Dutch analysis for P-recovery from municipal wastewater

2004 ◽  
Vol 49 (10) ◽  
pp. 191-199 ◽  
Author(s):  
P. Roeleveld ◽  
P. Loeffen ◽  
H. Temmink ◽  
B. Klapwijk

There is a considerable practical interest in phosphorus recovery from water authorities, elementary P-industry, fertilizer industry and regulators in a number of countries. Due to a handful of full-scale plants worldwide, P-recovery can be seen as technically feasible. However, the economic feasibility of P-recovery from sewage can still be judged as dubious. The most important reason for this is that the prices of the techniques (in €/tonne P) are much higher compared to the prices of phosphate rock. In this paper an analysis is given to recover phosphate from municipal wastewater for the elementary P-industry Thermphos International B.V. and the fertiliser industry Amsterdam Fertilizers B.V. in The Netherlands. Several scenarios are evaluated and the end products of these scenarios are compared to the quality required by both industries. From a Dutch study it became clear that all end products from the final sludge treatment do not provide a good source of secondary phosphate. As a consequence of this, the most preferred possibility for P-recovery is to extract phosphate before sludge goes to the final sludge treatment. Different scenarios can be selected based on the position of P-recovery in the WWTP configuration, the type of P-recovery product, and the precipitation technique. Local conditions will determine which scenario is the most expedient. Because it is more realistic to judge a practical situation instead of theoretical estimations based on literature, some local situations have to be assessed in sufficient detail to gain more feeling for the expenses and possible savings of P-recovery. One important actor that should be involved in the process management around P-recovery, is the national government. Especially, the Government have the responsibility for sustainable development and should have attention for some stimulation of P-recovery in The Netherlands. Water authorities and the P- and fertilizer industry made already some good steps.

Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2697
Author(s):  
Gabriel Gerner ◽  
Luca Meyer ◽  
Rahel Wanner ◽  
Thomas Keller ◽  
Rolf Krebs

Phosphorus recovery from waste biomass is becoming increasingly important, given that phosphorus is an exhaustible non-renewable resource. For the recovery of plant nutrients and production of climate-neutral fuel from wet waste streams, hydrothermal carbonization (HTC) has been suggested as a promising technology. In this study, digested sewage sludge (DSS) was used as waste material for phosphorus and nitrogen recovery. HTC was conducted at 200 °C for 4 h, followed by phosphorus stripping (PS) or leaching (PL) at room temperature. The results showed that for PS and PL around 84% and 71% of phosphorus, as well as 53% and 54% of nitrogen, respectively, could be recovered in the liquid phase (process water and/or extract). Heavy metals were mainly transferred to the hydrochar and only <1 ppm of Cd and 21–43 ppm of Zn were found to be in the liquid phase of the acid treatments. According to the economic feasibility calculation, the HTC-treatment per dry ton DSS with an industrial-scale plant would cost around 608 USD. Between 349–406 kg of sulfuric acid are required per dry ton DSS to achieve a high yield in phosphorus recovery, which causes additional costs of 96–118 USD. Compared to current sewage sludge treatment costs in Switzerland, which range between 669 USD and 1173 USD, HTC can be an economically feasible process for DSS treatment and nutrient recovery.


2018 ◽  
Vol 78 (12) ◽  
pp. 2597-2607
Author(s):  
Fanzhe Zeng ◽  
Wenbiao Jin ◽  
Qingliang Zhao

Abstract A novel sewage sludge treatment process is developed in which sludge anaerobically phosphorus (P) released with the temperature control/ultrasonic treatment and recovery with human urine are incorporated to a conventional anaerobic/aerobic (A/O) process. The results showed that temperature affected the anaerobic P release and the maximum orthophosphate (PO43–P) release rate was 21.68 mg PO43–P/(g MLVSS.h) at 20 °C. The optimal specific energy of ultrasonic treatment was 15,000 kJ/kg TS, at which the solubilization degree of soluble chemical oxygen demand (SCOD) was 37.93%, which verified that the anaerobic sludge flocs were broken and the organic matter was obviously released. Human urine and P-rich sludge stream could be verified as a feasible way of P recovery in the form of struvite. The output of P in the combined A/O treatment process consisted of three pathways (i.e., effluent wastewater, sewage sludge, and P recovery). The influent P could be recovered by 22.84% and about 1.48 g/d potential struvite could be recovered from the anaerobic sludge flow using 0.27 L/d-human urine. The mass balances of COD and nitrogen (N) indicated that the combined A/O process also improved the organic mineralization and the removal of N.


2017 ◽  
Vol 76 (2) ◽  
pp. 413-424 ◽  
Author(s):  
A. Nättorp ◽  
K. Remmen ◽  
C. Remy

Phosphorus (P) recovery from wastewater has considerable potential to supplement limited fossil P reserves. Reliable cost data are essential for investor and policymaker decisions. In this study, investment and operational costs for nine P recovery processes were calculated from the investor's perspective, taking into account all relevant side effects on the sludge treatment or the wastewater treatment plant. The assessment was based on pilot and full-scale data which were thoroughly consolidated and standardized with technical and cost data from the German wastewater–sludge treatment train to enable direct comparison. The cost influence of precipitation processes on the current wastewater–sludge treatment train ranges from −0.14 (generating profit) to 0.23 EUR per population equivalent (PE) and year, while the cost influence of sludge leaching processes is around 2.50 EUR/(PE y). The cost influence of processes using dry sludge and mono-incineration ash varies between 0.33 and 3.13 EUR/(PE y), depending on existing disposal pathways, mono-incineration, co-incineration or agricultural use of sludge. The specific costs per kg P recovered (−4 to 10 EUR/kg P) are in general higher than conventional fertilizer production (1.6 EUR/kg P). However, annual costs per PE represent less than 3% of the total costs for wastewater disposal.


HortScience ◽  
2008 ◽  
Vol 43 (3) ◽  
pp. 868-874 ◽  
Author(s):  
Robert F. Polomski ◽  
Douglas G. Bielenberg ◽  
Ted Whitwell ◽  
Milton D. Taylor ◽  
William C. Bridges ◽  
...  

Intensive production of container-grown nursery and greenhouse crops in soilless substrate may result in significant leaching of nutrients and pesticides. The resulting runoff can escape from production areas and negatively impact surface and ground water. Constructed wetlands (CWs) have been shown to be a simple, low-technology method for treating agricultural, industrial, and municipal wastewater. We investigated the nitrogen (N) and phosphorus (P) removal potential by a vegetated, laboratory-scale subsurface flow (SSF) CW system. Over an 8-week period, five commercially available aquatic garden plants received a range of N and P (0.39 to 36.81 mg·L−1 N and 0.07 to 6.77 mg·L−1 P) that spanned the rates detected in nursery runoff. Whole plant dry weight was positively correlated with N and P supplied. Highest N and P recovery rates were exhibited by Thalia geniculata f. rheumoides Shuey and Oenenathe javanica (Blume) DC. ‘Flamingo’, Phyla lanceolata (Michx.) Greene also had high P recovery rates. The potential exists for using SSF CWs to concomitantly produce aquatic garden plants and attenuate nutrients in a sustainable nursery enterprise.


2019 ◽  
Vol 11 (2) ◽  
pp. 376 ◽  
Author(s):  
John Hallas ◽  
Cheryl Mackowiak ◽  
Ann Wilkie ◽  
Willie Harris

Small, municipal wastewater treatment plants (WWTPs) that use aerobic digestion treat approximately 40% of the discharged wastewater in the USA, and yet they are an overlooked source of recoverable P. There are no known reports of small, aerobic WWTPs recovering P through struvite (MgNH4PO4·6H2O) precipitation for repurposing as a mineral fertilizer, even though some large WWTPs with anaerobic digestion are. Four small WWTPs in north Florida, USA, with treatment capacities from 371 to 2650 m3 wastewater d−1 and incoming P loads from 2 to 14 kg d−1 were investigated for their potential to produce struvite from digester filtrates. A chemical equilibrium model was used to predict the feasibility of struvite production and the results compared with actual WWTP filtrate measurements. Filtrates from aerobic digesters were able to form struvite if solution pH was increased by ≤1 pH unit. Depending on the WWTP, P recovery in filtrates through struvite precipitation ranged from 27–57% by mass at pH 8.5, via NaOH additions or air sparging. Increasing filtrate Mg concentrations improved P recovery up to 97%. Based upon these results, small WWTPs using aerobic digestion will be able to lower their P waste output through recovery as struvite fertilizer.


2020 ◽  
Vol 12 (24) ◽  
pp. 10632
Author(s):  
Augusto Bianchini ◽  
Jessica Rossi

The recovery of phosphorus (P) from waste streams in specific industrial processes could really contribute to a more sustainable P supply chain, which is considered critical due to its high-risk economic relevance and to negative impacts on the environment. Although more than 30 types of P recovery technologies are already available, their full-scale implementation is not widespread. To make solutions for P recovery in the industrial sector mainstream, it is necessary to change the perception of companies that own flows rich in P, often considered an issue. The lack of decision-making tools and methodologies to identify the optimal solution for specific cases limits the diffusion of P recovery technologies. To unlock this situation, this paper proposes an integrated industry-oriented methodology to facilitate knowledge transfer from the scientific community to the industrial sector, supporting companies in the evaluation of technical, economic, environmental and social benefits/risks of P recovery. The methodology, applied to an Italian case study, uses both innovative and consolidated tools to provide quantitative information at the firm level to investigate a closed P loop: starting from mapping P flows in the industrial process, the methodology guides companies in the choice of the most suitable option for its business strategy, providing data to evaluate the economic feasibility of the investment and some Key Performance Indicators (KPIs) to assess and monitor their efficiency in managing P. The methodology can be replicated in other contexts by both companies and consultants to explore and disseminate the opportunity to recover and reuse P from industries. The evaluation of the selected KPIs can be integrated into scientific analyses to compare solutions and to accelerate the shift from pilot to full-scale implementation of promising technologies. Finally, it can be used as an exercise for the training of new professionals in the P management sector.


Membranes ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 388
Author(s):  
Ihtisham Ul Haq Shami ◽  
Bing Wu

In this study, three gravity-driven membrane (GDM) reactors with flat sheet membrane modules and various biocarriers (synthetic fibers, lava stones, and sands) were operated for municipal wastewater treatment. The effects of water head, periodically cleaning protocol, and operation temperature on the GDM reactor performance were illustrated in terms of membrane performance and water quality. The results indicated that: (1) the cake layer fouling was predominant (>~85%), regardless of reactor configuration and operation conditions; (2) under lower water head, variable water head benefited in achieving higher permeate fluxes due to effective relaxation of the compacted cake layers; (3) the short-term chemical cleaning (30–60 min per 3–4 days) improved membrane performance, especially when additional physical shear force was implemented; (4) the lower temperature had negligible effect on the GDM reactors packed with Icelandic lava stones and sands. Furthermore, the wastewater treatment costs of the three GDM reactors were estimated, ranging between 0.31 and 0.37 EUR/m3, which was greatly lower than that of conventional membrane bioreactors under lower population scenarios. This sheds light on the technical and economic feasibility of biocarrier-facilitated GDM systems for decentralized wastewater treatment in Iceland.


Author(s):  
Ю.А. Егорова ◽  
В.И. Кичигин ◽  
О.И. Нестеренко ◽  
А.А. Юдин

Осадки городских очистных канализационных сооружений являются самым массовым технологическим отходом, создающим проблемы утилизации для любого города. Рассмотрены возможные методы обработки осадков сточных вод на городских очистных канализационных сооружениях городского округа Самара с целью их последующей утилизации. Обозначены причины и приведены документальные подтверждениянекорректности возложения ответственности за обращение с такими отходами только на организации водопроводно-канализационного хозяйства. Рассмотрен способ захоронения обезвоженного осадка сточных вод в обвалованном полигоне. Установлено, что обработанные на очистных сооружениях осадки относятся к V классу опасности для окружающей среды. Обработанные, стабилизированные, подсушенные, обезвреженные отходы осадков сточных вод (малоопасный осадок с песколовок при очистке хозяйственно-бытовых и смешанных сточных вод, практически не опасный осадок с песколовок при очистке хозяйственно-бытовых и смешанных сточных вод и избыточный ил биологических очистных сооружений в смеси с сырым осадком) могут быть использованы в качестве наполнителей бетонно-цементных смесей и органоминеральных удобрений или переданы для утилизации сторонним организациям. Sludge from the municipal wastewater treatment facilities is the most massive technological waste that causes trouble for any city. Possible methods of wastewater sludge treatment at the municipal wastewater treatment facilities of the Samara Urban District with the purpose of its further utilization are considered. The reasons are indicated and documentary evidence of the incorrectness of assigning the responsibility for processing such wastes only to the water and wastewater utilities is provided. The method of landfilling dewatered wastewater sludge in a ridged landfill is considered. It has been established that the sludge processed at the wastewater treatment facilities is referred to the V class of environmental hazard. Sludge subjected to the treatment, stabilization, drying and neutralization (low hazardous sludge from grit chambers for domestic and mixed wastewater treatment; almost non-hazardous sludge from grit chambers for domestic and mixed wastewater treatment and excess sludge from biological treatment facilities mixed with raw sludge) can be used as fillers for concrete-cement mixtures and organo-mineral fertilizers or transferred for disposal to outside companies.


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