Heavy metal removal in waste stabilisation ponds and high rate ponds

2000 ◽  
Vol 42 (10-11) ◽  
pp. 17-21 ◽  
Author(s):  
A. Toumi ◽  
A. Nejmeddine ◽  
B. El Hamouri

Heavy metals, zinc (Zn), copper (Cu) and lead (Pb) removal in two wastewater treatment units were compared. One of the systems consisted of a train of Waste Stabilisation Ponds (WSP) including one anaerobic, three facultative in series and two maturation ponds, also in series. The other system, called High Rate Ponds (HRP) consisted of one anaerobic, one High Rate Algal Pond (HRAP) and two maturation ponds in series. The two treatment systems were located on the same site and received the same wastewater. Data collected from the two treatment systems, for a period of three consecutive months (May, June and July, 1995) show that the content of the three elements in the crude wastewater of the city of Ouarzazate varied from 210 to 340 mg/l for Zn; 35 to 55 for Cu and 30 to 25 for Pb. The removal rate for the three elements reached 91, 92 and 71% respectively for Zn, Cu and Pb in the WSP train. The corresponding values in the HRP train were, respectively 89, 88 and 51%. However, since the two trainswere not receiving the same flow, the use of specific removal rate expressed as mg removed m-2 d-1 showed that the HRAP was 1.3, 10 and 2 times more efficient respectively for Zn, Cu and Pb removal than the three facultative ponds in series of the WSP. Also, the collected data showed that the content of the sediment of the anaerobic pond was high for all the three elements. However, the recorded concentrations 613, 99 and 78 mg/kg, respectively for Zn, Cu and Pb did not exceed the EEC recommended limits.

2020 ◽  
Vol 158 ◽  
pp. 04005
Author(s):  
Sunyu Jung ◽  
Soon-Ho Park

Fe2O3 is an especially promising material for water purification as it shows high heavy metal adsorption capacity. However, the high cost of commercial Fe2O3 makes it difficult to be widely used in developing countries. Herein, we probe the heavy metal removal performance of iron oxide rust. Rust was grown on iron nails in a controlled manner using peracetic acid (CH3CO3H), a safe and environment-friendly oxidizer. Arsenic was selected as an example of a heavy metal contaminant in this study. XRD and EDS analysis revealed that the iron oxide prepared with peracetic acid was nearly amorphous Fe2O3. Amorphous iron oxide is reported to show higher reactivity than crystalline iron oxide. The BET specific surface area of prepared Fe2O3 is 71 m2/g, which is larger than that of commercial Fe2O3, and the average pore diameter is 73 Å. Oxidized nails are highly effective for removing heavy metals: about 90% of 1ppm arsenic in water was removed at the residence time of 20 minutes, and the removal rate of 90% is maintained after 10 back-to-back arsenic removal experiments at the same residence time. Iron oxide prepared in this study can remove, per 1 cm2, up to 0.114 mg of arsenic.


2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Jingyong Liu ◽  
Jiacong Chen ◽  
Limao Huang

Abstract The thermal behavior of heavy metals in the co-incineration of municipal solid waste-sludge incinerator fly ash (MSS fly ash) was studied using a laboratory-scale tube furnace. The results indicate that without the addition of chlorinating agents, temperature was an important parameter and had significantly influenced on heavy metal removal, whereas the residence time had a weak effect. Between 900 and 1000 °C for 60 to 300 min, heavy metals reacted with chloride-inherent in the fly ash and approximately 80 to 89% of Pb, 48% to 56% of Cd, 27% to 36% of Zn and 6% to 24% of Cu were removed. After the adding chlorinating agents, the evaporation rate of the heavy metals improved dramatically, where the evaporation rates of Cu and Zn were larger than that of Pb and Cd. As the amount of added chlorinating agents increased, the removal rate of heavy metals increased. However, the effect of the type of chlorinating agent on the chlorination of heavy metals differed considerably, where NaCl had the weakest effect on the removal rate of Cu, Cd and Zn. In terms of resource recovery and decontamination, MgCl2 and CaCl2 are the best choices due to their efficient removal of Zn.


2021 ◽  
Vol 897 ◽  
pp. 109-115
Author(s):  
Sri Martini ◽  
Kiagus Ahmad Roni ◽  
Dian Kharismadewi ◽  
Erna Yuliwaty

This review article presents the usage of various animal bones such as chicken bone, fish bone, pig bone, camel bone, and cow bone as reliable biosorbent materials to remove heavy metals contained in contaminated water and wastewater. The sources and toxicity effects of heavy metal ions are also discussed properly. Then specific insights related to adsorption process and its influential factors along with the proven potentiality of selected biosorbents especially derived from animal bone are also explained. As the biosorbents are rich in particular organic and inorganic compounds and functional groups in nature, they play an important role in heavy metal removal from contaminated solutions. Overall, after conducting study reports on the literature, a brief conclusion can be drawn that animal bone waste has satisfactory efficacy as effective, efficient, and environmentally friendly sorbent material.


2001 ◽  
Vol 44 (10) ◽  
pp. 53-58 ◽  
Author(s):  
L. C. Aralp ◽  
A. Erdincler ◽  
T. T. Onay

Heavy metal concentration in sludge is one of the major obstacles for the application of sludge on land. There are various methods for the removal of heavy metals in sludge. Using sulfur oxidizing bacteria for microbiological removal of heavy metals from sludges is an outstanding option because of high metal solubilization rates and the low cost. In this study, bioleaching by indigenous sulfur oxidizing bacteria was applied to sludges generated from the co-treatment of municipal wastewater and leachate for the removal of selected heavy metals. Sulfur oxidizing bacteria were acclimated to activated sludge. The effect of the high organic content of leachate on the bioleaching process was investigated in four sets of sludges having different concentrations of leachate. Sludges in Sets A, B, C and D were obtained from co-treatment of wastewater and 3%, 5%, 7% and 10% (v/v) leachate respectively. The highest Cr, Ni and Fe solubilization was obtained from Set A. Sulfur oxidizing bacteria were totally inhibited in Set D that received the highest volume of leachate.


2018 ◽  
Vol 6 (28) ◽  
pp. 13624-13632 ◽  
Author(s):  
He Ding ◽  
Yang Chen ◽  
Tianyi Fu ◽  
Peng Bai ◽  
Xianghai Guo

Nanosheet-based magadiites are promising adsorbents with controlled interlayer space and a well-defined 2D structure, which make them new candidates for heavy metal removal.


2020 ◽  
Vol 8 (4) ◽  
pp. 505 ◽  
Author(s):  
Muhammad Faheem ◽  
Sadaf Shabbir ◽  
Jun Zhao ◽  
Philip G Kerr ◽  
Nasrin Sultana ◽  
...  

Cadmium (Cd), chromium (Cr) and lead (Pb) are heavy metals that have been classified as priority pollutants in aqueous environment while methane-oxidizing bacteria as a biofilter arguably consume up to 90% of the produced methane in the same aqueous environment before it escapes into the atmosphere. However, the underlying kinetics and active methane oxidizers are poorly understood for the hotspot of epipelon that provides a unique micro-ecosystem containing diversified guild of microorganisms including methane oxidizers for potential bioremediation of heavy metals. In the present study, the Pb2+, Cd2+and Cr6+ bioremediation potential of epipelon biofilm was assessed under both high (120,000 ppm) and near-atmospheric (6 ppm) methane concentrations. Epipelon biofilm demonstrated a high methane oxidation activity following microcosm incubation amended with a high concentration of methane, accompanied by the complete removal of 50 mg L−1 Pb2+ and 50 mg L−1 Cd2+ (14 days) and partial (20%) removal of 50 mg L−1 Cr6+ after 20 days. High methane dose stimulated a faster (144 h earlier) heavy metal removal rate compared to near-atmospheric methane concentrations. DNA-based stable isotope probing (DNA-SIP) following 13CH4 microcosm incubation revealed the growth and activity of different phylotypes of methanotrophs during the methane oxidation and heavy metal removal process. High throughput sequencing of 13C-labelled particulate methane monooxygenase gene pmoA and 16S rRNA genes revealed that the prevalent active methane oxidizers were type I affiliated methanotrophs, i.e., Methylobacter. Type II methanotrophs including Methylosinus and Methylocystis were also labeled only under high methane concentrations. These results suggest that epipelon biofilm can serve as an important micro-environment to alleviate both methane emission and the heavy metal contamination in aqueous ecosystems with constant high methane fluxes.


2020 ◽  
Vol 81 (9) ◽  
pp. 1797-1827 ◽  
Author(s):  
Ya-Nan Xu ◽  
Yinguang Chen

Abstract Industrial development has led to generation of large volumes of wastewater containing heavy metals, which need to be removed before the wastewater is released into the environment. Chemical and electrochemical methods are traditionally applied to treat this type of wastewater. These conventional methods have several shortcomings, such as secondary pollution and cost. Bioprocesses are gradually gaining popularity because of their high selectivities, low costs, and reduced environmental pollution. Removal of heavy metals by sulfate-reducing bacteria (SRB) is an economical and effective alternative to conventional methods. The limitations of and advances in SRB activity have not been comprehensively reviewed. In this paper, recent advances from laboratory studies in heavy metal removal by SRB were reported. Firstly, the mechanism of heavy metal removal by SRB is introduced. Then, the factors affecting microbial activity and metal removal efficiency are elucidated and discussed in detail. In addition, recent advances in selection of an electron donor, enhancement of SRB activity, and improvement of SRB tolerance to heavy metals are reviewed. Furthermore, key points for future studies of the SRB process are proposed.


2016 ◽  
Vol 7 (4) ◽  
pp. 387-419 ◽  
Author(s):  
Renu ◽  
Madhu Agarwal ◽  
K. Singh

Heavy metals are discharged into water from various industries. They can be toxic or carcinogenic in nature and can cause severe problems for humans and aquatic ecosystems. Thus, the removal of heavy metals from wastewater is a serious problem. The adsorption process is widely used for the removal of heavy metals from wastewater because of its low cost, availability and eco-friendly nature. Both commercial adsorbents and bioadsorbents are used for the removal of heavy metals from wastewater, with high removal capacity. This review article aims to compile scattered information on the different adsorbents that are used for heavy metal removal and to provide information on the commercially available and natural bioadsorbents used for removal of chromium, cadmium and copper, in particular.


2019 ◽  
Vol 7 (12) ◽  
pp. 697 ◽  
Author(s):  
Chaolin Fang ◽  
Varenyam Achal

The global energy crisis and heavy metal pollution are the common problems of the world. It is noted that the microbial fuel cell (MFC) has been developed as a promising technique for sustainable energy production and simultaneously coupled with the remediation of heavy metals from water and soil. This paper reviewed the performances of MFCs for heavy metal removal from soil and water. Electrochemical and microbial biocatalytic reactions synergistically resulted in power generation and the high removal efficiencies of several heavy metals in wastewater, such as copper, hexavalent chromium, mercury, silver, thallium. The coupling system of MFCs and microbial electrolysis cells (MECs) successfully reduced cadmium and lead without external energy input. Moreover, the effects of pH and electrode materials on the MFCs in water were discussed. In addition, the remediation of heavy metal-contaminated soil by MFCs were summarized, noting that plant-MFC performed very well in the heavy metal removal.


2020 ◽  
Vol 1010 ◽  
pp. 489-494
Author(s):  
Abdul Hafidz Yusoff ◽  
Rosmawani Mohammad ◽  
Mardawani Mohamad ◽  
Ahmad Ziad Sulaiman ◽  
Nurul Akmar Che Zaudin ◽  
...  

Conventional methods to remove heavy metals from polluted water are expensive and not environmentally friendly. Therefore, this study was carried out to investigate the potential of agricultural waste such as pineapple peel (Ananas Cosmos) as low-cost absorbent to remove heavy metals from synthetic polluted water. The results showed that Cd, Cr and Pb were effectively removed by the biosorbent at 12g of pineapple peels in 100 mL solution. The optimum contact time for maximum adsorption was found to be 90 minutes, while the optimum pH for the heavy metal’s adsorption was 9. It was demonstrated that with the increase of adsorbent dosage, the percent of heavy metals removal was also increased due to the increasing adsorption capacity of the adsorbent. In addition, Langmuir model show maximum adsorption capacity of Cd is 1.91 mg/g. As conclusions, our findings show that pineapple peel has potential to remove heavy metal from polluted water.


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