scholarly journals Investigation on the fate of quinolone antibiotics in three drinking water treatment plants of China

Author(s):  
Zhiquan Liu ◽  
Yongpeng Xu ◽  
Yuan Wang ◽  
Fuyi Cui

Abstract Quinolone (QN) antibiotics are widely used all over the world and have been frequently detected in source water, but the occurrence in tap water and the treatment efficiencies of QNs by drinking-water treatment plants (DWTPs) were rarely reported. In the present study, the occurrence and distribution of six representative QNs in three urban DWTPs of China were investigated. The results showed that the concentrations of total QNs in the three source waters ranged from 26.4 ng/L to 313.8 ng/L and all of the six QNs were detectable with a detection frequency of 100% (4.6 to 121.7 ng/L). Enrofloxacin (ENR) and ofloxacin (OFL) were the dominant species of QNs and accounted for 40.1% to 79.5% of the total QNs. After the treatments, there were still considerable QNs in the finished water (total amounts of 74.9 ng/L to 148.4 ng/L). The adsorbed QNs could be readily treated with the removal of turbidity by DWTPs, but only a part of the dissolved QNs (13.6% to 68.5%) can be removed. This implies that the dissolved QNs were more hazardous in the source water. Pre-oxidation and disinfection could remove 15.8 ± 8.3% and 16.9 ± 10.8% of dissolved QNs, respectively, depending on the chemical structure of QNs and the types of oxidant. Chemical oxidation was more efficient than coagulation-sedimentation and filtration for the treatment of dissolved QNs. Ozone-granular activated carbon filtration may fail to remove dissolved QNs in the actual DWTPs, because of the insufficient dosage of oxidant and the competition effect of natural organic matter.

2021 ◽  
pp. 117296
Author(s):  
Émile Sylvestre ◽  
Michèle Prévost ◽  
Jean-Baptiste Burnet ◽  
Patrick Smeets ◽  
Gertjan Medema ◽  
...  

2005 ◽  
Vol 71 (2) ◽  
pp. 1042-1050 ◽  
Author(s):  
Gerald Sedmak ◽  
David Bina ◽  
Jeffrey MacDonald ◽  
Lon Couillard

ABSTRACT Reoviruses, enteroviruses, and adenoviruses were quantified by culture for various ambient waters in the Milwaukee area. From August 1994 through July 2003, the influent and effluent of a local wastewater treatment plant (WWTP) were tested monthly by a modified U.S. Environmental Protection Agency Information Collection Rule (ICR) organic flocculation cell culture procedure for the detection of culturable viruses. Modification of the ICR procedure included using Caco-2, RD, and HEp-2 cells in addition to BGM cells. Lake Michigan source water for two local drinking water treatment plants (DWTPs) was also tested monthly for culturable viruses by passing 200 liters of source water through a filter and culturing a concentrate representing 100 liters of source water. Reoviruses, enteroviruses, and adenoviruses were detected frequently (105 of 107 samples) and, at times, in high concentration in WWTP influent but were detected less frequently (32 of 107 samples) in plant effluent and at much lower concentrations. Eighteen of 204 samples (8.8%) of source waters for the two DWTPs were positive for virus and exclusively positive for reoviruses at relatively low titers. Both enteroviruses and reoviruses were detected in WWTP influent, most frequently during the second half of the year.


2018 ◽  
Vol 19 (5) ◽  
pp. 1305-1312
Author(s):  
Chen Wang ◽  
Qi Zheng ◽  
Xiaoqiu Yang

Abstract Acesulfame (ACE) and sucralose (SUC) are ideal sewage markers for drinking water. In this paper, 33 samples were collected from eight cities' drinking water treatment plants (DWTPs) along the Yangtze River to analyse the occurrence and removal of ACE and SUC. These two compounds were determined using ultra-high performance liquid chromatography–high resolution mass spectrometry. The limits of detection for ACE and SUC were 1.75 ng/L and 0.03 ng/L, respectively. The results showed that ACE and SUC existed widely in DWTPs along the Yangtze River. The concentration of ACE was 13–320 ng/L and the concentration of SUC was 200–1,592 ng/L. In general, the concentrations of ACE and SUC increased from upstream to downstream but decreased after water treatment procedures at every DWTP. In most DWTPs, a 9–30% removal of ACE and SUC was achieved using traditional chlorination disinfection technology. Ozonation combined with granular activated carbon filtration techniques had a high removal efficiency (63.8% for ACE and 50.2% for SUC).


2017 ◽  
Vol 24 (17) ◽  
pp. 14889-14902 ◽  
Author(s):  
Xia-Lin Hu ◽  
Yi-Fan Bao ◽  
Jun-Jian Hu ◽  
You-Yu Liu ◽  
Da-Qiang Yin

Abstract Pharmaceuticals in drinking water sources have raised significant concerns due to their persistent input and potential human health risks. The seasonal occurrence of 25 pharmaceuticals including 23 antibiotics, paracetamol (PAR), and carbamazepine (CMZ) in Taihu Lake was investigated; meanwhile, the distribution and removal of these pharmaceuticals in two drinking water treatment plants (DWTPs) and a constructed wetland were evaluated. A high detection frequency (>70%) in the Taihu Lake was observed for nearly all the 25 pharmaceutics. Chlortetracycline (234.7 ng L−1), chloramphenicol (27.1 ng L−1), erythromycin (72.6 ng L−1), PAR (71.7 ng L−1), and CMZP (23.6 ng L−1) are compounds with both a high detection frequency (100%) and the highest concentrations, suggesting their wide use in the Taihu Basin. Higher concentrations of chloramphenicols, macrolides, PAR, and CMZP were observed in dry season than in wet season, probably due to the low flow conditions of the lake in winter and the properties of pharmaceuticals. The overall contamination levels of antibiotic pharmaceutics (0.2–74.9 ng L−1) in the Taihu Lake were lower than or comparable to those reported worldwide. However, for nonantibiotic pharmaceutics, PAR (45.0 ng L−1) and CMZP (14.5 ng L−1), significantly higher concentrations were observed in the Taihu Lake than at a global scale. High detection frequencies of 25 pharmaceuticals were observed in both the two DWTPs (100%) and the wetland (>60%) except for florfenicol and sulfapyridine. The removal efficacies of the studied pharmaceuticals in DWTP B with advanced treatment processes including ozonation and granular activated carbon filtration (16.7–100%) were superior to DWTP A with conventional treatment processes (2.9–100%), except for sulfonamides. Wetland C with the constructed root channel technology was efficient (24.2–100%) for removing most pharmaceuticals. This work suggests that the application of cost-effective technologies such as constructed wetlands should be considered as an efficient alternative for removing pharmaceuticals from water supply sources.


2009 ◽  
Vol 75 (17) ◽  
pp. 5714-5718 ◽  
Author(s):  
Chuanwu Xi ◽  
Yongli Zhang ◽  
Carl F. Marrs ◽  
Wen Ye ◽  
Carl Simon ◽  
...  

ABSTRACT The occurrence and spread of antibiotic-resistant bacteria (ARB) are pressing public health problems worldwide, and aquatic ecosystems are a recognized reservoir for ARB. We used culture-dependent methods and quantitative molecular techniques to detect and quantify ARB and antibiotic resistance genes (ARGs) in source waters, drinking water treatment plants, and tap water from several cities in Michigan and Ohio. We found ARGs and heterotrophic ARB in all finished water and tap water tested, although the amounts were small. The quantities of most ARGs were greater in tap water than in finished water and source water. In general, the levels of bacteria were higher in source water than in tap water, and the levels of ARB were higher in tap water than in finished water, indicating that there was regrowth of bacteria in drinking water distribution systems. Elevated resistance to some antibiotics was observed during water treatment and in tap water. Water treatment might increase the antibiotic resistance of surviving bacteria, and water distribution systems may serve as an important reservoir for the spread of antibiotic resistance to opportunistic pathogens.


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