Potential for biohydrogen and methane production from olive pulp

2005 ◽  
Vol 52 (1-2) ◽  
pp. 209-215 ◽  
Author(s):  
H.N. Gavala ◽  
I.V. Skiadas ◽  
B.K. Ahring ◽  
G. Lyberatos
Keyword(s):  
Methane Production ◽  
Anaerobic Treatment ◽  
Batch Experiments ◽  
Two Phase ◽  
Simultaneous Production ◽  
Production Of Hydrogen ◽  
Subsequent Step ◽  
Methane Potential ◽  
Olive Pulp ◽  
Semi Solid

The present study investigates the potential for thermophilic biohydrogen and methane production from olive pulp, which is the semi-solid residue coming from the two-phase processing of olives. It focussed on: a) production of methane from the raw olive pulp, b) anaerobic bio-production of hydrogen from the olive pulp, and c) subsequent anaerobic treatment of the hydrogen-effluent with the simultaneous production of methane. Both continuous and batch experiments were performed. The hydrogen potential of the olive pulp amounted to 1.6 mmole H2 per g TS. The methane potential of the raw olive pulp and hydrogen-effluent was as high as 19 mmole CH4 per g TS. This suggests that olive pulp is an ideal substrate for methane production and it shows that biohydrogen production can be very efficiently coupled with a subsequent step for methane production.

Thermophilic anaerobic fermentation of olive pulp for hydrogen and methane production: modelling of the anaerobic digestion process

2006 ◽  
Vol 53 (8) ◽  
pp. 271-279 ◽  
Author(s):  
H.N. Gavala ◽  
I.V. Skiadas ◽  
B.K. Ahring ◽  
G. Lyberatos
Keyword(s):  
Anaerobic Digestion ◽  
Methane Production ◽  
Anaerobic Fermentation ◽  
Anaerobic Treatment ◽  
Two Phase ◽  
Production Of Hydrogen ◽  
Subsequent Step ◽  
Methane Potential ◽  
Olive Pulp ◽  
Semi Solid

The present study investigates the thermophilic biohydrogen and methane production from olive pulp, which is the semi-solid residue coming from the two-phase processing of olives. It focussed on: a) production of methane from the raw olive pulp; b) anaerobic bio-production of hydrogen from the olive pulp; c) subsequent anaerobic treatment of the hydrogen-effluent with the simultaneous production of methane; and d) development of a mathematical model able to describe the anaerobic digestion of the olive pulp and the effluent of hydrogen producing process. Both continuous and batch experiments were performed. The hydrogen potential of the olive pulp amounted to 1.6 mmole H2 per g TS. The methane potential of the raw olive pulp and hydrogen-effluent was as high as 19 mmole CH4 per g TS suggesting that: a) olive pulp is a suitable substrate for methane production; and b) biohydrogen production can be very efficiently coupled with a subsequent step for methane production.

A hybrid anaerobic solid–liquid system for food waste digestion

2005 ◽  
Vol 52 (1-2) ◽  
pp. 223-228 ◽  
Author(s):  
J.Y. Wang ◽  
H. Zhang ◽  
O. Stabnikova ◽  
S.S. Ang ◽  
J.H. Tay
Keyword(s):  
Food Waste ◽  
Methane Production ◽  
Anaerobic Treatment ◽  
Liquid System ◽  
Ammonia Removal ◽  
Total Removal ◽  
Two Phase ◽  
Satisfactory Performance ◽  
Volatile Solids ◽  
Solid Liquid

A hybrid anaerobic solid – liquid (HASL) system was developed to enhance food waste bioconversion in comparison with the conventional two-phase anaerobic digester. The advantages of the HASL system were the higher efficiency of methane production and smaller volume of effluent from the system. The biogas, which was generated from the methanogenic phase, had an average methane content of 71–72%. Total removal of volatile solids consisted of 78–80%. The HASL system can be operated in both batch and semi-continuous modes with satisfactory performance. The addition of a submerged biofilter for ammonia removal to the HASL system further enhanced the performance of anaerobic digestion. Methane production in the enhanced HASL system was increased by 26% in comparison with the HASL system without submerged filter. This paper describes the development of the enhanced HASL system for anaerobic treatment of food waste.

scholarly journals Enhancing methane production from the invasive macroalga Rugulopteryx okamurae through anaerobic co-digestion with olive mill solid waste: process performance and kinetic analysis

2021 ◽  
Author(s):  
D. de la Lama-Calvente ◽  
M. J. Fernández-Rodríguez ◽  
J. Llanos ◽  
J. M. Mancilla-Leytón ◽  
R. Borja
Keyword(s):  
Anaerobic Digestion ◽  
Solid Waste ◽  
Methane Production ◽  
Methane Yield ◽  
Specific Rate ◽  
Order Kinetic ◽  
Two Phase ◽  
First Order ◽  
Olive Mill Solid Waste ◽  
Olive Mill

AbstractThe biomass valorisation of the invasive brown alga Rugulopteryx okamurae (Dictyotales, Phaeophyceae) is key to curbing the expansion of this invasive macroalga which is generating tonnes of biomass on southern Spain beaches. As a feasible alternative for the biomass management, anaerobic co-digestion is proposed in this study. Although the anaerobic digestion of macroalgae barely produced 177 mL of CH4 g−1 VS, the co-digestion with a C-rich substrate, such as the olive mill solid waste (OMSW, the main waste derived from the two-phase olive oil manufacturing process), improved the anaerobic digestion process. The mixture improved not only the methane yield, but also its biodegradability. The highest biodegradability was found in the mixture 1 R. okamurae—1 OMSW, which improved the biodegradability of the macroalgae by 12.9% and 38.1% for the OMSW. The highest methane yield was observed for the mixture 1 R. okamurae—3 OMSW, improving the methane production of macroalgae alone by 157% and the OMSW methane production by 8.6%. Two mathematical models were used to fit the experimental data of methane production time with the aim of assessing the processes and obtaining the kinetic constants of the anaerobic co-digestion of different combination of R. okamurae and OMSW and both substrates independently. First-order kinetic and the transference function models allowed for appropriately fitting the experimental results of methane production with digestion time. The specific rate constant, k (first-order model) for the mixture 1 R. okamurae- 1.5 OMSW, was 5.1 and 1.3 times higher than that obtained for the mono-digestion of single OMSW and the macroalga, respectively. In the same way, the transference function model revealed that the maximum methane production rate (Rmax) was also found for the mixture 1 R. okamurae—1.5 OMSW (30.4 mL CH4 g−1 VS day−1), which was 1.6 and 2.2 times higher than the corresponding to the mono-digestions of the single OMSW and sole R. okamurae (18.9 and 13.6 mL CH4 g−1 VS day−1), respectively.

The Temperature-Phased Anaerobic Biofilter Process

1994 ◽  
Vol 29 (9) ◽  
pp. 213-223 ◽  
Author(s):  
Sandra K. Kaiser ◽  
Richard R. Dague
Keyword(s):  
System Performance ◽  
Anaerobic Treatment ◽  
Size Ratio ◽  
High Rate ◽  
Phase System ◽  
Optimum Size ◽  
Treatment Technology ◽  
Two Phase ◽  
In Series ◽  
Two Temperature

The “temperature-phased anaerobic biofilter” or TPAB process (U.S. Patent pending), is a new high-rate anaerobic treatment system that includes a thermophilic (56°C) biofilter connected in series with a mesophilic (35°C) biofilter providing for two-temperature, two-phase treatment. Three TPAB systems of different thermophilic:mesophilic reactor size ratios were operated at system HRTs of 24 hrs, 36 hrs, and 48 hrs to characterize performance and to determine if an optimum size ratio exists between the thermophilic and mesophilic phases. The three TPAB systems achieved SCOD reductions in excess of 97% and TCOD reductions in excess of 90% for a synthetic milk substrate over a range of system COD loadings from 2 g COD/L/day to 16 g COD/L/day. There was little difference in performance between the three TPAB systems based on COD reduction and methane production. The 1:7 ratio of thermophilic:mesophilic phase TPAB system performed as well as the 1:3 and 1:1 size ratio TPAB systems. In applications of the process, a relatively small thermophilic first-phase can be used without sacrificing overall two-phase system performance. The TPAB process is a promising new anaerobic treatment technology with the ability to achieve higher efficiencies of organic removals than is generally possible for single-stage anaerobic filter systems operated at equivalent HRTs and organic loadings.

Final products and kinetics of biochemical and chemical sulfide oxidation under microaerobic conditions

2018 ◽  
Vol 78 (9) ◽  
pp. 1916-1924 ◽  
Author(s):  
Lucie Pokorna-Krayzelova ◽  
Dana Vejmelková ◽  
Lara Selan ◽  
Pavel Jenicek ◽  
Eveline I. P. Volcke ◽  
...  
Keyword(s):  
Mathematical Model ◽  
Oxidation Rate ◽  
Elemental Sulfur ◽  
Sulfide Oxidation ◽  
Cost Effective ◽  
Anaerobic Treatment ◽  
Batch Experiments ◽  
Cost Effective Method ◽  
Microaerobic Conditions ◽  
Kinetics Of

Abstract Hydrogen sulfide is a toxic and usually undesirable by-product of the anaerobic treatment of sulfate-containing wastewater. It can be removed through microaeration, a simple and cost-effective method involving the application of oxygen-limiting conditions (i.e., dissolved oxygen below 0.1 mg L−1). However, the exact transformation pathways of sulfide under microaerobic conditions are still unclear. In this paper, batch experiments were performed to study biochemical and chemical sulfide oxidation under microaerobic conditions. The biochemical experiments were conducted using a strain of Sulfuricurvum kujiense. Under microaerobic conditions, the biochemical sulfide oxidation rate (in mg S L−1 d−1) was approximately 2.5 times faster than the chemical sulfide oxidation rate. Elemental sulfur was the major end-product of both biochemical and chemical sulfide oxidation. During biochemical sulfide oxidation elemental sulfur was in the form of white flakes, while during chemical sulfide oxidation elemental sulfur created a white suspension. Moreover, a mathematical model describing biochemical and chemical sulfide oxidation was developed and calibrated by the experimental results.

Effects of thermochemical pretreatment on the anaerobic digestion of waste activated sludge

1997 ◽  
Vol 35 (8) ◽  
pp. 209-215 ◽  
Author(s):  
Shuzo Tanaka ◽  
Toshio Kobayashi ◽  
Ken-ichi Kamiyama ◽  
Ma. Lolita N. Signey Bildan
Keyword(s):  
Anaerobic Digestion ◽  
Activated Sludge ◽  
Production Rate ◽  
Methane Production ◽  
Waste Activated Sludge ◽  
Batch Experiments ◽  
Industrial Wastewaters ◽  
Thermochemical Pretreatment ◽  
Chemical Heating ◽  
Methane Production Rate

Effects of pretreatment on the anaerobic digestion of waste activated sludge (WAS) were investigated in terms of VSS solubilization and methane production by batch experiments. The methods of pretreatment studied are NaOH addition (chemical), heating (thermal) and heating with NaOH addition (thermochemical) to the domestic WAS and to the combined WAS from domestic, commercial and industrial wastewaters. The thermochemical pretreatment gave the best result among three methods in the combined WAS, i.e., the VSS was solubilized by 40-50% and the methane production increased by more than 200% over the control when the WAS was heated at 130°C for 5 minutes with the dose 0.3 g NaOH/g VSS. In the domestic WAS, the VSS solubilization rate was 70-80% but the increase of the methane production was about 30% after thermochemically pretreated. The domestic WAS consists of 41% protein, 25% lipid and 14% carbohydrate on COD basis, and the solubilization rate of protein, which is the largest constituent of the WAS, was 63% in the thermochemical pretreatment. Although the effect of the thermochemical pretreatment on the methane production was higher to the combined WAS than to the domestic WAS, the methane production rate was 21.9 ml CH4/g VSSWAS·day in the domestic WAS and 12.8 ml CH4/g VSSWAS·day in the combined WAS.

The influence of chemical structure on the anaerobic catabolism of refractory compounds: a case study of instant coffee wastes

1994 ◽  
Vol 30 (12) ◽  
pp. 223-232 ◽  
Author(s):  
N. G. Azhar ◽  
D. C. Stuckey
Keyword(s):  
Industrial Effluent ◽  
Anaerobic Treatment ◽  
Instant Coffee ◽  
Waste Sample ◽  
Coffee Waste ◽  
Refractory Compounds ◽  
Methane Potential ◽  
Bioassay Technique ◽  
High Concentrations

Due to concerns about meeting the strict legislation currently in force, anaerobic treatment is being investigated for the treatment of a variety of waste streams. Instant coffee wastes are one type of industrial effluent that appears to be amenable to anaerobic digestion, and this paper presents some results on the biodegradation of this effluent. The method used was a batch bioassay technique known as the Biochemical Methane Potential assay (BMP), which gave 84% degradation of a composite coffee waste sample. Various fractions of the coffee waste revealed mixed degradation results mostly attributed to structural differences, with the liquid fractions being almost 60% degradable, and the solids filter cake fraction, containing most of the lignocellulosic material being only 9% degradable. Volatile fatty acid (VFA) analysis revealed high concentrations of formate being formed and subsequently degraded in the bioconversion process, and a possible role for formate production was postulated. Variations in structure did not appear to affect the route by which VFAs were produced. Bioconversion of 5-6 major classes of pure organic compounds thought to be potentially recalcitrant in coffee effluent was investigated to determine possible mechanisms of degradation, and the extent to which structural variation affected degradability. The phenolics and chlorogenic acids gave the highest degradation of 70% and 60% respectively, and the cyclic volatiles the least degradation at 40%.

Effect of RE on Performance of Semi-Solid AlSi7 Alloy

2010 ◽  
Vol 426-427 ◽  
pp. 581-584 ◽  
Author(s):  
Rong Xi Yi ◽  
Shi Kun Xie ◽  
Xiao Qiu Zheng ◽  
Yong Ping Ai
Keyword(s):  
Phase Zone ◽  
Two Phase ◽  
Semi Solid ◽  
Solid Liquid ◽  
Different Content ◽  
Zone Temperature

The semi-solid slurry of AlSi7 alloy was prepared by near-liquids cast processing. The effects of different content of RE on the cast performance and the semi-solid remelting performance in AlSi7 alloy was researched. The results indicated that adding RE will widen the AlSi7 alloy solid-liquid two-phase zone temperature and refine the grains, silicon will obvious metamorphoses. The best amount of RE is about 0.5%. Its semi-solid remelting organization is equilateral globular grains.

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