A multivariate calibration procedure for UV/VIS spectrometric quantification of organic matter and nitrate in wastewater

2003 ◽  
Vol 47 (2) ◽  
pp. 63-71 ◽  
Author(s):  
G. Langergraber ◽  
N. Fleischmann ◽  
F. Hofstädter
Keyword(s):  
Municipal Wastewater ◽  
Multivariate Calibration ◽  
Correlation Coefficients ◽  
Calibration Procedure ◽  
Calibration Model ◽  
Long Term Stability ◽  
Global Calibration ◽  
Outlier Tests ◽  
Single Instrument

A submersible UV/VIS spectrometer for in-situ real-time measurements is presented. It utilises the UV/VIS range (200-750 nm) for simultaneous measurement of COD, filtered COD, TSS and nitrate with just a single instrument. A global calibration is provided that is valid for typical municipal wastewater compositions. Usually high correlation coefficients can be achieved using this standard setting. By running a local calibration improvements concerning trueness, precision and long term stability of the results can be achieved. The calibration model is built by means of PLS, various validation procedures and outlier tests to reach both high correlation quality and robustness. This paper describes the UV/VIS spectrometer and the calibration procedure.

scholarly journals Long-term stability of maxillary anterior alignment in non-extraction cases

2013 ◽  
Vol 18 (3) ◽  
pp. 46-53 ◽  
Author(s):  
Luiz Filiphe Gonçalves Canuto ◽  
Marcos Roberto de Freitas ◽  
Karina Maria Salvatore de Freitas ◽  
Rodrigo Hermont Cançado ◽  
Leniana Santos Neves
Keyword(s):  
Pearson Correlation ◽  
Correlation Coefficients ◽  
Term Stability ◽  
Long Term Stability ◽  
Irregularity Index ◽  
Posttreatment Period ◽  
Fixed Appliances ◽  
Maxillary Incisors ◽  
Dental Cast

OBJECTIVE: The purpose of this retrospective study was to evaluate long-term stability of maxillary incisors alignment in cases submitted to non-extraction orthodontic treatment. METHODS: The sample comprised 23 patients (13 female; 10 male) at a mean initial age of 13.36 years (SD = 1.81 years), treated with fixed appliances. Dental cast measurements were obtained at three different time points (T1 - pretreatment, T2 - posttreatment and T3 - long-term posttreatment). Variables assessed in maxillary arch were Little Irregularity Index, intercanine, interpremolar and intermolar widths, arch length and perimeter. The statistical analysis was performed by one-way ANOVA and Tukey tests when necessary. Pearson' correlation coefficients were used to investigate possible associations between the evaluated variables. RESULTS: There was no significant change in most arch dimension measurements during and after treatment, however, during the long-term posttreatment period, it was observed a significant maxillary incisors crowding relapse. CONCLUSION: The maxillary incisors irregularity increased significantly (1.52 mm) during long-term posttreatment. None of the studied clinical factors demonstrated to be predictive of the maxillary crowding relapse.

scholarly journals Validation of Preliminary Results of Thermal Tropopause Derived from FY-3C GNOS Data

2019 ◽  
Vol 11 (9) ◽  
pp. 1139 ◽  
Author(s):  
Ziyan Liu ◽  
Yueqiang Sun ◽  
Weihua Bai ◽  
Junming Xia ◽  
Guangyuan Tan ◽  
...  
Keyword(s):  
Correlation Coefficients ◽  
Satellite System ◽  
Research Field ◽  
Temperature Profiles ◽  
Temperature Deviation ◽  
Climate Research ◽  
Long Term Stability ◽  
Research Fields ◽  
Global Navigation Satellite

The state-of-art global navigation satellite system (GNSS) occultation sounder (GNOS) onboard the FengYun 3 series C satellite (FY-3C) has been in operation for more than five years. The accumulation of FY-3C GNOS atmospheric data makes it ready to be used in atmosphere and climate research fields. This work first introduces FY-3C GNOS into tropopause research and gives the error evaluation results of long-term FY-3C atmosphere profiles. We compare FY-3C results with Constellation Observing System for Meteorology, Ionosphere and Climate (COSMIC) and radiosonde results and also present the FY-3C global seasonal tropopause patterns. The mean temperature deviation between FY-3C GNOS temperature profiles and COSMIC temperature profiles from January 2014 to December 2017 is globally less than 0.2 K, and the bias of tropopause height (TPH) and tropopause temperature (TPT) annual cycle derived from both collocated pairs are about 80–100 m and 1–2 K, respectively. Also, the correlation coefficients between FY-3C GNOS tropopause parameters and each radiosonde counterpart are generally larger than 0.9 and the corresponding regression coefficients are close to 1. Multiple climate phenomena shown in seasonal patterns coincide with results of other relevant studies. Our results demonstrate the long-term stability of FY-3C GNOS atmosphere profiles and utility of FY-3C GNOS data in the climate research field.

scholarly journals Recovering Long-term Aerosol Optical Depth Series (1976–2012) from an Astronomical Potassium-based Resonance Scattering Spectrometer

2014 ◽  
Vol 7 (4) ◽  
pp. 4093-4121 ◽  
Author(s):  
A. Barreto ◽  
E. Cuevas ◽  
P. Pallé ◽  
P. M. Romero ◽  
F. Almansa ◽  
...  
Keyword(s):  
Aerosol Optical Depth ◽  
Optical Depth ◽  
Correlation Coefficients ◽  
Resonant Scattering ◽  
Resonance Scattering ◽  
Data Series ◽  
Long Term Stability ◽  
Filter Radiometer ◽  
Scattered Component

Abstract. A 37 year long-term series of monochromatic Aerosol Optical Depth (AOD) has been recovered from solar irradiance measurements performed with the solar spectrometer Mark-I, deployed at Izaña mountain since 1976. The instrument operation is based on the method of resonant scattering, which presents a long-term stability and high precision in comparison to other instruments based on interference filters. However, it has been specifically designed as a reference instrument for helioseismology, and its ability to determine AOD from transmitted and scattered monochromatic radiation at 769.9 nm inside a potassium vapor cell in the presence of a permanent magnetic field is evaluated in this paper. Particularly, the use of an exposed mirrors arrangement to collect sunlight as well as the Sun-laboratory velocity dependence of the scattered component introduces some inconveniences when we perform the instrument's calibration. We have solved this problem using a quasi-continuous Langley calibration technique and a refinement procedure to correct for calibration errors as well as for the fictitious diurnal cycle on AOD data. Our results showed that calibration errors associated to the quasi-continuous Langley technique are not dependent on aerosol load, provided aerosol concentration remains constant throughout the day, assuring the validity of this technique for those periods with relatively high aerosol content required to calibrate the scattered component. The comparative analysis between the recovered AOD dataset from Mark-I and collocated quasi-simultaneous data from Cimel AErosol RObotic NETwork (AERONET) and Precision Filter Radiometer (PFR) instruments showed an absolute mean bias ≤ 0.01 in the 11 year and 12 year comparison, respectively. High correlation coefficients between AERONET/Mark-I and PFR/Mark-I pairs confirmed a very good linear relationship between instruments, proving that recovered AOD data series from Mark-I can be used together PFR and AERONET AOD data to build a long-term AOD data series at Izaña site (1976–now), suitable for future analysis of aerosols trends and inter-annual variability. Finally, the AOD preliminary trend analysis in the 29 year period from 1984 to 2012 with Mark-I AOD revealed no significant trends. However, we detected a negative significant trend of 0.047 decade−1 during the period 1984–1993.

New Hybrid Algorithm for Maintaining Multivariate Quantitative Calibrations of a Near-Infrared Spectrometer

2002 ◽  
Vol 56 (5) ◽  
pp. 605-614 ◽  
Author(s):  
Christine M. Wehlburg ◽  
David M. Haaland ◽  
David K. Melgaard ◽  
Laura E. Martin
Keyword(s):  
Least Squares ◽  
Real Time ◽  
Hybrid Model ◽  
Hybrid Algorithm ◽  
Near Infrared ◽  
Multivariate Calibration ◽  
Calibration Model ◽  
Spectral Variation ◽  
Calibration Data

Our newly developed prediction-augmented classical least-squares/partial least-squares (PACLS/PLS) hybrid algorithm can correct for the presence of unmodeled sources of spectral variation such as instrument drift by explicitly incorporating known or empirically derived information about the unmodeled spectral variation. We have tested the ability of the new hybrid algorithm to maintain a multivariate calibration in the presence of instrument drift using a near-infrared (NIR) spectrometer (7500–11 000 cm−1) to quantitate dilute aqueous solutions containing glucose, ethanol, and urea. The spectral variations required to update the multivariate models for both short- and long-term drift were obtained using a single representative midpoint sample whose spectrum was repeatedly measured during collection of calibration data and during collection of separate validation sample spectra on three subsequent days. The performance of the PACLS/PLS model for maintaining a calibration was compared to PLS with subset recalibration, a method that has previously been applied to maintenance and transfer of calibration. Without drift corrections, both PACLS/PLS and PLS had poor predictive ability on sample spectra collected on subsequent days. Unlike previous maintenance of calibration studies that corrected for long-term drift only, the PACLS/PLS and PLS models demonstrated the best predictive abilities when short-term drift was also corrected. The PACLS/PLS hybrid model outperformed PLS with subset recalibration for near real-time predictions when instrument drift was determined from the repeat samples closest in time to the measurement of the unknown. Near real-time standard errors of prediction (SEPs) for the hybrid model were comparable to the cross-validated SEPs obtained with the original calibration model.

scholarly journals Recovering long-term aerosol optical depth series (1976–2012) from an astronomical potassium-based resonance scattering spectrometer

2014 ◽  
Vol 7 (12) ◽  
pp. 4103-4116 ◽  
Author(s):  
A. Barreto ◽  
E. Cuevas ◽  
P. Pallé ◽  
P. M. Romero ◽  
C. Guirado ◽  
...  
Keyword(s):  
Aerosol Optical Depth ◽  
Optical Depth ◽  
Correlation Coefficients ◽  
Resonant Scattering ◽  
Resonance Scattering ◽  
Data Series ◽  
Data Set ◽  
Long Term Stability ◽  
Filter Radiometer

Abstract. A 37-year long-term series of monochromatic aerosol optical depth (AOD) has been recovered from solar irradiance measurements performed with the solar spectrometer Mark-I, deployed at Izaña mountain since 1976. The instrument operation is based on the method of resonant scattering, which affords wavelength absolute reference and stability (long-term stability and high precision) in comparison to other instruments based purely on interference filters. However, it has been specifically designed as a reference instrument for helioseismology, and its ability to determine AOD from transmitted and scattered monochromatic radiation at 769.9 nm inside a potassium vapour cell in the presence of a permanent magnetic field is evaluated in this paper. Particularly, the use of an exposed mirror arrangement to collect sunlight as well as the Sun–laboratory velocity dependence of the scattered component introduces some important inconveniences to overcome when we perform the instrument's calibration. We have solved this problem using a quasi-continuous Langley calibration technique and a refinement procedure to correct for calibration errors as well as for the fictitious diurnal cycle on AOD data. Our results showed similar calibration errors retrieved by means of this quasi-continuous Langley technique applied in different aerosol load events (from 0.04 to 0.3), provided aerosol concentration remains constant throughout the calibration interval. It assures the validity of this technique when it is applied in those periods with relatively high aerosol content. The comparative analysis between the recovered AOD data set from the Mark-I and collocated quasi-simultaneous data from the Cimel-AErosol RObotic NETwork (AERONET) and Precision Filter Radiometer (PFR) instruments showed an absolute mean bias ≤ 0.01 in the 10- and 12-year comparison, respectively. High correlation coefficients between AERONET and Mark-I and PFR/Mark-I pairs confirmed a very good linear relationship between instruments, proving that recovered AOD data series from Mark-I can be used together with PFR and AERONET AOD data to build a long-term AOD data series at the Izaña site (1976–now), suitable for future analysis of aerosols trends and inter-annual variability. Finally, the AOD preliminary trend analysis in the 29-year period from 1984 to 2012 with Mark-I AOD revealed no significant trends.

Quantification of an Active Substance in a Tablet by NIR and Raman Spectroscopy

1998 ◽  
Vol 6 (1) ◽  
pp. 279-289 ◽  
Author(s):  
Ingela Jedvert ◽  
Mats Josefson ◽  
Frans Langkilde
Keyword(s):  
Raman Spectroscopy ◽  
Active Substance ◽  
Reference Method ◽  
Spectroscopic Technique ◽  
Calibration Model ◽  
Baseline Correction ◽  
Spectroscopic Techniques ◽  
Long Term Stability ◽  
Calibration Models

Spectroscopic techniques in combination with chemometrics give opportunities to analyse tablets without time-consuming sample preparation. The aim of the present study was to develop a method to quantify the active substance, isosorbide-5-mononitrate, in Imdur® 120 mg tablets either by NIR diffuse reflectance or Raman spectroscopy. The calibration set was selected to simulate, with the available samples, as closely as possible a full factorial design with three factors. The reference method was liquid chromatography (LC). Calibration models with different baseline correction methods, different parts of wavelength range and different measures of weights have been evaluated. The calibration model found for each spectroscopic technique is discussed. The accuracy for the spectroscopic techniques were equal in merit to the LC method. Both the NIR and the Raman calibrations also showed a good long-term stability. With the baseline correction methods used for the spectra, it was possible to analyse tablets after 1.5 years. In conclusion it is possible to quantify Imdur® 120 mg with either NIR or Raman spectroscopy.

scholarly journals Development and evaluation of woven fabric immersed membrane bioreactor for treatment of domestic waste water for re-use

2014 ◽  
Author(s):  
◽  
Mxolisi Norman Cele
Keyword(s):  
Wastewater Treatment ◽  
Membrane Bioreactor ◽  
Municipal Wastewater ◽  
Domestic Wastewater ◽  
Pilot Scale ◽  
Woven Fabric ◽  
Small Scale ◽  
Critical Flux ◽  
Long Term Stability

Increased public concern over health and the environment, the need to expand existing wastewater treatment plants due to population increase, and increasingly stringent discharge requirements, have created a need for new innovative technologies that can generate high quality effluent at affordable cost for primary and secondary re-use. The membrane biological reactor (MBR) process is one of the innovative technologies that warrant consideration as a treatment alternative where high quality effluent and/or footprint limitations are a prime consideration. MBR processes have been applied for the treatment of industrial effluent for over ten years (Harrhoff, 1990). In this process, ultrafiltration or microfiltration membranes separate the treated water from the mixed liquor, replacing the secondary settling tanks of the conventional activated sludge process. Historically, energy costs associated with pumping the treated water through the membranes have limited widespread application for the treatment of high volumes of municipal wastewater. However, recent advancements and developments in membrane technology have led to reduced process energy costs and induced wider application for municipal wastewater treatment (Stephenson et al., 2000). This report describes a small and pilot scale demonstration study conducted to test a woven fabric microfiltration immersed membrane bioreactor (WFM-IMBR) process for use in domestic wastewater treatment. The study was conducted at Durban Metro Southern Wastewater Treatment Works, Veolia Plant, South Africa. The main objective of this project was to develop and evaluate the performance of an aerobic woven fabric microfiltration immersed membrane bioreactor (WFM-IMBR) for small scale domestic wastewater treatment. The experiments were oriented towards three sub objectives: to develop the membrane pack for immersed membrane bioreactor based on WF microfilters; to evaluate the hydrodynamics of WF membrane pack for bioreactor applications; and to evaluate the long-term performance and stability of WFM-IMBR in domestic waste water treatment. The literature was reviewed on membrane pack design for established commercial IMBR. The data collected from literature was then screened and used to design the WF membrane pack. Critical flux was used as the instrument to measure the WF membrane pack hydrodynamics. Long-term operation of the WFM-IMBR was in two folds: evaluating the performance and long term stability of WFM-IMBR. The membrane pack of 20 flat sheet rectangular modules (0.56 m by 0.355 m) was developed with the gap of 5 mm between the modules. The effects of parameters such as mixed liquor suspended solids or aeration on critical flux were examined. It was observed that the critical flux decreased with the increase of sludge concentration and it could be enhanced by improving the aeration intensity as expected and in agreement with the literature. Hence the operating point for long term subcritical operation was selected to be at a critical flux of 30 LMH and 7.5 L/min/module of aeration. Prior to the long term subcritical flux of WFM-IMBR, the operating point was chosen based on the hydrodynamic study of the WF membrane pack. The pilot scale WFM-IMBR demonstrated over a period of 30 days that it can operate for a prolonged period without a need for cleaning. Under subcritical operation, it was observed that there was no rise in TMP over the entire period of experimentation. Theoretically this was expected but it was never investigated before. Good permeate quality was achieved with 95% COD removal and 100% MLSS removal. The permeate turbidity was found to be less than 1 NTU and it decreased with an increase in time and eventually stabilized over a prolonged time. Woven fibre membranes have demonstrated great potential in wastewater treatment resulting in excellent COD and MLSS removal; low permeate turbidity and long term stability operation. From the literature surveyed, this is the first study which investigated the use of WF membranes in IMBRs. The study found that the small scale WFM-IMBR unit can be employed in fifty equivalence person and generate effluent that is free of suspended solids, having high levels of solid rejection and has acceptable discharge COD for recycle. Future work should be conducted on energy reduction strategies that can be implemented in WFM-IMBR for wastewater treatment since high energy requirements have been reported by commercial IMBRs.

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