Effect of chemical treatment on the acute toxicity of two commercial textile dye carriers

2007 ◽  
Vol 55 (10) ◽  
pp. 253-260 ◽  
Author(s):  
I. Arslan-Alaton ◽  
G. Iskender ◽  
B. Ozerkan ◽  
F. Germirli Babuna ◽  
O. Okay
Keyword(s):  
Acute Toxicity ◽  
Activated Sludge ◽  
Chemical Treatment ◽  
Textile Industry ◽  
Ferrous Sulphate ◽  
Textile Dye ◽  
Sludge Treatment ◽  
Treatment Conditions ◽  
Test Organisms ◽  
Sludge Settling

In the present experimental study, the effect of chemical treatment (coagulation–flocculation) on the acute toxicity exerted by two commercial dye carriers (called Carrier A and B herein) often used in the textile industry was investigated. Two different test organisms were selected to elucidate the situations in activated sludge treatment systems (activated sludge microorganisms) as well as in receiving water bodies (ultimate marine discharge). According to the results of a comprehensive analysis covering COD removal efficiencies, sludge settling characteristics and operating costs involved in coagulation-flocculation, the optimum treatment conditions were defined as follows; application of 750 mg/L ferrous sulphate at a pH of 9.0 for Carrier A; and application of 550 mg/L ferrous sulphate at a pH of 9.0 for Carrier B. The acute toxicities of both dye carriers towards marine microalgea Phaeodactylum tricornutum could be reduced significantly after being subjected to coagulation–flocculation. Fair toxicity removals (towards heterotrophic mixed bacterial culture accommodated in activated sludge treatment) were obtained with coagulation–flocculation for both of the carriers under investigation.

Behaviour of Alkylphenol Polyethoxylate Surfactants and of Nitrilotriacetate in Sewage Treatment

1987 ◽  
Vol 19 (3-4) ◽  
pp. 449-460 ◽  
Author(s):  
W. Giger ◽  
M. Ahel ◽  
M. Koch ◽  
H. U. Laubscher ◽  
C. Schaffner ◽  
...  
Keyword(s):  
Activated Sludge ◽  
Sewage Treatment ◽  
Operating Conditions ◽  
Municipal Sewage ◽  
Sludge Treatment ◽  
Loading Rates ◽  
Treatment Conditions ◽  
Physico Chemical ◽  
Treated Sewage ◽  
Removal Efficiencies

Effluents and sludges from several municipal sewage treatment plants in Switzerland were analyzed for nonylphenol polyethoxylates (NPnEO, n=3-20), nonylphenol mono- and diethoxylate (NPlEO, NP2EO), corresponding nonylphenoxy carboxylic acids (NP1EC, NP2EC) and nonylphenol (NP). These chemicals derive from nonionic surfactants of the NPnEO-type, and specific analitical techniques were used to study their behaviour during mechanical-biological sewage and subsequent sludge treatment. The parent NPnEO-surfactants, with concentrations in raw and mechanically treated sewage from 400-2200 mg/m3, were relatively efficiently removed by the activated sludge treatment. The abundances of the different metabolites varied depending on treatment conditions. The refractory nature of NPl/2EO, NP and NPl/2EC was recognized. Both biotransformations and physico-chemical processes determine the behaviour and fate of nonylphenolic substances in sewage treatment. Nitrilotriacetate (NTA) was found in primary effluents at concentrations between 430 and 1390 mg/m3. The various treatment plants showed different removal efficiencies for NTA depending on the operating conditions. Activated sludge treatment with low sludge loading rates and nitrifying conditions removed NTA with efficiencies between 95 and 99%. High sludge loading caused a decrease in NTA removal efficiencies from 70% to 39%.

Control of the Phosphorus Level of Effluent in the Treatment of Forest Industry Waste Waters

1988 ◽  
Vol 20 (1) ◽  
pp. 81-86 ◽  
Author(s):  
P. Väänänen
Keyword(s):  
Activated Sludge ◽  
Chemical Treatment ◽  
Phosphorus Removal ◽  
Kraft Pulp ◽  
Ferrous Sulphate ◽  
Pulp Mill ◽  
Phosphorus Concentration ◽  
Activated Sludge Process ◽  
Phosphorus Level ◽  
Biological Phosphorus Removal

Pulp and paper mill wastewaters are nutrient deficient, BOD5:N:P may be as low as 100:1:0.2. Now that purification requirements have been tightened, the activated sludge process seems to be most commonly used treatment method. The conventional activated sludge process requires BOD:P ratios of 100 to 0.6 resulting in a need for P addition and hence in a possible increase in the P-level of the effluent. In Finland and also in some other areas phosphorus removal is of great importance in the prevention of eutrophication of watercourses. There are several methods to control phosphorus level, such as biological phosphorus removal, running of the process under starvation of phosphorus, tertiary (chemical) treatment and simultaneous precipitation of phosphorus. This paper lists possible treatment methods and presents more closely chemical treatment using simultaneous precipitation by ferrous sulphate. The results are based on both pilot and full-scale experiments in two kraft pulp mills. The study showed that phosphorus concentration can be reduced to a level of 1.2 mg/l (tot.P) by adding ferrous sulphate to the aeration basin in activated sludge treatment of kraft pulp mill wastewaters. Ferrous sulphate has, also, a slight positive effect on the sludge properties e.g. sludge settleability.

scholarly journals The influence of operating conditions of activated-sludge treatment on the behaviour of f2 coliphage

1979 ◽  
Vol 82 (2) ◽  
pp. 285-291 ◽  
Author(s):  
S. A. Balluz ◽  
M. Butler
Keyword(s):  
High Temperature ◽  
Activated Sludge ◽  
Suspended Solids ◽  
Operating Conditions ◽  
Regression Coefficients ◽  
Sludge Treatment ◽  
Mixed Liquor ◽  
Treatment Conditions ◽  
Solids Concentration ◽  
Flow Through

SUMMARYThe behaviour of f2 coliphage during activated-sludge treatment was influenced by the temperature, flow-through-time, concentration of mixed liquor suspended solids and the virus load.The most sensitive way to detect behavioural changes was to examine the regression coefficients for the rate of uptake or loss of virus by the mixed liquor solids. This type of analysis revealed, for instance, high values when the solids concentration was high and even greater values occured when high inocula were used. At high temperature the rate of loss of virus titre after inoculation had stopped was greater than the rate of uptake of virus during inoculation although in all other conditions uptake occurred at a greater rate than the loss of virus. The coefficients were relatively low when the flow rate was increased, when the temperature was low or when the inoculum was small.The distribution of virus between the solids and liquid fractions of the mixed liquor varied somewhat for all conditions but was notably different when (a) the plant was incubated at 5 °C when there was much less virus in the solids fraction than usual, and (b) when the inoculum was low and a much higher proportion of virus was found in the solids.The efficiency with which virus was removed across the plant was the least-sensitive determinant of viral behaviour and the value was about the same for most treatment conditions. However, low or high inocula did result in some increased or decreased removal of virus, respectively.

Biological treatment of highly foaming pharmaceutical wastewater by modified bubble-column under mechanical foam control

2000 ◽  
Vol 42 (3-4) ◽  
pp. 331-337 ◽  
Author(s):  
K. Yamagiwa ◽  
M. Yoshida ◽  
A. Ohkawa ◽  
S. Takesono
Keyword(s):  
Activated Sludge ◽  
Biological Treatment ◽  
Bubble Column ◽  
Bubble Columns ◽  
Pharmaceutical Wastewater ◽  
Sludge Treatment ◽  
Mechanical Foam ◽  
Breaking Mechanism ◽  
Foam Control ◽  
Sludge Settling

Activated sludge treatment of highly foaming pharmaceutical wastewater was carried out with modified bubble columns equipped with a mechanical foam-breaker (MFRD). The geometry of the bubble column was modified based on the foam breaking mechanism of the MRFD in order to improve the foam breaking capacity and hence to enhance the treatment capacity. Four types of modifications were examined. The activated sludge treatment of the wastewater with the modified columns was successfully carried out with COD removal efficiency about 90% at BOD loading of 4 g/Ld. Little effect of the mechanical foam control on the sludge settling characteristics was observed. The column modification significantly reduced the power required for foam control. The maximum power decrement of 75% was attained. Furthermore, oxygen transfer was found to be facilitated in the modified bubble columns. The results are expected to be helpful for economic and effective treatment of highly foaming organic wastewater.

Behaviour of Mechanically Blended Return-Sludge in Absence of Substrate

1970 ◽  
Vol 5 (1) ◽  
pp. 34-54
Author(s):  
Shyam D. Bokil ◽  
Jatinder K. Bewtra
Keyword(s):  
Activated Sludge ◽  
Suspended Solids ◽  
Treatment Plant ◽  
Aeration Rate ◽  
Batch Experiments ◽  
Sludge Treatment ◽  
Waring Blender ◽  
Settling Characteristics

Abstract Nine sets of batch experiments, each of ten to twelve days duration, were conducted in the laboratory on return-sludge samples collected from activated sludge treatment plant at Windsor. The thickened sludge samples were blended daily in a waring blender and were continuously aerated in twelve-litres capacity jars. Parallel runs were made on control sludge samples which were not blended. Amongst the parameters varied were the speed and frequency of blending and the aeration rate. The effects of these variables on progressive bio-degradation of volatile suspended solids and the settling characteristics of the sludge were determined. Blended sludge showed significant improvement in the rate of bio-degradation and its settling characteristics as compared to the control unblended sludge

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