Effect of chemical and biological treatment on COD fingerprints of textile wastewaters

2007 ◽  
Vol 55 (10) ◽  
pp. 277-287 ◽  
Author(s):  
E. Dulekgurgen ◽  
S. Doğruel ◽  
D. Orhon
Keyword(s):  
Size Distribution ◽  
Chemical Treatment ◽  
Biological Treatment ◽  
Size Range ◽  
Soluble Fraction ◽  
Size Spectrum ◽  
Total Removal ◽  
Before And After ◽  
Treatment Alternatives ◽  
Textile Wastewaters

Particle size distribution (PSD) via sequential filtration/ultrafiltration was used as the tool for COD fractionation and colour profiling of textile wastewaters before and after treatment. Profiles prior to treatment suggested PSD-based COD fingerprints characteristic for the influents. Treatment efficiencies were determined via comparing the profiles of the effluents from chemical- and biological-treatment to those of the corresponding influents. COD fingerprints of the wastewaters from the textile plants, applying different treatment alternatives, were different especially at the upper size range; yet profiles after treatment were similar, with the soluble fraction (<2 nm) being almost the only apparent one. Half of the overall COD-removal via chemical treatment was at the particulate- and upper colloidal-ranges, revealing that this alternative was effective at higher ranges, but not at the soluble fraction. In contrast, biological treatment was effective at both ends of size distribution, with total removal at the particulate range and 50% elimination at the soluble portion. Overall colour content and PSD-based colour profiles of the influents were also different. Chemical treatment was successful in removing colour originating from the entire colloidal range, but was not efficient at the soluble fraction. Conversely, colour removal efficiency of biological treatment was moderate throughout the entire size spectrum.

Effect of chemical treatment on soluble residual COD in textile wastewaters

2002 ◽  
Vol 45 (12) ◽  
pp. 251-259 ◽  
Author(s):  
H. Dulkadiroglu ◽  
S. Dogruel ◽  
D. Okutman ◽  
I. Kabdaşlı ◽  
S. Sözen ◽  
...  
Keyword(s):  
Particulate Matter ◽  
Chemical Treatment ◽  
Biological Treatment ◽  
Post Treatment ◽  
Cod Removal ◽  
Minor Portion ◽  
Pre Treatment ◽  
A Minor ◽  
Textile Wastewaters ◽  
Fabric Finishing

The effect of chemical treatment on the magnitude of soluble residual COD in the biological treatment effluent is investigated for knit fabric finishing wastewater. Bentonite is selected for its potential to remove soluble COD together with color and particulate components. Chemical treatment using bentonite, when applied prior to biological treatment removes around 40% of the biodegradable as well as soluble inert COD initially present in the wastewater. As a chemical post-treatment, it acts as a polishing step, removing particulate matter and a minor portion of around 20% of the remaining soluble COD. These findings suggest chemical pre-treatment as a better alternative for the optimization of soluble COD removal.

Determination of the Size Distribution of Dissolved Organics in Effluents

1973 ◽  
Vol 8 (1) ◽  
pp. 1-15 ◽  
Author(s):  
L.A. Addie ◽  
K.L. Murphy ◽  
J.L. Robertson
Keyword(s):  
Size Distribution ◽  
Biological Treatment ◽  
Oxygen Demand ◽  
Molecular Size ◽  
Monitoring Systems ◽  
Clean Surface ◽  
Sephadex Column ◽  
Dissolved Organics ◽  
Molecular Size Distribution

Abstract The importance of removing the small amounts of residual organics is increasing as the sources of clean surface water decrease. Knowledge of the nature of these soluble residual organics will be needed in order to assess the type of treatment required for their removal. Residual organics in three different biological treatment plants were analyzed and compared. An attempt was made to characterize these organics by a molecular size distribution on a Sephadex column monitored by differential ultraviolet and refractive index detectors. The organic carbon and chemical oxygen demand of the fractions collected from the column was also determined. An investigation of some of the problems inherent in the monitoring systems was conducted.

Characterization and treatability studies of cigarette industry wastewaters: a case study

1997 ◽  
Vol 36 (2-3) ◽  
pp. 69-74
Author(s):  
G. Bozarslan ◽  
S. K. Çelebi ◽  
F. Sengül
Keyword(s):  
Chemical Treatment ◽  
Biological Treatment ◽  
Continuous System ◽  
Cod Removal ◽  
Optimum Dose ◽  
Fenton Reagent ◽  
Cigarette Industry ◽  
Settling Behaviour ◽  
Characterization Studies

In this study, the wastewater of one of the cigarette factories in Izmir was characterized and treatability studies were done. The characterization studies of the wastewater showed that the COD, and the pH changes drastically. The chemical treatability studies of the influent wastewater were done by using Ca(OH)2, FeCl3 and Fenton Reagent. The optimum dose of FeCI3 was determined by jar tests. When using Ca(OH)2, the best flocculation, settling behaviour, and the highest COD removal occurred around pH 11. The optimum doses of Fenton Reagent (FeSO4 and H2O2) were determined. The supernatants of the previously chemically treated wastewaters were used for biological treatment. According to total COD removal efficiencies and the amount of sludge production during chemical treatment, FeCl3 was found to be the most economical and effective coagulant. Chemical treatment units were designed for a batch and a continuous system. The batch system has more advantages than a continuous system in this case.

scholarly journals Uncertainty assessment of current size-resolved parameterizations for below-cloud particle scavenging by rain

2010 ◽  
Vol 10 (12) ◽  
pp. 5685-5705 ◽  
Author(s):  
X. Wang ◽  
L. Zhang ◽  
M. D. Moran
Keyword(s):  
Size Distribution ◽  
Collection Efficiency ◽  
Theoretical Calculations ◽  
Terminal Velocity ◽  
Moderate Intensity ◽  
Size Spectrum ◽  
Cloud Particle ◽  
Particle Collection ◽  
Particle Scavenging ◽  
Empirical Size

Abstract. Current theoretical and empirical size-resolved parameterizations of the scavenging coefficient (Λ), a parameter commonly used in aerosol transport models to describe below-cloud particle scavenging by rain, have been reviewed in detail and compared with available field and laboratory measurements. Use of different formulations for raindrop-particle collection efficiency can cause uncertainties in size-resolved Λ values of one to two orders of magnitude for particles in the 0.01–3 μm diameter range. Use of different formulations of raindrop number size distribution can cause Λ values to vary by a factor of 3 to 5 for all particle sizes. The uncertainty in Λ caused by the use of different droplet terminal velocity formulations is generally small than a factor of 2. The combined uncertainty due to the use of different formulations of raindrop-particle collection efficiency, raindrop size spectrum, and raindrop terminal velocity in the current theoretical framework is not sufficient to explain the one to two order of magnitude under-prediction of Λ for the theoretical calculations relative to the majority of field measurements. These large discrepancies are likely caused by additional known physical processes (i.e, turbulent transport and mixing, cloud and aerosol microphysics) that influence field data but that are not considered in current theoretical Λ parameterizations. The predicted size-resolved particle concentrations using different theoretical Λ parameterization can differ by up to a factor of 2 for particles smaller than 0.01 μm and by a factor of >10 for particles larger than 3 μm after 2–5 mm of rain. The predicted bulk mass and number concentrations (integrated over the particle size distribution) can differ by a factor of 2 between theoretical and empirical Λ parameterizations after 2–5 mm of moderate intensity rainfall.

scholarly journals Particle size distribution and particle mass measurements at urban, near-city and rural level in the Copenhagen area and Southern Sweden

2003 ◽  
Vol 3 (6) ◽  
pp. 5513-5546 ◽  
Author(s):  
M. Ketzel ◽  
P. Wåhlin ◽  
A. Kristensson ◽  
E. Swietlicki ◽  
R. Berkowicz ◽  
...  
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Particle Number ◽  
Size Range ◽  
Urban Background ◽  
Total Particle ◽  
Urban Level ◽  
20 Nm ◽  
Traffic Source

Abstract. Particle size distribution (size-range 3–900 nm) and PM10 was measured simultaneously at an urban background station in Copenhagen, a near-city background and a rural location during a period in September-November 2002. The study investigates the contribution from urban versus regional sources of particle number and mass concentration. The total particle number (ToN) and NOx are well correlated at the urban and near-city level and show a distinct diurnal variation, indicating the common traffic source. The average ToN at the three stations differs by a factor of 3. The observed concentrations are 2500 # cm−3, 4500 # cm−3 and 7700 # cm−3 at rural, near-city and urban level, respectively. PM10 and total particle volume (ToV) are well correlated between the three different stations and show similar concentration levels, in average within 30% relative difference, indicating a common source from long-range transport that dominates the concentrations at all locations. Measures to reduce the local urban emissions of NOx and ToN are likely to affect both the street level and urban background concentrations, while for PM10 and ToV only measurable effects at the street level are probable. Taking into account the supposed stronger health effects of ultrafine particles reduction measures should address particle number emissions. The traffic source contributes strongest in the 10–200 nm particle size range. The maximum of the size distribution shifts from about 20–30 nm at kerbside to 50–60 nm at rural level. We also observe particle formation events in the 3–20 nm size range at rural location in the afternoon hours, mainly under conditions with low concentrations of pre-existing aerosol particles. The maximum in the size distribution of the "traffic contribution" seems to be shifted to about 28 nm in the urban location compared to 22 nm at kerbside. Assuming NOx as an inert tracer on urban scale let us estimate that ToN at urban level is reduced by 15–30% compared to kerbside. Particle removal processes, e.g. deposition and coagulation, which are most efficient for smallest particle sizes (<20 nm) and condensational growth are likely mechanisms for the loss of particle number and the shift in particle size.

Implementation of EU discharge guidelines at IVAR's Regional Wastewater Treatment Plant of North Jaeren, Stavanger, Norway

2001 ◽  
Vol 44 (1) ◽  
pp. 33-39 ◽  
Author(s):  
O. Tornes
Keyword(s):  
Wastewater Treatment ◽  
Feasibility Study ◽  
Chemical Treatment ◽  
Biological Treatment ◽  
Treatment Plant ◽  
Primary Treatment ◽  
Full Scale ◽  
Precipitation Process ◽  
European Economic Area ◽  
The Eu

Norway is a leading country on wastewater treatment comprising chemical precipitation processes. This is because Norwegian effluent standards to the North Sea have traditionally focused on phosphorus removal. In most cases, chemical treatment therefore has been considered to give lower investment and operating costs than biological treatment. Norwegian wastewater policy and management is based on the EU guidelines resulting from the EEA (European Economic Area) Agreement. According to the 1991 Urban Wastewater Treatment Directive, this will in most cases require secondary treatment. However, primary treatment can be accepted for plants larger than 10,000 PT with effluents to less sensitive coastal areas, if no negative environmental impacts can be proved. The main objective of the Regional Water, Sewerage and Waste Company (IVAR) is to comply with the prevailing effluent limits at lowest possible cost. During the past four years, IVAR has therefore undertaken comprehensive optimising of the precipitation process including full-scale experiments with different coagulant dosing control systems and different types of coagulants. IVAR also accomplished a feasibility study of introducing biological treatment as an alternative to chemical treatment. Under the prevailing frame conditions of discharge requirements and sludge deposit costs, it is not economically feasible to change to organic coagulants or biological treatment. This conclusion might have to be altered later resulting from the implementation of new EU regulations and increasing sludge deposit costs. This paper presents results from full-scale experiments, extracts from the feasibility study and a comparison of costs. Furthermore, the practical consequences of implementing the EU-guidelines are discussed.

The Effect of Residual COD on the Biological Treatability of Textile Wastewaters

1992 ◽  
Vol 26 (3-4) ◽  
pp. 815-825 ◽  
Author(s):  
D. Orhon ◽  
N. Artan ◽  
S. Büyükmurat ◽  
E. Görgün
Keyword(s):  
Biological Treatment ◽  
Treatment Process ◽  
Textile Effluents ◽  
Kinetic Information ◽  
A Value ◽  
Effluent Standards ◽  
Microbial Products ◽  
Biological Treatability ◽  
Activated Sludge Systems ◽  
Textile Wastewaters

Textile effluents often contain an array of chemicals with different biodegradation characteristics. Consequently, it is quite difficult to evaluate and interpret the degree of COD removal that can be attained by biological treatment without identifying COD portions that are resistant to biodegradation. This study evaluates the biological treatability of textile wastewaters generated by the knit and wowen fabric finishing category with specific emphasis on the assessment of different residual COD components. A new method is proposed to experimentally measure the initial particulate inert COD. The method is tested to yield a value of 73 mgl-1 for this COD component, corresponding to 16 % of the particulate COD in the textile sample. A previously developed procedure is used to quantify the initial soluble inert COD and the residual COD generated through microbial metabolism during the treatment process. The ratio of the inert fraction to the soluble COD of the textile effluents is found to vary between 0.076 and 0.22. A similar ratio in the range of 0.04 - 0.09 is calculated for the residual microbial products. The kinetic and stoichiometric constants associated with the biodegradable COD are also experimentally measured. The residual components, together with the kinetic information about biodegradable fractions, are used to simulate the performance of activated sludge systems by means of a relationship between the total effluent COD and the sludge age. The results indicate that the residual components practically dominate the effluent COD and seriously challenge related effluent standards.

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