Autotrophic nitrogen removal from anaerobic supernatant of Florence's WWTP digesters

2006 ◽  
Vol 53 (12) ◽  
pp. 129-137 ◽  
Author(s):  
S. Caffaz ◽  
C. Lubello ◽  
R. Canziani ◽  
D. Santianni
Keyword(s):  
Nitrogen Removal ◽  
Municipal Wastewater ◽  
Removal Rate ◽  
Treatment Plant ◽  
Experimental Period ◽  
Anaerobic Sludge ◽  
Sludge Digestion ◽  
The One ◽  
Limiting Condition ◽  
Autotrophic Nitrogen Removal

In municipal WWTP with anaerobic sludge digestion, 10–20% of total nitrogen load comes from the return supernatant produced by the final sludge dewatering. In recent years a completely autotrophic nitrogen removal process based on Anammox biomass has been tested in a few European countries, in order to treat anaerobic supernatant and to increase the COD/N ratio in municipal wastewater. This work reports the experimental results of the SHARON-ANAMMOX process application to anaerobic supernatant taken from the urban Florentine area wastewater treatment plant (S. Colombano WWTP). A nitritation lab-scale chemostat (7.4 L) has been started-up seeded with the S. Colombano WWTP nitrifying activated sludge. During the experimental period, nitrite oxidising bacteria wash-out was steadily achieved with a retention time ranging from 1 to 1.5 d at 35 °C. The Anammox inoculum sludge was taken from a pilot plant at EAWAG (Zurich). Anammox biomass has been enriched at 33°C with anaerobic supernatant diluted with sodium nitrite solution until reaching a maximum specific nitrogen removal rate of 0.065 kgN kg−1 VSS d−1, which was 11 times higher than the one found in inoculum sludge (0.005 kgN kg−1VSS d−1). In a lab-scale SBR reactor (4 L), coupled with nitritation bioreactor, specific nitrogen removal rate (doubling time equal to 26 d at 35 °C and at nitrite-limiting condition) reached the value of 0.22 kgN kg−1 VSS d−1, which was approximately 44 times larger than the rate measured in the inoculum Anammox sludge.

scholarly journals Upflow packed bed Anammox reactor used in two-stage deammonification of sludge digester effluent

2018 ◽  
Vol 78 (9) ◽  
pp. 1843-1851 ◽  
Author(s):  
İ. Çelen-Erdem ◽  
E. S. Kurt ◽  
B. Bozçelik ◽  
B. Çallı
Keyword(s):  
Removal Efficiency ◽  
Nitrogen Removal ◽  
Municipal Wastewater ◽  
Removal Rate ◽  
Treatment Plant ◽  
Packed Bed ◽  
Municipal Wastewater Treatment ◽  
Two Stage ◽  
N Removal ◽  
Total Nitrogen Removal

Abstract The sludge digester effluent taken from a full scale municipal wastewater treatment plant (WWTP) in Istanbul, Turkey, was successfully deammonified using a laboratory scale two-stage partial nitritation (PN)/Anammox (A) process and a maximum nitrogen removal rate of 1.02 kg N/m3/d was achieved. In the PN reactor, 56.8 ± 4% of the influent NH4-N was oxidized to NO2-N and the effluent nitrate concentration was kept below 1 mg/L with 0.5–0.7 mg/L of dissolved oxygen and pH of 7.12 ± 12 at 24 ± 4°C. The effluent of the PN reactor was fed to an upflow packed bed Anammox reactor where high removal efficiency was achieved with NO2-N:NH4-N and NO3-N:NH4-N ratios of 1.32 ± 0.19:1 and 0.22 ± 0.10:1, respectively. The results show that NH4-N removal efficiency up to 98.7 ± 2.4% and total nitrogen removal of 87.7 ± 6.5% were achieved.

Upgrading of Florence wastewater treatment plant: co-digestion and nitrogen autotrophic removal

2005 ◽  
Vol 52 (4) ◽  
pp. 9-17 ◽  
Author(s):  
S. Caffaz ◽  
R. Canziani ◽  
C. Lubello ◽  
D. Santianni
Keyword(s):  
Nitrogen Removal ◽  
Pilot Plant ◽  
Municipal Wastewater ◽  
Biogas Production ◽  
Removal Rate ◽  
Treatment Plant ◽  
Experimental Results ◽  
Septic Tank ◽  
Technical Solution ◽  
Nitrite Production

In recent years a completely autotrophic nitrogen removal process based on Anammox biomass has been tested in a few European countries in order to treat anaerobic supernatant and to increase the COD/N ratio in municipal wastewater. This work reports experimental results on a possible technical solution to upgrade the S. Colombano treatment plant which treats wastewater from the Florentine urban area. The idea is to use 50% of the volume of the anaerobic digester in order to treat external sewage sludge (as septic tank sludge) together with waste activated sludge and to treat the resulting effluent on a SHARON-ANAMMOX process in order to remove nitrogen from the anaerobic supernatant. Anaerobic co-digestion, tested in a 200 L pilot plant, enables low cost treatment of septic tank sludge and increases biogas production; however, it also increases the nitrogen load re-circulated to the WWTP, where nitrogen removal efficiency is already low (<50%), due to the low COD/N ratio, which limits predenitrification efficiency. Experimental results from a SHARON process tested in a lab-scale pilot plant show that nitrite oxidising bacteria are washed-out and steady nitrite production can be achieved at retention times in the range 1–1.5 days, at 35 °C. In a lab-scale SBR reactor, coupled with a nitration bioreactor, maximum specific nitrogen removal rate under nitrite-limiting conditions (with doubling time equal to about 26 days at 35 °C) was equal to 0.22 kgN/kgSSV/d, about 44 times the rate measured in inoculum Anammox sludge. Finally, a cost analysis of the proposed upgrade is reported.

Implications of full-scale implementation of an anammox-based process as post-treatment of a municipal anaerobic sludge digester operated with co-digestion

2013 ◽  
Vol 69 (6) ◽  
pp. 1151-1158 ◽  
Author(s):  
J. R. Vázquez-Padín ◽  
N. Morales ◽  
R. Gutiérrez ◽  
R. Fernández ◽  
F. Rogalla ◽  
...  
Keyword(s):  
Nitrogen Removal ◽  
Pilot Plant ◽  
Removal Rate ◽  
Treatment Plant ◽  
Full Scale ◽  
Stream Line ◽  
Anaerobic Sludge ◽  
Main Stream ◽  
Batch Mode ◽  
Water Line

The feasibility of treating the supernatant of a municipal sludge digester supplemented with co-substrates by means of an anammox-based process (ELAN®) was tested in Guillarei (NW of Spain). Ammonia concentration measured in the supernatant of the sludge digester varied in the range 800–1,500 g N/m3 due to the fact that the sludge produced in the plant was co-digested with wastes coming from surrounding food industries. Treating this supernatant in the ELAN® reactor, nitrogen removal rates up to 1.1 kg N/(m3 d) were reached in experiments run in a pilot plant reactor operated in batch mode. No nitrite oxidation was registered after several months of operation despite the average dissolved oxygen (DO) concentrations being 1.5 g O2/m3 and the temperature reaching values as low as 18 °C. By keeping the DO set point at 1–2 g O2/m3 and tuning the hydraulic retention time, the stability of the process was guaranteed and the presence of co-substrates in the anaerobic digester did not affect negatively the operation of the autotrophic nitrogen removal process. Due to the success of the pilot plant experiment, an upscale of the process to full scale is proposed. Mass balances applied to Guillarei wastewater treatment plant revealed that in the main stream line the average denitrification rate calculated with the data of year 2011 was 226 kg N/d. Since the nitrogen removal efficiency is limited by the amount of readily biodegradable organic matter available to carry out denitrification in the water line, the implementation of an anammox-based process to treat the supernatant seems the best option to improve the effluent quality in terms of nitrogen content. The nitrogen removal rate in the sludge line would be 30 times higher than the one in the water line. The implementation of the process would improve the energetic balance and the nitrogen removal performance of the plant.

Treating an aged pentachlorophenol- (PCP-) contaminated soil through three sludge handling processes, anaerobic sludge digestion, post-sludge digestion and sludge land application

2001 ◽  
Vol 44 (10) ◽  
pp. 149-156 ◽  
Author(s):  
S.-T. Chen ◽  
P.M. Berthouex
Keyword(s):  
Contaminated Soil ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Land Application ◽  
Anaerobic Sludge ◽  
Primary Sludge ◽  
Sludge Digestion ◽  
Anaerobic Sludge Digestion ◽  
Soil Cleanup ◽  
Sludge Application

The extensive pentachlorophenol (PCP) contamination and its increasing treatment costs motivate the search for a more competitive treatment alternative. In a municipal wastewater treatment plant, anaerobic sludge-handling processes comprises three bio-processes, namely the anaerobic sludge digestion, post-sludge digestion and sludge land application, which reduce sludge organic content and make sludge a good fertilizer for land application. Availability and effectiveness make the anaerobic sludge handling processes potential technologies to treat PCP-contaminated soil. The technical feasibility of using anaerobic sludge bioprocesses was studied by treating PCP soil in two pilot digesters to simulate the primary sludge digestion, in serum bottles to mimic the post-sludge digestion, and in glass pans to represent the on-site sludge application. For primary digestion, the results showed that up to 0.98 and 0.6 mM of chemical and soil PCP, respectively, were treated at nearly 100% and 97.5% efficiencies. The PCP was transformed 95% to 3-MCP, 4.5% to 3,4-DCP, and 0.5% to 3,5-DCP. For post-digestion, 100% pure chemical PCP and greater than 95% soil PCP were removed in less than 6 months with no chlorophenol residues of any kind. Complete removal of PCP by-products makes this process a good soil cleanup method. For on-site treatment, PCP was efficiently treated by multiple sludge application; however, the PCP residue was observed due to the high initial PCP content in soil. Overall, more mass PCP per unit sludge per day was processed using the primary sludge digestion than the on-site soil treatment or post-sludge digestion. And, sludge acclimation resulted in better PCP treatment efficiencies with all three processes.

scholarly journals Assessment of Microplastics in a Municipal Wastewater Treatment Plant with Tertiary Treatment: Removal Efficiencies and Loading per Day into the Environment

Water ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1339
Author(s):  
Javier Bayo ◽  
Sonia Olmos ◽  
Joaquín López-Castellanos
Keyword(s):  
Wastewater Treatment ◽  
Wastewater Treatment Plant ◽  
Municipal Wastewater ◽  
Removal Rate ◽  
Treatment Plant ◽  
Source Control ◽  
Municipal Wastewater Treatment ◽  
Tertiary Treatment ◽  
Stable Performance ◽  
Wastewater Samples

This study investigates the removal of microplastics from wastewater in an urban wastewater treatment plant located in Southeast Spain, including an oxidation ditch, rapid sand filtration, and ultraviolet disinfection. A total of 146.73 L of wastewater samples from influent and effluent were processed, following a density separation methodology, visual classification under a stereomicroscope, and FTIR analysis for polymer identification. Microplastics proved to be 72.41% of total microparticles collected, with a global removal rate of 64.26% after the tertiary treatment and within the average retention for European WWTPs. Three different shapes were identified: i.e., microfiber (79.65%), film (11.26%), and fragment (9.09%), without the identification of microbeads despite the proximity to a plastic compounding factory. Fibers were less efficiently removed (56.16%) than particulate microplastics (90.03%), suggesting that tertiary treatments clearly discriminate between forms, and reporting a daily emission of 1.6 × 107 microplastics to the environment. Year variability in microplastic burden was cushioned at the effluent, reporting a stable performance of the sewage plant. Eight different polymer families were identified, LDPE film being the most abundant form, with 10 different colors and sizes mainly between 1–2 mm. Future efforts should be dedicated to source control, plastic waste management, improvement of legislation, and specific microplastic-targeted treatment units, especially for microfiber removal.

Benchmarks for the energy demand of nutrient removal plants

2003 ◽  
Vol 47 (12) ◽  
pp. 125-132 ◽  
Author(s):  
O. Nowak
Keyword(s):  
Nutrient Removal ◽  
Energy Demand ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Electrical Energy ◽  
Anaerobic Sludge ◽  
Operational Experience ◽  
Municipal Wastewater Treatment ◽  
Sludge Digestion ◽  
Municipal Wastewater Treatment Plants

The energy demand of municipal wastewater treatment plants for nutrient removal equipped with primary clarifiers, activated sludge system, anaerobic sludge digestion, and CHP is evaluated theoretically, on the basis of COD balances. Operational experience from energy-efficient Austrian treatment plants confirms that the demand on external electrical energy can be kept as low as 5 to 10 kWh/(pe.a) depending on the N:COD ratio in the raw wastewater. A low N:COD ratio helps to keep not only the effluent nitrogen load low, but also the energy demand. Measures to minimise the energy demand at treatment plants and to reduce the nitrogen load are discussed.

scholarly journals Anammox biofilm process using sugarcane bagasse as an organic carrier

2021 ◽  
Vol 26 (1) ◽  
pp. 25
Author(s):  
Zulkarnaini Zulkarnaini ◽  
Puti Sri Komala ◽  
Arief Almi
Keyword(s):  
Sugarcane Bagasse ◽  
Nitrogen Removal ◽  
Removal Rate ◽  
Nitrogen Loading ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Ammonium Oxidation ◽  
Biofilm Process ◽  
Anaerobic Sludge Blanket ◽  
Anammox Process

The anaerobic ammonium oxidation (anammox) biofilm process commonly uses various inorganic carriers to enhance nitrogen removal under anaerobic conditions. This study aims to analyze the performance of nitrogen removal in anammox process using sugarcane bagasse as an organic carrier. The experiment was carried out by using an up‐flow anaerobic sludge blanket (UASB) reactor for treating artificial wastewater at room temperature. The reactor was fed with ammonium and nitrite with the concentrations of 70‐150 mg–N/L and variations in the hydraulic retention time of 24 and 12 h. The granular anammox belongs to the genus Candidatus Brocadia sinica that was added as an inoculum of the reactor operation. The experimental stoichiometric of anammox for ΔNO2‐–N: ΔNH4+–N and ΔNO3‐: ΔNH4+ were 1.24 and 0.18, respectively, which is similar to anammox stoichiometry. The maximum Nitrogen Removal Rate (NRR) has achieved 0.29 kg–N/m3.d at Nitrogen Loading Rate (NLR) 0.6 kg–N/m3.d. The highest ammonium conversion efficiency (ACE) and nitrogen removal efficiency (NRE) were 88% and 85%, respectively. Based on this results, it indicated that sugarcane bagasse as organic carriers could increase the amount of total nitrogen removal by provided of denitrification process but inhibited the anammox process at a certain COD concentration.

Intermittent feeding of wastewater in combination with alternating aeration for complete denitrification and control of filaments

2010 ◽  
Vol 61 (9) ◽  
pp. 2259-2266 ◽  
Author(s):  
Styliani Kantartzi ◽  
Paraschos Melidis ◽  
Alexander Aivasidis
Keyword(s):  
Wastewater Treatment ◽  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Wastewater Treatment Plant ◽  
Municipal Wastewater ◽  
Settling Tank ◽  
Treatment Plant ◽  
Operating Conditions ◽  
Anoxic Conditions ◽  
Total Nitrogen Removal

In the present study, a laboratory scale system, consisting of a primary settling tank, a continuous stirred tank reactor and a clarifier were constructed and operated, using wastewater from the municipal wastewater treatment plant in Xanthi, Greece. The system operated under intermittent aeration in aerobic/anoxic conditions and feeding of the wastewater once in every cycle. The unit was inoculated with sludge, which originated from the recirculation stream of the local wastewater treatment plant. The wastewater was processed with hydraulic retention time (HRT) of 12 h, in which various experimental states were studied regarding the combination of aerobic and anoxic intervals. The wastewater was fed in limited time once in every cycle of aerobic/anoxic conditions at the beginning of the anoxic period. The two states that exhibited highest performance in nitrification and total nitrogen removal were, then, repeated with HRT of 10 h. The results show that, regarding the nitrification stage and the organic load removal, the intermittent system achieved optimum efficiency, with an overall removal of biological oxygen demand (BOD5) and ammonium nitrogen in the range of 93–96% and 91–95% respectively. As far as the total nitrogen removal is concerned, and if the stage of the denitrification is taken into account, the performance of the intermittent system surpassed other methods, as it is shown by the total Kjeldahl nitrogen (TKN) removal efficiency of 85–87%. These operating conditions suppressed the growth of filamentous organisms, a fact reflected at the SVI values, which were lower than 150 ml/g.

Total nitrogen removal from high-strength ammonia recycle stream using a single submerged attached growth bioreactor

2007 ◽  
Vol 55 (8-9) ◽  
pp. 59-65 ◽  
Author(s):  
A. Onnis-Hayden ◽  
P.B. Pedros ◽  
J. Reade
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Removal Rate ◽  
Treatment Plant ◽  
High Strength ◽  
Nitrogen Loading ◽  
Digested Sludge ◽  
Attached Growth ◽  
Anaerobically Digested Sludge ◽  
Total Nitrogen Removal

An experimental study investigating the nitrogen removal efficiency from the recycle stream generated in the dewatering facility of the anaerobically digested sludge at the Deer Island wastewater treatment plant (WWTP) in Boston was conducted using a single submerged attached growth bioreactor (SAGB), designed for simultaneous nitrification and denitrification. The applied nitrogen loading to the reactor ranged from 0.7 to 2.27 kg-N/m3·d, and the corresponding total nitrogen (TN) removal rate ranged from 0.38 to 1.8 kg-N/m3·d. The observed nitrification rates varied from 0.42 kg-N/m3·d to 1.45 kg-N/m3·d with an ammonia load of 0.5 kg-N/m3·d and 1.8 kg-N/m3·d, respectively. An average nitrification efficiency of 91% was achieved throughout the experiment. Denitrification efficiency varied from 55%, obtained without any addition of carbon source, to 95% when methanol was added in order to obtain a methanol/nitrate ratio of about 3 kg methanol/kg NO3−-N.

Sludge digestion enhancement and nutrient removal from anaerobic supernatant by Mg(OH)2 application

2001 ◽  
Vol 44 (1) ◽  
pp. 161-166 ◽  
Author(s):  
Q. Wu ◽  
P. L. Bishop ◽  
T. C. Keener ◽  
J. Stallard ◽  
L. Stile
Keyword(s):  
Biogas Production ◽  
Treatment Plant ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Phosphate Removal ◽  
Anaerobic Sludge ◽  
Phosphorus Concentration ◽  
Sludge Stabilization ◽  
Sludge Digestion ◽  
Anaerobic Sludge Digestion

Anaerobic sludge digestion is a widely adopted process for sludge stabilization. Phosphate removal from anaerobic supernatant is necessary to limit the phosphate returned to the head of the treatment plant, thereby improving the overall treatment efficiency. In this study, magnesium hydroxide (Mg(OH)2) was used to improve the sludge digestion efficiency and to remove phosphorus from anaerobic supernatant. The anaerobic sludge digestion experiment was conducted at a pilot scale, and the results showed that applying Mg(OH)2 to anaerobic sludge digester resulted in a larger reduction in SS and COD, a higher biogas production rate, a lower level of phosphate and ammonia nitrogen concentrations in the sludge supernatant and an improved sludge dewaterability. Research results at both lab scale and pilot scale on phosphorus removal from anaerobic supernatant using Mg(OH)2 showed that a high removal of phosphorus can be achieved through the addition of Mg(OH)2. The required reaction time depends on the initial phosphorus concentration and the Mg(OH)2 dosage.

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