Diffuse sources of heavy metals in the Rhine basin

2001 ◽  
Vol 44 (7) ◽  
pp. 41-49 ◽  
Author(s):  
V. Mohaupt ◽  
U. Sieber ◽  
J. van den Roovaart ◽  
C. G. Verstappen ◽  
F. Langenfeld ◽  
...  

An estimate of diffuse sources of heavy metals (Hg, Cd, Cu, Zn, Pb, Cr, Ni) in the Rhine catchment stressed the urban storm water discharges in the German part and drainage flow in the Dutch part as the most important pathways. Additional sources are erosion and, to a far lesser extent, atmospheric deposition on open water areas. All other pathways were of minor importance. Meanwhile, after reduction of the point sources by between 72-95%, the diffuse sources dominate the total emissions. For several metals the anthropogenic diffuse sources amounted to 40-80%, the point sources to 15-40% and the geogeneous sources to 5-40%. The estimated inputs sufficiently agreed with the loads of the river Rhine. For the estimation, mean values were used for the water masses and the substance concentrations of the different hydrological pathways. It is recommended to undertake further studies on diffuse sources of heavy metals in urban areas and on the possibilities to improve urban storm water management. The calculation methods and the recommendations of the International Commission for the Protection of the Rhine (ICPR) are explained in detail.

2020 ◽  
Vol 17 (13) ◽  
pp. 3409-3425
Author(s):  
Xuefei Li ◽  
Outi Wahlroos ◽  
Sami Haapanala ◽  
Jukka Pumpanen ◽  
Harri Vasander ◽  
...  

Abstract. Many wetlands have been drained due to urbanization, agriculture, forestry or other purposes, which has resulted in a loss of their ecosystem services. To protect receiving waters and to achieve services such as flood control and storm water quality mitigation, new wetlands are created in urbanized areas. However, our knowledge of greenhouse gas exchange in newly created wetlands in urban areas is currently limited. In this paper we present measurements carried out at a created urban wetland in Southern Finland in the boreal climate. We conducted measurements of ecosystem CO2 flux and CH4 flux (FCH4) at the created storm water wetland Gateway in Nummela, Vihti, Southern Finland, using the eddy covariance (EC) technique. The measurements were commenced the fourth year after construction and lasted for 1 full year and two subsequent growing seasons. Besides ecosystem-scale fluxes measured by the EC tower, the diffusive CO2 and CH4 fluxes from the open-water areas (FwCO2 and FwCH4, respectively) were modelled based on measurements of CO2 and CH4 concentration in the water. Fluxes from the vegetated areas were estimated by applying a simple mixing model using the above-mentioned fluxes and the footprint-weighted fractional area. The half-hourly footprint-weighted contribution of diffusive fluxes from open water ranged from 0 % to 25.5 % in 2013. The annual net ecosystem exchange (NEE) of the studied wetland was 8.0 g C-CO2 m−2 yr−1, with the 95 % confidence interval between −18.9 and 34.9 g C-CO2 m−2 yr−1, and FCH4 was 3.9 g C-CH4 m−2 yr−1, with the 95 % confidence interval between 3.75 and 4.07 g C-CH4 m−2 yr−1. The ecosystem sequestered CO2 during summer months (June–August), while the rest of the year it was a CO2 source. CH4 displayed strong seasonal dynamics, higher in summer and lower in winter, with a sporadic emission episode in the end of May 2013. Both CH4 and CO2 fluxes, especially those obtained from vegetated areas, exhibited strong diurnal cycles during summer with synchronized peaks around noon. The annual FwCO2 was 297.5 g C-CO2 m−2 yr−1 and FwCH4 was 1.73 g C-CH4 m−2 yr−1. The peak diffusive CH4 flux was 137.6 nmol C-CH4 m−2 s−1, which was synchronized with the FCH4. Overall, during the monitored time period, the established storm water wetland had a climate-warming effect with 0.263 kg CO2-eq m−2 yr−1 of which 89 % was contributed by CH4. The radiative forcing of the open-water areas exceeded that of the vegetation areas (1.194 and 0.111 kg CO2-eq m−2 yr−1, respectively), which implies that, when considering solely the climate impact of a created wetland over a 100-year horizon, it would be more beneficial to design and establish wetlands with large patches of emergent vegetation and to limit the areas of open water to the minimum necessitated by other desired ecosystem services.


2021 ◽  
Author(s):  
Karen L. Rojas-Gómez ◽  
Jakob Benisch ◽  
Julian D. Reyes-Silva ◽  
Renato Mariano ◽  
Soohyun Yang ◽  
...  

<p>During heavy rainfall events, the large amounts of generated runoff in urban areas mobilise particulate matter from different surfaces. These particles have attached other contaminants such as heavy metals, polycyclic aromatic hydrocarbons and, faecal microorganisms. In urbanised areas, particle-bound contaminants (PBCs) may reach rivers through surface runoff, combined sewer overflows or storm water discharges. This may affect the water quality of receiving water bodies and creates health risks to humans and ecosystems. Due to the spatial variability of PBCs, associated to different land uses and pollution sources, the quantification and characterisation of contaminant pathways remain a challenge. Despite high investments, the implemented management alternatives to improve river water quality are still inefficient due to late identification of pressures and lack of a real paradigm shift towards holistic approaches. Therefore, it is necessary to better understand and describe the main factors controlling PBCs pathways in urban areas. This is expected to facilitate the selection of appropriate technologies and strategies to reduce the impact of urban discharges on receiving water bodies.</p><p>In this context, the aim of this study is to evaluate the influence of spatial and temporal variability of sediments and PBCs sources on river water quality in an urbanised catchment, considering land-use distribution within the sewersheds. This is expected to provide a better understanding of the relationship between drivers of relevant PBCs and the response of the urban water system under dynamic conditions (i.e. variable sediment load, urban runoff, storm water discharge and river flow). </p><p>Data for this study is obtained from an integrated monitoring network in a small watershed (Lockwitzbach) located in Dresden, Germany. This urban observatory consists of four water quality monitoring stations within the stream and in the sewer network. High-resolution (1min) discharge and turbidity data are collected. This allows to understand the dynamic transport mechanisms of sediments in the catchment, providing insights in complex runoff and discharge processes.</p><p>Integrated simulation of sediments and PBCs (i.e. heavy metals) is done by using EPA SWMM to evaluate surface build-up and wash-off. Additionally, the impact of sedimentation, accumulation and re-suspension of sediments and heavy metals within the sewer network and river are analysed using a simplified block developed in Simba#. Calibration and validation of the integrated model was done using online monitoring data and water samples taken during the period 2018-2020. Turbidity was used as a proxy for total suspended solids and PBCs. We identified and prioritised urban areas that are hotspots for high sediment and PBCs loads. Those represent potential locations for an optimal control and reduction of water pollution strategies. Results suggest that integrated simulation is an effective approach to analyse transport mechanisms and pathways of sediments and PBCs within urbanised catchments. Furthermore, high-resolution discharge and turbidity data are especially useful to represent the wash-off of contaminants associated to the first flush process during rainfall events.</p>


2003 ◽  
Vol 47 (7-8) ◽  
pp. 251-257 ◽  
Author(s):  
U. Scherer ◽  
S. Fuchs ◽  
H. Behrendt ◽  
T. Hillenbrand

The input of seven heavy metals (Cd, Cr, Cu, Hg, Ni, Pb and Zn) into the large river basins of Germany via various point and diffuse pathways were estimated for the period of 1985 through 2000. To quantify the emissions via point sources a nationwide survey on heavy metal data of municipal wastewater treatment plants and industrial direct discharges was carried out. The input via diffuse pathways was calculated using an adapted version of the model MONERIS. This model accounts for the significant transport processes, and it includes a Geographical Information System (GIS) that provides digital maps as well as extensive statistical information. For a comparison of the calculated heavy metal emission with the measured heavy metal load at monitoring stations the losses of heavy metals due to retention processes within the river systems have to be considered. Therefore heavy metal retention was calculated according to the retention functions given by Vink and Behrendt. For the large river basins a good correspondence could be found between estimated and measured heavy metal loads in rivers. The total emission into the North Sea decreased for each metal during the period of 1985 to 2000. The reduction varies between 87% for Hg and 41% for Ni mainly caused by the decline via point sources. Today's emissions of heavy metals into river basins of Germany are dominated by the input via diffuse pathways. The most important diffuse emission pathways are “paved urban areas” and “erosion”.


2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Spyros Foteinis ◽  
Nikolaos G. Kallithrakas-Kontos ◽  
Costas Synolakis

The existence and distribution of persistent pollutants, such as heavy metals, in coastal sediment used for opportunistic beach nourishment, is a problem that has not received much attention. Here, we assessed the coastal sediments in one restoration project for the occurrence and distribution of heavy metals, by utilizing an Energy Dispersive X-Ray Fluorescence (EDXRF) system. Heavy metal point sources included (i) the effluents of small industries (tanneries), (ii) wastewater treatment plant effluents, and (iii) paint and oil scraps from substandard ship maintenance activities that take place on ports breakwaters. A few neighboring beaches were found to have similar heavy metal concentrations, with mean values of Cu, Zn, and Pb ranging from 80 to 130, 15 to 25, and 25 to 40 mg/kg, respectively. Existing legislation regarding dredging activities in Greece appears insufficient for sustainable and environmentally friendly nourishment. We conclude that before opportunistic beach restoration projects materialize with material borrowed from ports and harbors the quality of the dredged material needs to be assessed.


1993 ◽  
Vol 28 (3-5) ◽  
pp. 165-175 ◽  
Author(s):  
H. Behrendt

The results of a new method for estimating point and diffuse loads of rivers from analysis of monitoring data are presented (immission approach). The estimated point source loads of dissolved nitrogen, total phosphorus, and the heavy metals, cadmium, lead and zinc were compared with the loads of existing inventories. The diffuse loads of these pollutants were compared with estimations calculated on the basis of area related loads of the main diffuse sources (emission approach). Reasonable agreement was obtained in these comparisons, thus demonstrating the utility of the new method as a tool for analyzing point sources and diffuse loads of pollutants to a river system from analysis of monitoring data.


2021 ◽  
Author(s):  
Nataliia Osadcha ◽  
Yurii Nabyvanets ◽  
Volodimir Osadchyi ◽  
Olha Ukhan ◽  
Valeriy Osypov ◽  
...  

<p>The third largest European river Dnipro covers 48% of Ukraine’s territory. An analysis of the main anthropogenic pressures in the Dnipro Basin was first performed according to the requirements of EU WFD.</p><p>Surface water pollution by organic substances and nutrients is principally attributed with point sources, among which the municipal wastewaters play the dominant role. The main load by organic substances and nutrients is caused by the wastewater discharges of big cities with Population Equivalent >100 000; 89% of such cities are located within the sub-basins of Middle Dnipro and Lower Dnipro. </p><p>Point sources form 33% of nitrogen and 61% of phosphorus loads in the Dnipro Basin. Diffuse sources related to agricultural production cause incoming of 29% of nitrogen and 36% of phosphorus. Phosphorus is transported to the water bodies mainly with erosion particles. </p><p>Natural conditions in the River Basin are one of the reasons of nitrogen load significant share (33%). Humus compounds and nitrogen compounds enter into water bodies due to the high bogginess of the Dnipro Basin upper part, especially the Prypiaty Basin. This leads to winter and summer anoxia in the rivers and upper reservoirs and creates prerequisites for eutrophication of the Dnipro cascade reservoirs. Rivers of the Prypiaty sub-basin, Upper Dnipro, and Desna sub-basins are extremely vulnerable to anthropogenic pollution by nutrients and organic substances that generates the increased background of organic compounds and nitrogen in the Dnipro reservoirs cascade. </p><p>The load of the Dnipro Basin surface water by hazardous substances (especially synthetic) still remains insufficiently studied. Currently, information is only available regarding load by heavy metals included to the list of priority substances and some other ones. Water pollution by metals is noted mostly in the Lower Dnipro sub-basin where the most of the metallurgical enterprises are located. </p><p>The high application of pesticides (> 3 kg/ha) in 4 administrative Rayons leads to the appearance of risk conditions for pollution of xenobiotics in 50 surface water bodies (SWBs). </p><p>The Dnipro reservoirs cascade serves as a powerful geochemical barrier causing heavy metals and pesticides deposition in bottom sediments. The highest pollution by metals is noted in the sediments of the Dnipro reservoirs that receive the metallurgy enterprises wastewaters. Probability of significant secondary remobilization is foremost noted for Cadmium. Organochloride pesticides content in the bottom sediments is 2 to 5 times lower than maximal allowable concentration in soil. </p><p>Water abstraction volume is around 22% of the annual flow of 95% probability. The natural flow of the Dnipro is regulated by 6 large reservoirs. Besides, there are 1072 dams and other cross-sectional artificial installations. Natural morphology changes are observed in a large number of rivers within the Dnipro Basin. </p><p>It was found that 56% of the Dnipro Basin SWBs are at risk of failing the “good” ecological status.</p><p>Hydromorphological alterations cause the main anthropogenic pressure in the Dnipro Basin (concerning 45% of the SWBs). Risks from diffuse sources and point sources are observed in 23% and 5% of SWBs, respectively.</p>


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