spectrometry ◽  
Wastewater Reclamation ◽  
Kd Values ◽  
Endocrine Disrupting

The removal of eight typical endocrine disrupting compounds (EDCs) in a full scale membrane bioreactor combined with anaerobic-anoxic-oxic process (A2/O-MBR) for municipal wastewater reclamation located in Beijing was investigated. These EDCs, including 4-octylphenol (4-OP), 4-n-nonylphenol (4-n-NP), bisphenol A (BPA), estrone (E1), 17α-estradiol (17α-E2), 17β-estradiol (17β-E2), estriol (E3) and 17α-ethinylestradiol (EE2), were simultaneously analyzed by gas chromatography/mass spectrometry after derivatization. The concentrations of eight EDCs were also measured in sludge of anaerobic, anoxic, oxic and membrane tanks to measure sludge-water distribution coefficients (Kd values) as the indicator of adsorption propensity of target compound to sludge. The removal efficiencies of EDCs reached above 97%, except for 4-n-NP removal efficiency of 72%, 4-OP removal efficiency of 75% and EE2 removal efficiency of 87% in the A2/O-MBR process. The high Kd values indicated that the sludge had a large adsorption capacity for these EDCs, and significantly contributed to removal of EDCs. Yeast estrogen screen assay was performed on samples to assess the total estrogenic activity by measuring the 17β-E2 equivalent quantity (EEQ), expressed in ng-EEQ/L. The measured EEQ value was markedly reduced from 72.1 ng-EEQ/L in the influent to 4.9 ng-EEQ/L in the effluent. Anoxic tank and anaerobic tank contributed to 80% and 37% in total EEQ removal, respectively.

Nanofiltration of endocrine disrupting compounds

2003 ◽  
Vol 3 (5-6) ◽  
pp. 321-327 ◽  
Author(s):  
M. Gallenkemper ◽  
T. Wintgens ◽  
T. Melin
Keyword(s):  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Endocrine Disrupting Compounds ◽  
Municipal Wastewater Treatment ◽  
Water And Wastewater Treatment ◽  
Wide Range ◽  
Endocrine Disrupting ◽  
Municipal Wastewater Treatment Plants ◽  
Set Up

Endocrine disrupting compounds can affect the hormone system in organisms. A wide range of endocrine disrupters were found in sewage and effluents of municipal wastewater treatment plants. Toxicological evaluations indicate that conventional wastewater treatment plants are not able to remove these substances sufficiently before disposing effluent into the environment. Membrane technology, which is proving to be an effective barrier to these substances, is the subject of this research. Nanofiltration provides high quality permeates in water and wastewater treatment. Eleven different nanofiltration membranes were tested in the laboratory set-up. The observed retention for nonylphenol (NP) and bisphenol A (BPA) ranged between 70% and 100%. The contact angle is an indicator for the hydrophobicity of a membrane, whose influence on the permeability and retention of NP was evident. The retention of BPA was found to be inversely proportional to the membrane permeability.

scholarly journals Removal of Six Estrogenic Endocrine-Disrupting Compounds (EDCs) from Municipal Wastewater Using Aluminum Electrocoagulation

Water ◽  
2016 ◽  
Vol 8 (4) ◽  
pp. 128 ◽  
Author(s):  
Monica Cook ◽  
Erin Symonds ◽  
Bert Gerber ◽  
Armando Hoare ◽  
Edward Van Vleet ◽  
...  
Keyword(s):  
Municipal Wastewater ◽  
Endocrine Disrupting Compounds ◽  
Endocrine Disrupting

Removal of endocrine disrupting compounds using a membrane bioreactor and disinfection

2007 ◽  
Vol 6 (2) ◽  
pp. 131-137 ◽  
Author(s):  
A J Spring ◽  
D M Bagley ◽  
R C Andrews ◽  
S Lemanik ◽  
P Yang
Keyword(s):  
Membrane Bioreactor ◽  
Endocrine Disrupting Compounds ◽  
Endocrine Disrupting

Tertiary ozonation of industrial wastewater for the removal of estrogenic compounds (NP and BPA): a full-scale case study

2013 ◽  
Vol 68 (3) ◽  
pp. 567-574 ◽  
Author(s):  
G. Bertanza ◽  
M. Papa ◽  
R. Pedrazzani ◽  
C. Repice ◽  
M. Dal Grande
Keyword(s):  
Removal Efficiency ◽  
Industrial Wastewater ◽  
Treatment Plant ◽  
Endocrine Disrupting Compounds ◽  
Full Scale ◽  
Residual Content ◽  
Endocrine Disrupting ◽  
Treatment Stage ◽  
Flow Rate Increase

Wastewater treatment plant (WWTP) effluents are considered to be a major source for the release in the aquatic environment of endocrine-disrupting compounds (EDCs). Ozone has proved to be a suitable solution for polishing secondary domestic effluents. In this work, the performance of a full-scale ozonation plant was investigated in order to assess the removal efficiency of four target EDCs: nonylphenol, nonylphenol monoethoxylate, nonylphenol diethoxylate and bisphenol A. The studied system was the tertiary treatment stage of a municipal WWTP which receives an important industrial (textile) load. Chemical analyses showed that the considered substances occurred with a significant variability, typical of real wastewaters; based on this, ozonation performance was carefully evaluated and it appeared to be negatively affected by flow-rate increase (during rainy days, with consequent contact time reduction). Moreover, EDCs' measured removal efficiency was lower than what could be predicted based on literature data, because of the relatively high residual content of biorefractory compounds still present after biological treatment.

Removal Efficiency of Environmental Endocrine Disrupting Chemicals Pollutants-Phthalate Esters in Northern WWTP

2013 ◽  
Vol 807-809 ◽  
pp. 694-698
Author(s):  
Rong Xin Huang ◽  
Zhen Xing Wang ◽  
Gang Liu ◽  
Qi Jin Luo
Keyword(s):  
Activated Sludge ◽  
Removal Efficiency ◽  
Municipal Wastewater ◽  
Removal Rate ◽  
Phthalate Esters ◽  
Endocrine Disrupting Chemicals ◽  
Treatment Plant ◽  
Activated Sludge Process ◽  
Wastewater Reclamation ◽  
Conventional Activated Sludge

In order to guarantee the reliability and security of reclaiming water, research on the removal efficiency of the environmental endocrine chemicals (EDCs) --the Phthalate Esters (PAEs) in conventional secondary activated sludge and wastewater reclamation and reuse process was undergoing at Harbin wastewater treatment plant (WWTP). The wastewater samples were colleted from every unit effluent of WWTP. The results showed that contamination of EDCs were presented in municipal wastewater at Harbin and the concentrations of the four PAEs were 21.01μg/L for Di-n-butyl Phthalate (DBP); 9.63μg/L for Di-n-octyl Phthalate (DnOP); 4.56μg/L for Diethyl Phthalate (DEP); 1.96μg/L for Dimethyl Phthalate (DMP) respectively in the influent. The conventional activated sludge has good removal efficiencies performance on DMP, DEP and DBP. With the increasing of molecular weight and branch chains of PAEs contaminations, the removal rate of the four PAEs in the conventional activated sludge process decreased from 99.82%(DMP)，90.60%(DEP)，90.10%(DBP) to the only 45.13% removal rate for DnOP, which was mostly removed from primary treatment but no from secondary activated sludge process; Coagulation-air flotation plus filtration process was not a feasible way to remove PAEs from reclaiming treatment units.

Evaluation of a membrane bioreactor and nanofiltration for municipal wastewater reclamation: Trace contaminant control and fouling mitigation

Desalination ◽  
2011 ◽  
Vol 272 (1-3) ◽  
pp. 128-134 ◽  
Author(s):  
Kangmin Chon ◽  
Sarper Sarp ◽  
Sungyun Lee ◽  
Jong-Hoon Lee ◽  
J.A. Lopez-Ramirez ◽  
...  
Keyword(s):  
Membrane Bioreactor ◽  
Municipal Wastewater ◽  
Wastewater Reclamation ◽  
Fouling Mitigation ◽  
Trace Contaminant ◽  
Contaminant Control

Detection and removal of estrogencity in membrane biological reactors

2006 ◽  
Vol 6 (6) ◽  
pp. 19-26 ◽  
Author(s):  
J.Y. Hu ◽  
X. Chen
Keyword(s):  
Estrogenic Activity ◽  
Solid Phase ◽  
Treatment Plant ◽  
Endocrine Disrupting Compounds ◽  
Pilot Scale ◽  
Membrane Bioreactors ◽  
Yeast Cells ◽  
Endocrine Disrupting ◽  
And Behavior ◽  
Fate And Behavior

Three pilot-scale submerged membrane bioreactors (MBRs) in a local wastewater treatment plant (K, M and Z) were studied with the objective to compare the performance of pre-denitrification MBR systems in eliminating the estrogenic activity of the effluent of primary clarifier. A total of 5 batches of samples, which included influent, effluent, supernatant and sludge from the respective aerobic and anoxic tanks were collected over the span. They were investigated by using the developed solid-phase extraction (SPE) protocol coupled with a modified yeast-based estrogen screen (YES) assay. From the results, it could be seen that M MBR demonstrated the best endocrine disrupting compounds (EDCs) removal efficiency. The fate and behavior of EDCs in MBR systems were fairly understood with estrogenic activity formation dominating in the anoxic tank and removal dominating in the aerobic tank. It is believed that the sorption of EDCs onto the sludge as well as biodegradation of EDCs might be the key mechanisms for the EDCs removal. The low response of YES when dealing with influent samples was mainly due to the inhibition and antagonist effects induced by the influent samples on yeast cells.

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