Pilot plant study on the performance and optimization of submerged membranes for taste and odor removal

2002 ◽  
Vol 2 (2) ◽  
pp. 185-192 ◽  
Author(s):  
L. Schideman ◽  
V.L. Snoeyink ◽  
B.J. Mariñas ◽  
M. Kosterman

Hybrid sorption-membrane processes are an attractive alternative for meeting a range of water treatment goals in a single process that is compact and cost-effective. This study investigated the performance and optimization of a hybrid sorption-membrane process using powdered activated carbon (PAC) and submerged-style membranes for odor control. Specifically, this study focused on the removal of 2-methylisoborneol (2-MIB) from a Lake Michigan source water and investigated the effects of PAC dose, dosing method, backwash interval, and aeration. Adsorption performance was predicted using a mathematical model, and tested using a pilot-scale, submerged membrane system. Modeling continuously dosed PAC performance agreed well with pilot results, but pulse dosed PAC performance was overestimated by the model. Non-ideal mixing effects were identified as important factors in explaining the pulse dosing results. Pilot results with aeration and pulse dosing were also overestimated by the model. It is hypothesized that aeration disturbs the PAC cake layer that forms on the membrane, and thus eliminates the beneficial effects that this cake layer can have on adsorption. Extending backwash intervals from 30 to 180 minutes with continuous dosing increased the percent removal of 2-MIB by up to 30% in both the model predictions and pilot results. This study highlights some important considerations in the design of full-scale systems and future mathematical models.

1992 ◽  
Vol 26 (7-8) ◽  
pp. 1831-1840 ◽  
Author(s):  
L. A. Roesner ◽  
E. H. Burgess

Increased concern regarding water quality impacts from combined sewer overflows (CSOs) in the U.S. and elsewhere has emphasized the role of computermodeling in analyzing CSO impacts and in planning abatement measures. These measures often involve the construction of very large and costly facilities, and computer simulation during plan development is essential to cost-effective facility sizing. An effective approach to CSO system modeling focuses on detailed hydraulic simulation of the interceptor sewers in conjunction with continuous simulation of the combined sewer system to characterize CSOs and explore storage-treatment tradeoffs in planning abatement facilities. Recent advances in microcomputer hardware and software have made possible a number of new techniques which facilitate the use of computer models in CSO abatement planning.


2018 ◽  
Vol 115 (2) ◽  
pp. 204
Author(s):  
Deng Ma ◽  
Wei Wu ◽  
Shifan Dai ◽  
Zhibin Liu

In this study, the feasibility of the carburization of vanadium-bearing hot metal was first investigated by thermodynamic analysis. Next, three carburizers, namely a low-nitrogen carburizer, anthracite, and coke, were used for carburization of 500 g of vanadium-bearing hot metal at 1450 °C, 1500 °C, and 1550 °C, respectively. The carbon increments for the low-nitrogen carburizer, anthracite and coke followed decreasing order in the temperature range from 1450 °C to 1550 °C. Anthracite was the most cost-effective carburizer. Hence, anthracite is used in pilot-scale experiments of the vanadium-bearing hot metal (100 kg and 200 kg). Finally, vanadium extraction experiments of the vanadium-bearing hot metal were carried out in a top-bottom-combined blowing induction furnace. It is proved that the average superheat degree of semi-steel increases from 100 °C to 198 °C by the carburization of vanadium-containing hot metal.


Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 290
Author(s):  
Chih-Yu Cheng ◽  
Chia-Huang Tsai ◽  
Pei-Jyun Liou ◽  
Chi-Hang Wang

For pilot-scale production of chito-oligosaccharides, it must be cost-effective to prepare designable recombinant chitosanase. Herein, an efficient method for preparing recombinant Bacillus chitosanase from Escherichia coli by elimination of undesirable substances as a precipitate is proposed. After an optimized culture with IPTG (Isopropyl β-d-1-thiogalactopyranoside) induction, the harvested cells were resuspended, disrupted by sonication, divided by selective precipitation, and stored using the same solution conditions. Several factors involved in these procedures, including ion types, ionic concentration, pH, and bacterial cell density, were examined. The optimal conditions were inferred to be pH = 4.5, 300 mM sodium dihydrogen phosphate, and cell density below 1011 cells/mL. Finally, recombinant chitosanase was purified to >70% homogeneity with an activity recovery and enzyme yield of 90% and 106 mg/L, respectively. When 10 L of 5% chitosan was hydrolyzed with 2500 units of chitosanase at ambient temperature for 72 h, hydrolyzed products having molar masses of 833 ± 222 g/mol with multiple degrees of polymerization (chito-dimer to tetramer) were obtained. This work provided an economical and eco-friendly preparation of recombinant chitosanase to scale up the hydrolysis of chitosan towards tailored oligosaccharides in the near future.


2018 ◽  
Vol 19 (3) ◽  
pp. 855-863 ◽  
Author(s):  
T. Miyoshi ◽  
Y. Takahashi ◽  
T. Suzuki ◽  
R. Nitisoravut ◽  
C. Polprasert

Abstract This study investigated the performance of a hybrid membrane filtration system to produce industrial water from highly-colored surface water. The system consists of a membrane filtration process with appropriate pretreatments, including coagulation, pre-chlorination, and anion exchange (IE) process. The results of the pilot-scale experiments revealed that the hybrid system can produce treated water with color of around 5 Pt-Co, dissolved manganese concentration of no more than 0.05 mg/L, and a silt density index (SDI) of no more than 5 when sufficient coagulant and sodium hypochlorite were dosed. Although the IE process effectively reduced the color of the water, a moderate increase in the color of the IE effluent was observed when there was a significant increase in the color of the raw water. This resulted in a severe membrane fouling, which was likely to be attributed to the excess production of inorganic sludge associated with the increased coagulant dosage required to achieve sufficient reduction of color. Such severe membrane fouling can be controlled by optimising the backwashing and relaxation frequencies during the membrane filtration. These results indicate that the hybrid system proposed is a suitable technology for treating highly-colored surface water.


Foods ◽  
2018 ◽  
Vol 7 (10) ◽  
pp. 166 ◽  
Author(s):  
Abhiram Arunkumar ◽  
Mark Etzel

Fractionation of the bovine glycomacropeptide (GMP) from the other proteins in cheese whey was examined using ultrafiltration membranes surface modified to contain positively charged polymer brushes made of polyhexamethylene biguanide. By placing a strong positive charge on a 1000 kDa ultrafiltration membrane and adjusting the pH of whey close to the isoelectric point of GMP, a 14-fold increase in selectivity was observed compared to unmodified membranes. A one stage membrane system gave 90% pure GMP and a three-stage rectification system gave 97% pure GMP. The charged membrane was salt-tolerant up to 40 mS cm−1 conductivity, allowing fractionation of GMP directly from cheese whey without first lowering the whey conductivity by water dilution. Thus, similarly sized proteins that differed somewhat in isoelectric points and were 50–100 fold smaller than the membrane molecular weight cut-off (MWCO), were cleanly fractionated using charged ultrafiltration membranes without water addition. This is the first study to report on the use of salt-tolerant charged ultrafiltration membranes to produce chromatographically pure protein fractions from whey, making ultrafiltration an attractive alternative to chromatography for dairy protein fractionation.


PLoS ONE ◽  
2021 ◽  
Vol 16 (11) ◽  
pp. e0260186
Author(s):  
Marta Braga ◽  
Chee Hau Leow ◽  
Javier Hernandez Gil ◽  
Jin H. Teh ◽  
Laurence Carroll ◽  
...  

The C-X-C chemokine receptor 4 (CXCR4) is G protein-coupled receptor that upon binding to its cognate ligand, can lead to tumor progression. Several CXCR4-targeted therapies are currently under investigation, and with it comes the need for imaging agents capable of accurate depiction of CXCR4 for therapeutic stratification and monitoring. PET agents enjoy the most success, but more cost-effective and radiation-free approaches such as ultrasound (US) imaging could represent an attractive alternative. In this work, we developed a targeted microbubble (MB) for imaging of vascular CXCR4 expression in cancer. A CXCR4-targeted MB was developed through incorporation of the T140 peptide into the MB shell. Binding properties of the T140-MB and control, non-targeted MB (NT-MB) were evaluated in MDA-MB-231 cells where CXCR4 expression was knocked-down (via shRNA) through optical imaging, and in the lymphoma tumor models U2932 and SuDHL8 (high and low CXCR4 expression, respectively) by US imaging. PET imaging of [18F]MCFB, a tumor-penetrating CXCR4-targeted small molecule, was used to provide whole-tumor CXCR4 readouts. CXCR4 expression and microvessel density were performed by immunohistochemistry analysis and western blot. T140-MB were formed with similar properties to NT-MB and accumulated sensitively and specifically in cells according to their CXCR4 expression. In NOD SCID mice, T140-MB persisted longer in tumors than NT-MB, indicative of target interaction, but showed no difference between U2932 and SuDHL8. In contrast, PET imaging with [18F]MCFB showed a marked difference in tumor uptake at 40–60 min post-injection between the two tumor models (p<0.05). Ex vivo analysis revealed that the large differences in CXCR4 expression between the two models are not reflected in the vascular compartment, where the MB are restricted; in fact, microvessel density and CXCR4 expression in the vasculature was comparable between U2932 and SuDHL8 tumors. In conclusion, we successfully developed a T140-MB that can be used for imaging CXCR4 expression in the tumor vasculature.


Author(s):  
R.D.Longhurst J. Luo ◽  
M.B. O'Connor ◽  
T. Pow

The recent invention of Herd Homes has presented NZ dairy farmers with a flexible facility for feeding and standing-off stock especially during wet periods. Herd Homes are a combination of feeding platform, stand-off facility and animal shelter comprising a "greenhouse" type roof over slatted concrete floors with an underfloor manure bunker. The prototype Herd Home built in Northland for 230 cows was closely monitored during its initial year (2002/03). Different bunker media were evaluated for their ability to absorb and retain manure nutrients. The media tested were natural materials (soil, wood shavings and a combination of soil/wood shavings) that were all effective at capturing nutrients (N and S) from the bunker manure. Benefits of media amendments are greater nutrient enrichment of the final bunker manure making it more useful for subsequent land application. Use of soil as a bunker medium appears to be the most viable and cost effective option. In early 2006, manure samples were collected from Herd Home bunkers from four geographically diverse areas of NZ and analysed for nutrient content. Nutrient concentrations found reflected variability in cow numbers, usage and feed inputs. In November 2004, 10 existing Herd Home owners were surveyed as to their reasons for purchase. The farmers reported ease of farm management, "on-off" grazing, reduced pugging damage, and improved stock condition and production were some of the beneficial effects of Herd Homes. Keywords: Herd Homes, winter management, wintering system, stand off, feed pad, manure management, bunker manure


Author(s):  
B. I. Dikhanbayev ◽  
◽  
A.B. Dikhanbayev ◽  

An energy-saving method for processing technogenic waste has been developed — a smelt layer with inversion phase as a combination of “ideal” mixing and “ideal” displacement regimes. On its basis, a new generation of melting unit was created - the “reactor inversion phase - rotary kiln”. Experimental data show that in the inversion phase layer the specific fuel consumption for processing the “poor” on zinc and “rich” on zinc slags is approximately the same. The latter provision contradicts the prevailing opinion of metallurgists that the processing of slag with a zinc concentration of less than 5% is unprofitable. Сalculation results demonstrate that in case of implementation of an industrial sample of “reactor inversion phase - rotary kiln for processing “poor” slag, compared to the Waelz kiln processing “rich” slag, the specific consumption of fuel will be reduced by 1.5-1.7 times and specific productivity will increase 1.4-1.5 times. The industrial realization of “reactor inversion phase -rotary kiln” would allow cost-effective processing of fuming slag dumps, Waelz clinker, “poor” zinc ores, enrichment tails and other non-ferrous metal wastes.


2021 ◽  
Vol 9 ◽  
Author(s):  
Maria Bernardo ◽  
Nuno Lapa ◽  
Isabel Fonseca ◽  
Isabel A. A. C. Esteves

Porous carbon materials, derived from biomass wastes and/or as by-products, are considered versatile, economical and environmentally sustainable. Recently, their high adsorption capacity has led to an increased interest in several environmental applications related to separation/purification both in liquid- and gas-phases. Specifically, their use in carbon dioxide (CO2) capture/sequestration has been a hot topic in the framework of gas adsorption applications. Cost effective biomass porous carbons with enhanced textural properties and high CO2 uptakes present themselves as attractive alternative adsorbents with potential to be used in CO2 capture/separation, apart from zeolites, commercial activated carbons and metal-organic frameworks (MOFs). The renewable and sustainable character of the precursor of these bioadsorbents must be highlighted in the context of a circular-economy and emergent renewable energy market to reach the EU climate and energy goals. This mini-review summarizes the current understandings and discussions about the development of porous carbons derived from bio-wastes, focusing their application to capture CO2 and upgrade biogas to biomethane by adsorption-based processes. Biogas is composed by 55–65 v/v% of methane (CH4) mainly in 35–45 v/v% of CO2. The biogas upgraded to bio-CH4 (97%v/v) through an adsorption process yields after proper conditioning to high quality biomethane and replaces natural gas of fossil source. The circular-economy impact of bio-CH4 production is further enhanced by the use of biomass-derived porous carbons employed in the production process.


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