Geochemical characteristics of deep groundwater from sandstone aquifer in Qianyingzi mine, northern Anhui province, China

2014 ◽  
Vol 9 (1) ◽  
pp. 95-103 ◽  
Author(s):  
He Rong Gui

Major ions, trace elements and isotope concentrations for eight groundwater samples were tested, which collected from sandstone aquifer in Qianyingzi mine, northern Anhui province, China. The Geochemical characteristic of groundwater samples were studied based on the conventional graphical and multivariate statistical approach, and the resulted showed: two types of groundwater could be identified through the Piper diagram, which have high concentrations total dissolved solids (1,164–5,165 mg/L), with alkaline environment (pH = 8.02–8.90) in nature; the rare earth element of groundwater samples are characterized by enrichment of HREEs compared to LREEs when normalized to PAAS, which presented from the NdSN/YbSN ratios ranging from 0.042 to 0.121, with an average 0.075; groundwater characterized by negative Ce anomalies and positive Eu anomalies, what could be caused by the Ph conditions and exchange reaction between Eu2+ and Sr2+, respectively; δ18O and δ2H of groundwater varied from −8.78 to −8.36‰ and −68.5 to −59.5‰, respectively. The detritus and the exchange reaction between groundwater and alkyl could be the reason of obviously drift of δ2H.

2013 ◽  
Vol 8 (1) ◽  
pp. 131-141 ◽  
Author(s):  
Song Chen ◽  
Xue Hai Fu ◽  
He Rong Gui ◽  
Lin Hua Sun

Major ions were analyzed for twenty five groundwater samples collected from diverse aquifer in Baishan mining, northern Anhui province, China. Conventional graphical and multivariate statistical approach were completed to identify the hydro-geochemical process and water-rock interaction, that be combined with the Cluster Analysis (CA) and Fisher discriminant analysis to recognize the sealed samples, the result showed: the diverse samples have vary ions inheriting from aquifer, samples collected from Sandstone aquifer (SA) is characterized by the high concentration of Na+ + K+, for the feldspar weathering is dominant; Ordovician limestone aquifer (OA) waters have abundance Ca2+ and Mg2+, for the dissolution of calcite and dolomite obviously; the dissolution of calcite and other calcareous concretions are dominant in Taiyuan formation water (TA) and Quaternary aquifer (QA) for the high ratio of Ca2+/Mg2+, otherwise the varied content of SO42– and HCO3− could distinguish the two aquifer water. Twenty five groundwater samples, containing six sealed samples, had been subdivided in to four groups by the CA, what are corresponded with four aquifers. Fisher discriminant functions were obtained and the efficiency was acceptable for the error rate 4% in all twenty five samples.


2013 ◽  
Vol 8 (3-4) ◽  
pp. 330-341 ◽  
Author(s):  
Song Chen ◽  
He Rong Gui ◽  
Lin Hua Sun

Hydro-geochemistry and isotopes were used to understand the geochemical character and origin of the groundwater from coal bearing aquifer in Northern Anhui province, China. Twenty three groundwater samples were collected, and the isotopic composition δD, δ18O and major ions were analyzed, conventional graphical and multivariate statistical approach was completed and the result showed: three groups of groundwater could be divided form the rectangular field, the Ca-Mg-Cl, Na-Cl-SO4 and Na-HCO3 type water; the feldspar weathering is dominating weathering process, whereas, the sulfuric acid is the weathering agent along with the carbonic acid; the groundwater mainly supplied from the meteoric water for all the plots are below the local meteoric water line and global meteoric water line, the values of δD are drifted obviously, what could be caused by the exchange reaction of δD between groundwater and alkyl.


2021 ◽  
Author(s):  
juyeon Lee ◽  
minjune Yang

<p>This study conducted a rhizofiltration experiment for uranium-removal with the edible plants (<em>Lactuca sativa, Brassica campestris </em>L., <em>Raphanus sativus </em>L., and <em>Oenanthe javanica</em>) which generally consumed in South Korea. Various batch experiments were performed with different initial uranium concentrations, pH conditions, and genuine groundwater. The results showed the uranium accumulation and bioconcentration factor (BCF) of plant roots increase with an increase in initial uranium concentrations in the solution. Of the four plants, the amount of uranium accumulated in <em>Raphanus sativus </em>L. roots was 1215.8 μg/g DW with the maximum BCF value of 2692.7. The BCF value based on various pH conditions (pHs 3, 5, 7 and 9) of artificial solutions was highest at pH 3 for all four plants, and the BCF value of <em>Brassica campestris </em>L. was the maximum of 11580.3 at pH 3. As a result of rhizofiltration experiments with genuine groundwater contaminated with uranium, the BCF values of <em>Raphanus sativus </em>L. were 1684.7 and 1700.1, the highest among the four species, in Oesam-dong and Bugokdong groundwater samples with uranium concentration of 83 and 173 μg/L. From SEM/EDS analysis, it was confirmed that uranium in contaminated groundwater was adsorbed as a solid phase on the root surface. These results demonstrate that <em>Raphanus sativus </em>L. not only has a high tolerance to high concentrations of uranium and low pH conditions but also has a remarkable potential for uranium accumulation capacity.</p>


2020 ◽  
Vol 69 (4) ◽  
pp. 398-414 ◽  
Author(s):  
Vasant Wagh ◽  
Shrikant Mukate ◽  
Aniket Muley ◽  
Ajaykumar Kadam ◽  
Dipak Panaskar ◽  
...  

Abstract The integration of pollution index of groundwater (PIG), multivariate statistical techniques including correlation matrix (CM), principal component analysis (PCA), cluster analysis (CA) and various ionic plots was applied to elucidate the influence of natural and anthropogenic inputs on groundwater chemistry and quality of the Kadava river basin. A total of 80 groundwater samples were collected and analysed for major ions during pre- and post-monsoon seasons of 2012. Analytical results inferred that Ca, Mg, Cl, SO4 and NO3 surpass the desirable limit (DL) and permissible limit (PL) of Bureau of Indian Standards (BIS) and the World Health Organization (WHO) in both the seasons. The elevated content of total dissolved solids (TDS), Cl, SO4, Mg, Na and NO3 is influenced by precipitation and agricultural dominance. PIG results inferred that 52.5 and 35%, 30 and 37.5%, 12.5 and 20%, 2.5 and 5% groundwater samples fall in insignificant, low, moderate and high pollution category (PC) in pre- and post-monsoon seasons, respectively. PC 1 confirms salinity controlled process due to high inputs of TDS, Ca, Mg, Na, Cl and SO4. Also, PC 2 suggests alkalinity influence by pH, CO3, HCO3 and F content. PIG and statistical techniques help to interpret the water quality data in an easier way.


2018 ◽  
Vol 39 (1) ◽  
pp. 109-117
Author(s):  
Ikram Mokeddem ◽  
Meriem Belhachemi ◽  
Touhami Merzougui ◽  
Noria Nabbou ◽  
Salih Lachache

AbstractGroundwater samples from Turonian aquifer of Béchar region were evaluated as drinking and irrigation water sources. physicochemical parameters including pH, EC, TH, Na+, Ca2+, Mg2+, Cl−, SO42– and NO3− were determined for 16 water sampling points. These characterizations show that the groundwater is fresh to brackish, slightly alkaline and the major ions are Na+, Ca2+, Mg2+, Cl− and SO42–. According to WHO standards, 50% of the analysed water are suitable as a drinking source while the other samples are not in compliance with drinking water standards. This non-compliance is basically due to the high concentrations of Na+, Cl−, and SO42– requesting further treatment to reach the stringent standards. According to the results of nitrate concentrations, anthropogenic source seems to influence the groundwater quality. The present study shows that Béchar groundwater may represent an important drinking and irrigation water source. However, a specific management strategy should be adapted in order to avoid the contamination by anthropogenic sources.


2019 ◽  
Vol 19 (1) ◽  
pp. 19
Author(s):  
Evarista Ristin Pujiindiyati ◽  
Satrio Satrio ◽  
Rasi Prasetio

Bantar Gebang landfill located in Bekasi regency is a biggest sanitary landfill in Indonesia which comes up some refusals from local people because of its bad impact on their environment. Major ion contents in leachate and fresh groundwater were investigated during the rainy and dry season to determine contamination by leachate released from Bantar Gebang and Sumur Batu landfill. Leachate contained high concentrations of all major ions that was mainly characterized as a NaKHCO3 water type. On the other hand, most fresh groundwater samples were predominated by CaMgHCO3 and CaMgCl water type. Concentrations of K+, Ca2+, Mg2+, Na+, SO42-, Cl-, HCO3- and NO3- in leachate were to be in a maximum factor of 2110; 7; 6; 143; 20; 112; 349 and 20, respectively than its contents in groundwater. Leachate from Bantar Gebang was detected have a higher concentration than those contained in Sumur Batu that was probably due to its mature leachate. An estimated mixture of leachate to fresh water in monitoring wells (5 m and 15 m depth) was in the range of 20 to 34%, related to Na+ and Cl- signatures, while the shallow groundwater located in residents in the vicinity of these landfills exhibited maximum leachate about 2%.


2015 ◽  
Vol 10 (3) ◽  
pp. 609-615
Author(s):  
Song Chen ◽  
Herong Gui

To understand the hydrochemistry evolution characters of deep groundwater under the coal mine exploitation, 66 historical chemical data of groundwater samples were collected from 1997 to 2011 in Qinan coal mine, Anhui Province, China, the hydrochemical characteristics and its evolution characters were obtained by the methods such as multivariate statistical approach and conventional graphical. The results showed that the concentrations of Na+ + K+ are higher in all groundwater samples, whereas the contents of Ca2+ and Mg2+ are lower. The concentrations of Na+ + K+ were decreasing as follows: limestone aquifer < quaternary aquifers < coal bearing aquifer. The chemical compositions of groundwater collected from three aquifer were varied obviously from 1997 to 2011. Three principle component factors could be extracted through statistical approach, PC1 was affirmed the dissolution of limestone, dolomite and gypsum dissolution. PC2 could be as the carbonation process or desulfurizing process, while PC3 indicated the weathering process of feldspar minerals weathering by the carbonate acid.


2022 ◽  
Vol 9 ◽  
Author(s):  
Mohd Yawar Ali Khan ◽  
Mohamed El Kashouty ◽  
Waleed Gusti ◽  
Amit Kumar ◽  
Ali Mohammad Subyani ◽  
...  

Seawater has intruded into many of Saudi Arabia’s Red Sea coastal aquifers, with varying degrees of extension depending on location, hydrogeology, and population density. This study aimed to evaluate and comprehend the processes that influence the hydrogeochemical characteristics of the coastal aquifer in Saudi Arabia’s Khulais region. Groundwater samples were taken from nineteen locations during the winter and summer of 2021, and data from major ions and trace elements were examined and interpreted using ArcGIS software. The total dissolved solids (TDS) concentrations ranged between 480 and 15,236 mg/L and 887–18,620 mg/L in winter and summer, respectively. Groundwater TDS concentration was observed to be influenced by groundwater flow, lithogenic, anthropogenic, and seawater intrusion in this study (2021) when compared to 2016. The concentration of nitrate (NO3−) and strontium (Sr) in most samples exceeds the drinking guidelines. The occurrence of high concentrations of bromide (Br), Fluoride (F), Iron (Fe) (winter and summer) and Aluminum (Al), Boron (B), Chromium (Cr), Nickel (Ni), lead (Pb), cadmium (Cd), cobalt (Co), copper (Cu) and manganese (Mn) (winter) was also exhibited and observed up to more than drinking and irrigation limits. The central part of the study area was affected by seawater intrusion. The hydraulic conductivity of the topsoil was measured, and it ranged from 0.24 to 29.3 m/day. Based on electrical conductivity (EC) and sodium absorption ratio, most aquifer samples were unsuitable for irrigation (SAR).


2020 ◽  
Vol 53 (2C) ◽  
pp. 121-133
Author(s):  
Muhammeed Jummah

Groundwater quality is of prime importance in determining its suitability for various human activity such as irrigation, therefore, groundwater samples are collected from selective wells in Anah city and subjected to hydrochemical analysis in order to measure the concentrations of the major ions, in addition to the Electrical Conductivity, pH, Total Dissolved Solids, Soluble Sodium Percentage (Na%), and Sodium Adsorption Ratio)SAR( to assess the suitability of groundwater for irrigation. Results showed that the groundwater in Anah city is characterized by excellent to good SAR with good Na% and accepted value of pH for irrigation, whereas, values of Electrical Conductivity and Total Dissolved Solids were not acceptable due to the rising of salinity (SO4 and Cl). According to Piper diagram, the type of water is Earth alkaline.


Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2009
Author(s):  
Youcef Boudjana ◽  
Serge Brouyère ◽  
Pierre Jamin ◽  
Philippe Orban ◽  
Davide Gasparella ◽  
...  

An abandoned industrial site in Belgium, located in the catchment of a chalk aquifer mainly used for drinking water, has been investigated for groundwater pollution due to a mixture of chlorinated solvents with mainly 1,1,1-trichloroethane (1,1,1-TCA) at high concentrations. The observed elevated groundwater mineralization was partly explained by chemical reactions associated with hydrolysis and dehydrohalogenation (HY/DH) of 1,1,1-TCA in the chalky aquifer. Leaching of soluble compounds from a backfilled layer located in the site could also have influenced the groundwater composition. In this context, the objective of this study was to investigate the hydrochemical processes controlling groundwater mineralization through a characterization of the backfill and groundwater chemical composition. This is essential in the context of required site remediation to define appropriate remediation measures to soil and groundwater. Groundwater samples were collected for chemical analyses of chlorinated aliphatic hydrocarbons, major ions, and several minor ones. X-Ray Diffraction Analysis (XRD), Scanning Electron Microscopy (SEM) and a leaching test according to CEN/TS 14405 norm were carried out on the backfill soil. δ34S and δ18O of sulphate in groundwater and in the backfill eluates were also compared. Both effects influencing the groundwater hydrochemistry around the site were clarified. First, calcite dissolution under the 1,1,1-TCA degradation reactions results in a water mineralization increase. It was assessed by geochemical batch simulations based on observed data. Second, sulphate and calcium released from the backfill have reached the groundwater. The leaching test provided an estimation of the minimal released quantities.


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