Effect of chloramine residual on iron release in drinking water distribution systems

2009 ◽  
Vol 9 (4) ◽  
pp. 349-355 ◽  
Author(s):  
Y. Wang ◽  
X. J. Zhang ◽  
Z. B. Niu ◽  
C. Chen ◽  
P. P. Lu ◽  
...  

Iron release from scale brought about serious problems such as noticeable increases in turbidity and colour of the water in distribution system and taps. Field study and bench scale experiment on iron release from corrosion scale were carried out. In old cast iron pipe, higher iron release occurred with lower chlorine residual concentration, while lower iron release occurred with higher chlorine residual concentration. The reason lay in the structure of scale and the electro-chemical reactions occurring on the scale and in the bulk. The passivated-out-layer of scale was formed by ferric oxide. It could be broken down by reductive reaction in an atmosphere of low chlorine residual concentration. In contrast, the situation was quite different with new cast iron pipe, the age of which was only half a year. Iron release was considered as the product of the iron matrix and chlorine since the passivated-out-layer of scale had not formed yet. This iron release was consistent with chlorine residual concentration. It is suggested that maintaining a high chlorine residual concentration in a drinking water distribution system is beneficial to controlling both microorganism' regrowth and iron release.

2021 ◽  
Vol 12 ◽  
Author(s):  
Debbie Lee ◽  
Gennaro Calendo ◽  
Kristin Kopec ◽  
Rebekah Henry ◽  
Scott Coutts ◽  
...  

As many cities around the world face the prospect of replacing aging drinking water distribution systems (DWDS), water utilities must make careful decisions on new pipe material (e.g., cement-lined or PVC) for these systems. These decisions are informed by cost, physical integrity, and impact on microbiological and physicochemical water quality. Indeed, pipe material can impact the development of biofilm in DWDS that can harbor pathogens and impact drinking water quality. Annular reactors (ARs) with cast iron and cement coupons fed with chloraminated water from a municipal DWDS were used to investigate the impact of pipe material on biofilm development and composition over 16 months. The ARs were plumbed as closely as possible to the water main in the basement of an academic building to simulate distribution system conditions. Biofilm communities on coupons were characterized using 16S rRNA sequencing. In the cast iron reactors, β-proteobacteria, Actinobacteria, and α-proteobacteria were similarly relatively abundant (24.1, 22.5, and 22.4%, respectively) while in the cement reactors, α-proteobacteria and Actinobacteria were more relatively abundant (36.3 and 35.2%, respectively) compared to β-proteobacteria (12.8%). Mean alpha diversity (estimated with Shannon H and Faith’s Phylogenetic Difference indices) was greater in cast iron reactors (Shannon: 5.00 ± 0.41; Faith’s PD: 15.40 ± 2.88) than in cement reactors (Shannon: 4.16 ± 0.78; Faith’s PD: 13.00 ± 2.01). PCoA of Bray-Curtis dissimilarities indicated that communities in cast iron ARs, cement ARs, bulk distribution system water, and distribution system pipe biofilm were distinct. The mean relative abundance of Mycobacterium spp. was greater in the cement reactors (34.8 ± 18.6%) than in the cast iron reactors (21.7 ± 11.9%). In contrast, the mean relative abundance of Legionella spp. trended higher in biofilm from cast iron reactors (0.5 ± 0.7%) than biofilm in cement reactors (0.01 ± 0.01%). These results suggest that pipe material is associated with differences in the diversity, bacterial composition, and opportunistic pathogen prevalence in biofilm of DWDS.


2017 ◽  
Vol 3 (1) ◽  
pp. 147-155 ◽  
Author(s):  
Haibo Wang ◽  
Chun Hu ◽  
Lang Yin ◽  
Sujia Zhang ◽  
Lizhong Liu

There is a relationship between biochemical function and chemical composition of corrosion scales, and Fe3O4formation reduced iron release.


2006 ◽  
Vol 6 (2) ◽  
pp. 147-151 ◽  
Author(s):  
X.-J. Zhang ◽  
W. Lu

Biofilm growth in drinking water distribution systems was studied in an annular reactor system which was designed to model the hydraulic conditions in water mains. Experiments were performed with chlorine-free water as well as with different disinfectant (chlorine or chloramine) residuals and different AOC concentrations added to the reactor influent to examine the effect of disinfectant residuals and AOC concentrations on biofilm accumulation and planktonic cell numbers. The dynamic parameters of bacteria growth were calculated in water with different disinfectant (chlorine or chloramine) and the results indicated that monochloramine may be more effective than free chlorine for control of biofilm accumulation.


2003 ◽  
Vol 3 (1-2) ◽  
pp. 239-246 ◽  
Author(s):  
G. Kastl ◽  
I. Fisher ◽  
V. Jegatheesan ◽  
J. Chandy ◽  
K. Clarkson

Nearly all drinking water distribution systems experience a “natural” reduction of disinfection residuals. The most frequently used disinfectant is chlorine, which can decay due to reactions with organic and inorganic compounds in the water and by liquid/solids reaction with the biofilm, pipe walls and sediments. Usually levels of 0.2-0.5 mg/L of free chlorine are required at the point of consumption to maintain bacteriological safety. Higher concentrations are not desirable as they present the problems of taste and odour and increase formation of disinfection by-products. It is usually a considerable concern for the operators of drinking water distribution systems to manage chlorine residuals at the “optimum level”, considering all these issues. This paper describes how the chlorine profile in a drinking water distribution system can be modelled and optimised on the basis of readily and inexpensively available laboratory data. Methods are presented for deriving the laboratory data, fitting a chlorine decay model of bulk water to the data and applying the model, in conjunction with a simplified hydraulic model, to obtain the chlorine profile in a distribution system at steady flow conditions. Two case studies are used to demonstrate the utility of the technique. Melbourne’s Greenvale-Sydenham distribution system is unfiltered and uses chlorination as its only treatment. The chlorine model developed from laboratory data was applied to the whole system and the chlorine profile was shown to be accurately simulated. Biofilm was not found to critically affect chlorine decay. In the other case study, Sydney Water’s Nepean system was modelled from limited hydraulic data. Chlorine decay and trihalomethane (THM) formation in raw and treated water were measured in a laboratory, and a chlorine decay and THM model was derived on the basis of these data. Simulated chlorine and THM profiles agree well with the measured values available. Various applications of this modelling approach are also briefly discussed.


2019 ◽  
Vol 5 (10) ◽  
pp. 1689-1698
Author(s):  
Xu Ma ◽  
Guiwei Li ◽  
Ying Yu ◽  
Ruya Chen ◽  
Yao Zhang ◽  
...  

Discoloration problems have occurred in drinking water distribution systems continuously for several years in a rural area of eastern China.


2007 ◽  
Vol 73 (11) ◽  
pp. 3755-3758 ◽  
Author(s):  
Talis Juhna ◽  
Dagne Birzniece ◽  
Janis Rubulis

ABSTRACT The effect of phosphorus addition on survival of Escherichia coli in an experimental drinking water distribution system was investigated. Higher phosphorus concentrations prolonged the survival of culturable E. coli in water and biofilms. Although phosphorus addition did not affect viable but not culturable (VBNC) E. coli in biofilms, these structures could act as a reservoir of VBNC forms of E. coli in drinking water distribution systems.


2014 ◽  
Vol 955-959 ◽  
pp. 3381-3384
Author(s):  
Hao Qiang Tan ◽  
Wen Jie He ◽  
Hong Da Han

Analyzing the seasonal variation of water quality, the indices which include total iron, pH, temperature, DO, alkalinity and hardness were of high statistical significance, and total iron had a high correlation with temperature, which influences many parameters influencing iron release, such as DO, solution viscosity, thermodynamic properties and microbial activity. Therefore, it can be concluded that temperature is a main factor that affects iron release in seasonal change for drinking water distribution systems. Variation in season and temperature should be paid attention to in practice of water supply.


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