High biofilm activity under increased oxygen concentrations in a pressurised biofilm system

2005 ◽  
Vol 52 (7) ◽  
pp. 69-75 ◽  
Author(s):  
K.F. Janning ◽  
S.N. Bak ◽  
M. Andersen ◽  
G.H. Kristensen
Keyword(s):  
Liquid Film ◽  
Reaction Rate ◽  
Removal Rate ◽  
Fold Increase ◽  
Order Rate Constant ◽  
Pilot Scale ◽  
Biofilm Reactor ◽  
Synthetic Wastewater ◽  
Film Diffusion ◽  
Zero Order Reaction

A new pressurised biofilm reactor (PBR) process with a patented disc system that enables constant biofilm control has been developed to treat concentrated wastewater with respect to easily degradable organic matter under pressures of up to 6 bar. The pressurisation enables a six-fold increase of the O2 saturation level and aeration capacity, which potentially increases the reaction rate of COD as long as O2 is limiting the reaction rate. Experiments performed in a pilot-scale PBR-reactor fed by synthetic wastewater were conducted to verify the potential and kinetics of heterotrophic conversion of O2 and acetate. Under O2-limited conditions the maximum removal rate of O2 and CODf was measured to rA,O2=60 g O2/m2/d and rA,CODf=150 g CODf/m2/d at 70 mg O2/l. Experiments verified that half-order kinetics could be applied but liquid film diffusion apparently influenced the reaction rate considerably. The observed half-order rate constant was experimentally determined to K½A,O2=7.0 (g O2)1/2m−1/2d−1 but this value is underestimated by 15% due to the observed liquid film diffusion. Based on this the intrinsic zero-order reaction rate was estimated at k0f,O2=190 kg O2/m3 biofilm/d when both liquid film and biofilm diffusion were taken into account.

Hydrolysis of organic wastewater particles in laboratory scale and pilot scale biofilm reactors under anoxic and aerobic conditions

1998 ◽  
Vol 38 (8-9) ◽  
pp. 179-188 ◽  
Author(s):  
K. F. Janning ◽  
X. Le Tallec ◽  
P. Harremoës
Keyword(s):  
Organic Matter ◽  
Mass Balance ◽  
Particulate Organic Matter ◽  
Removal Rate ◽  
Pilot Scale ◽  
Laboratory Scale ◽  
Synthetic Wastewater ◽  
Aerobic Conditions ◽  
Biofilm Reactors ◽  
Hydrolysis Of

Hydrolysis and degradation of particulate organic matter has been isolated and investigated in laboratory scale and pilot scale biofilters. Wastewater was supplied to biofilm reactors in order to accumulate particulates from wastewater in the filter. When synthetic wastewater with no organic matter was supplied to the reactors, hydrolysis of the particulates was the only process occurring. Results from the laboratory scale experiments under aerobic conditions with pre-settled wastewater show that the initial removal rate is high: rV, O2 = 2.1 kg O2/(m3 d) though fast declining towards a much slower rate. A mass balance of carbon (TOC/TIC) shows that only 10% of the accumulated TOC was transformed to TIC during the 12 hour long experiment. The pilot scale hydrolysis experiment was performed in a new type of biofilm reactor - the B2A® biofilter that is characterised by a series of decreasing sized granular media (80-2.5 mm). When hydrolysis experiments were performed on the anoxic pilot biofilter with pre-screened wastewater particulates as carbon source, a rapid (rV, NO3=0.7 kg NO3-N/(m3 d)) and a slowler (rV, NO3 = 0.3 kg NO3-N/(m3 d)) removal rate were observed at an oxygen concentration of 3.5 mg O2/l. It was found that the pilot biofilter could retain significant amounts of particulate organic matter, reducing the porosity of the filter media of an average from 0.35 to 0.11. A mass balance of carbon shows that up to 40% of the total incoming TOC accumulates in the filter at high flow rates. Only up to 15% of the accumulated TOC was transformed to TIC during the 24 hour long experiment.

Simplified and Monod kinetics in one-dimensional biofilm reactor modelling: a comparison

2001 ◽  
Vol 43 (1) ◽  
pp. 295-302 ◽  
Author(s):  
L. Bonomo ◽  
G. Pastorelli ◽  
E. Quinto
Keyword(s):  
Liquid Film ◽  
Removal Rate ◽  
Experimental Tests ◽  
Biofilm Reactor ◽  
Kinetic Approach ◽  
Monod Kinetics ◽  
One Dimensional ◽  
Monod Kinetic ◽  
The One ◽  
Reactor Models

A theoretical study supported by some experimental tests has been carried out with the aim of comparing one-dimensional (1-D) biofilm reactor models that use simplified (zero- and first-order) and Monod kinetics. Two different situations have been compared: one rate-limiting substrate with or without liquid film diffusion. The results obtained show that the use of a simplified kinetic approach compared to the Monod kinetic approach determines (1) an unjustified overestimate of the removal rate, especially for thin biofilms, and (2) an excessive overestimate of the liquid film layer thickness necessary to justify high kinetic orders. Even if recent research projects show that biofilm structure is more complicated than the one assumed in the modelling approach used in this study, nevertheless 1-D models still now continue to be the only ones that can reasonably support process engineers in biofilm reactor design, due to their intrinsic simplicity and the need for small sets of input data and parameters that can be obtained theoretically or often empirically.

Liquid film diffusion on reaction rate in submerged biofilters

1995 ◽  
Vol 29 (3) ◽  
pp. 947-952 ◽  
Author(s):  
Pia Christiansen ◽  
Line Hollesen ◽  
Poul Harremoës
Keyword(s):  
Liquid Film ◽  
Reaction Rate ◽  
Film Diffusion

scholarly journals Polishing of Chemical Oxygen Demand (COD) Using Moving Bed Bio-Reactor

2015 ◽  
Vol 773-774 ◽  
pp. 1281-1285
Author(s):  
Jamal Ali Kawan ◽  
Rakmi Abd-Rahman ◽  
Othman bin Jaafar ◽  
Fatihah Suja
Keyword(s):  
Chemical Oxygen Demand ◽  
Municipal Wastewater ◽  
Removal Rate ◽  
Research Work ◽  
Real Life ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
Biofilm Reactor ◽  
Moving Bed ◽  
Building Engineering

The pilot-scale experiment in moving bed biofilm reactor (MBBR) with a capacity of 433 L was carried out for this study with real life situations, it was decided that the complete research work must be done under as realistic conditions as possible,i.e.with real municipal wastewater, chemical free and with local commercially available products such as carriers for biofilm reactor. The reactor was start-up in 30/9/2013 up to date, Effluent from clarifier of STP used as influence of MBBR for polishing. MBBR is using continues down flow to polish effluent municipal wastewater from a faculty of new building engineering community in UKM to get the water free from main pollutant parameters, for reuse in the irrigation or discharge to the river. Laboratory experiments will conduct with different hydraulic retention time (HRT), filling ratio of plastic (Enviro Multi Media) in the MBBR about 5%. Aerobic reactors used the majority of the decaying organic material. An average removal rate of 41.75%, 32.85%, 24.80% and 35.77% of initial chemical oxygen demand (COD) were achieved under a HRT of 24hr, 12hr, 6hr and 2hr, respectively. The model simulated results showed good agreements with experimental results. The model could be employed in the design of a full-scale MBBR process for simultaneous removal of organic carbon from effluent STP.

Biological denitrification of a textile effluent in a dynamic sand filter

1998 ◽  
Vol 38 (1) ◽  
pp. 123-132 ◽  
Author(s):  
R. Canziani ◽  
L. Bonomo
Keyword(s):  
Removal Rate ◽  
Plug Flow ◽  
Pilot Scale ◽  
Zero Order ◽  
Biofilm Reactor ◽  
Textile Effluent ◽  
Order Kinetic ◽  
Sand Filter ◽  
Loading Rates ◽  
Nitrogen Bubbles

Post-denitrification of a pre-treated textile effluent was tested in a pilot-scale dynamic up-flow sand filter, which has been used as a biofilm reactor, together with filtration of suspended solids (SS) and decolorization. The potential application of the reactor as a three-in-one unit (decolorization, filtration and denitrification) has been successfully tested. Biomass growth and the sloughing of biological film did not prevent the removal of high concentrations of influent SS. Both pilot- and bench-scale tests confirmed that the intrinsic denitrification kinetics was zero-order, corresponding to a half-order removal rate if nitrate concentration is lower than 10 mgN l−1. Zero-order and half-order kinetic constants have also been calculated. At low nitrate loading rates (up to 2 kgN m−3 d−1) the filter followed the ideal plug-flow hydrodynamic model. In the lower part of the filter, zero-order kinetics fitted denitrification removal rates, while in the upper part of the filter denitrification followed half-order kinetics. At nitrate loading rates higher than 2.5 kgN m−3 d−1, nitrogen bubbles developed and partially mixed the reactor. Consequently, flatter concentration profiles were detected in the reactor and denitrification followed half-order kinetics along the entire filter.

High-rate nitrification of electronic industry wastewater by using nitrifying granules

2017 ◽  
Vol 76 (11) ◽  
pp. 3171-3180 ◽  
Author(s):  
Yoshiaki Hasebe ◽  
Hiroaki Meguro ◽  
Yuuki Kanai ◽  
Masahiro Eguchi ◽  
Toshifumi Osaka ◽  
...  
Keyword(s):  
Removal Rate ◽  
Pilot Scale ◽  
Ammonia Removal ◽  
High Rate ◽  
Synthetic Wastewater ◽  
Nitrifying Bacteria ◽  
Test Plant ◽  
Ammonia Oxidizing Bacteria ◽  
Water Conduction ◽  
Industry Wastewater

Abstract Nitrifying granules have a high sedimentation property and an ability to maintain a large amount of nitrifying bacteria in a reaction tank. Our group has examined the formation process of nitrifying granules and achieved high-rate nitrification for an inorganic synthetic wastewater using these granules. In this research, a pilot-scale test plant with an 850-liter reaction tank was assembled in a semiconductor manufacturing factory in order to conduct a continuous water conduction test using real electronics industry wastewater. The aim was to observe the formation of nitrifying granules and determine the maximum ammonia removal rate. The average granule diameter formed during the experiment was 780 μm and the maximum ammonia removal rate was observed to be 1.5 kgN·m−3·day−1 at 20 °C, which is 2.5–5 times faster than traditional activated sludge methods. A fluorescence in situ hybridization analysis showed that β-proteobacterial ammonia oxidizing bacteria and the Nitrospira-like nitrite-oxidizing bacteria dominate the bacteria population in the granules, and their strong aggregation capacity might confer some benefits to the formation of these nitrifying granules.

Dairy washwater treatment using a horizontal flow biofilm system

2008 ◽  
Vol 58 (9) ◽  
pp. 1879-1888 ◽  
Author(s):  
E. Clifford ◽  
M. Rodgers ◽  
D. de Paor
Keyword(s):  
Loading Rate ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Dairy Farm ◽  
Pilot Scale ◽  
Biofilm Reactor ◽  
Nitrate Contamination ◽  
Horizontal Flow ◽  
Ambient Temperatures ◽  
Economical Alternative

In Ireland, land-spreading is the most widely used method for treating dairy wastewaters. This can be labour intensive and can cause, in some cases, nitrate contamination of groundwater. In this study a simple pilot-scale horizontal flow biofilm reactor (HFBR) with a step-feed was developed and tested at a dairy farm site in County Offaly, Ireland for partial remediation of this soiled water prior to landspreading. During the 122-day study, the top surface plan area (TSPA) hydraulic loading rate was 50 L/m2/day. Influent concentrations averaged: 2904.2 mg total chemical oxygen demand (COD)/L, 950 mg 5-day biochemical oxygen demand (BOD5)/L and 177.9 mg total nitrogen (TN)/L. Between Days 1 and 45 frequent ambient temperatures below 4°C inhibited the build-up of biomass resulting in low removals. From Day 45 the HFBR unit removed 74.9% total COD and 69.6% BOD5, equivalent to TSPA removals of 108.8 g COD/m2/day and 33.1 g BOD5/m2/day. On Sheet 29, by the end of the study, the NH4–N had reduced from 123.1 mg/L in the influent to 37.0 mg/L. TN removal in the reactor averaged 56.0% equating to a TSPA removal rate of 5.0 g TN/m2/day. The HFBR does not require any mechanical aeration, was simple and inexpensive to construct and can provide a robust and economical alternative for the remediation of agricultural soiled water before landspreading.

scholarly journals Starch Production in Chlamydomonas reinhardtii through Supraoptimal Temperature in a Pilot-Scale Photobioreactor

Cells ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 1084
Author(s):  
Ivan N. Ivanov ◽  
Vilém Zachleder ◽  
Milada Vítová ◽  
Maria J. Barbosa ◽  
Kateřina Bišová
Keyword(s):  
Chlamydomonas Reinhardtii ◽  
Starch Content ◽  
Light Availability ◽  
Fold Increase ◽  
Pilot Scale ◽  
Temperature Treatment ◽  
Control Culture ◽  
Starch Accumulation ◽  
Cellular Division ◽  
Starch Production

An increase in temperature can have a profound effect on the cell cycle and cell division in green algae, whereas growth and the synthesis of energy storage compounds are less influenced. In Chlamydomonas reinhardtii, laboratory experiments have shown that exposure to a supraoptimal temperature (39 °C) causes a complete block of nuclear and cellular division accompanied by an increased accumulation of starch. In this work we explore the potential of supraoptimal temperature as a method to promote starch production in C. reinhardtii in a pilot-scale photobioreactor. The method was successfully applied and resulted in an almost 3-fold increase in the starch content of C. reinhardtii dry matter. Moreover, a maximum starch content at the supraoptimal temperature was reached within 1–2 days, compared with 5 days for the control culture at the optimal temperature (30 °C). Therefore, supraoptimal temperature treatment promotes rapid starch accumulation and suggests a viable alternative to other starch-inducing methods, such as nutrient depletion. Nevertheless, technical challenges, such as bioreactor design and light availability within the culture, still need to be dealt with.

Integrated Process for Textile Cotton Waste (TCW) Valorization: Waste-to-Energy and Wastewater Decontamination

2016 ◽  
Author(s):  
A. Ribeiro ◽  
C. Vilarinho ◽  
J. Araújo ◽  
J. Carvalho
Keyword(s):  
Raw Materials ◽  
Removal Rate ◽  
Low Cost ◽  
Calorific Value ◽  
Waste To Energy ◽  
Synthetic Wastewater ◽  
Small Scale ◽  
World Population ◽  
Cotton Waste ◽  
Textile Industries

The increasing of world population, industrialization and global consuming, existing market products existed in the along with diversification of raw materials, are responsible for an exponential increase of wastes. This scenario represents loss of resources and ultimately causes air, soils and water pollution. Therefore, proper waste management is currently one of the major challenges faced by modern societies. Textile industries represents, in Portugal, almost 10% of total productive transforming sector and 19% of total employments in the sector composed by almost 7.000 companies. One of the main environmental problems of textile industries is the production of significant quantities of wastes from its different processing steps. According to the Portuguese Institute of Statistics (INE) these industries produce almost 500.000 tons of wastes each year, with the textile cotton waste (TCW) being the most expressive. It was estimated that 4.000 tons of TCW are produced each year in Portugal. In this work an integrated TCW valorisation procedure was evaluated, firstly by its thermal and energetic valorisation with slow pyrolysis followed by the utilization of biochar by-product, in lead and chromium synthetic wastewater decontamination. Pyrolysis experiments were conducted in a small scale rotating pyrolysis reactor with 0.1 m3 of total capacity. Results of pyrolysis experiments showed the formation of 0,241 m3 of biogas for each kilogram of TCW. Results also demonstrated that the biogas is mostly composed by hydrogen (22%), methane (14 %), carbon monoxide (20%) and carbon dioxide (12%), which represents a total high calorific value of 12.3 MJ/Nm3. Regarding biochar, results of elemental analysis demonstrated a high percentage of carbon driving its use as low cost adsorbent. Adsorption experiments were conducted with lead and chromium synthetic wastewaters (25, 50 and 100 mg L−1) in batch vessels with controlled pH. It was evaluated the behaviour of adsorption capacity and removal rate of each metal during 120 minutes of contact time using 5, 10 and 50 g L−1 of adsorbent dosage. Results indicated high affinity of adsorbent with each tested metal with 78% of removal rate in chromium and 95% in lead experiments. This suggests that biochar from TCW pyrolysis may be appropriated to wastewaters treatment, with high contents of heavy metals and it can be an effective alternative to activated carbon.

Modeling the performance of biodegradation of textile wastewater using polyurethane foam sponge cube as a supporting medium

2010 ◽  
Vol 62 (12) ◽  
pp. 2801-2810 ◽  
Author(s):  
Yen-Hui Lin
Keyword(s):  
Steady State ◽  
Polyurethane Foam ◽  
Textile Wastewater ◽  
Pilot Scale ◽  
Biofilm Reactor ◽  
Column Test ◽  
Steady State Condition ◽  
Suspended Biomass ◽  
The Government ◽  
Carbon Dioxide Co2

A pilot-scale fixed-biofilm reactor (FBR) was established to treat textile wastewater to evaluate the feasibility of replacing conventional treatment processes that involve activated sludge and coagulation units. A kinetic model was developed to describe the biodegradation of textile wastewater by FBR. Batch kinetic tests were performed to evaluate the biokinetic parameters that are used in the model. FBR column test was fed with a mean COD of 692 mg/L of textile wastewater from flow equalization unit. The influent flow rate was maintained at 48.4 L/h for FBR column test. Experimental data and model-predicted data for substrate effluent concentration (as COD), concentration of suspended biomass in effluent and the amount of carbon dioxide (CO2) produced in the effluent agree closely with each other. Microscopic observations demonstrated that the biofilm exhibited a uniform distribution on the surface of polyurethane foam sponge. Under a steady-state condition, the effluent COD from FBR was about 14.7 mg COD/L (0.0213 Sb0), meeting the discharge standard (COD < 100 mg/L) that has been set by the government of Taiwan for textile wastewater effluent. The amount of biofilm and suspended biomass reached a maximal value in the steady state when the substrate flux reached a constant value and remained maximal. Approximately 33% of the substrate concentration (as COD) was converted to CO2 during biodegradation in the FBR test. The experimental and modeling schemes proposed in this study could be employed to design a full-scale FBR to treat textile wastewater.

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