Emissions of chlorinated aromatics during sludge combustion
The emissions of the toxic chlorinated dioxins and furans during the combustion of sewage sludge and their distribution to the gas/solid phase were examined in this work. Sewage sludge samples were collected from two municipal and one industrial wastewater treatment plant, and were incinerated in a lab scale reactor at 1000°C. High PCDD/F emissions, about 300 ng I-TEQ/kg of fuel were observed during the combustion of the industrial sewage sludge due to the high chlorine and copper content in this sample. Co-combustion of the industrial sludge with coal resulted in reduced toxic emissions reaching up to 158 ng/kg fuel. Almost similar PCDD/F concentrations were measured in the solid particles removed at the quartz wool filter and in the gas phase. The examination of the homologue patterns revealed the domination of furans over dioxins in both the gas and the solid phase. The tetrachlorinated congeners prevailed over the other isomers in the gas phase, while in the solid phase the lower chlorinated isomers with four and five chlorine atoms dominated.